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Glycerol to Solketal for Fuel Additive: Recent Progress in Heterogeneous Catalysts

Author

Listed:
  • Is Fatimah

    (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Islam Indonesia, Jl. Kaliurang Km 14, Sleman, Yogyakarta 55584, Indonesia)

  • Imam Sahroni

    (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Islam Indonesia, Jl. Kaliurang Km 14, Sleman, Yogyakarta 55584, Indonesia)

  • Ganjar Fadillah

    (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Islam Indonesia, Jl. Kaliurang Km 14, Sleman, Yogyakarta 55584, Indonesia)

  • Muhammad Miqdam Musawwa

    (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Islam Indonesia, Jl. Kaliurang Km 14, Sleman, Yogyakarta 55584, Indonesia)

  • Teuku Meurah Indra Mahlia

    (School of Information, Systems and Modelling, Faculty of Engineering and Information Technology, University of Technology Sydney, Sydney, NSW 2007, Australia)

  • Oki Muraza

    (Center of Research Excellence in Nanotechnology and Chemical Engineering Department, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia)

Abstract

Biodiesel has been successfully commercialized in numerous countries. Glycerol, as a byproduct in biodiesel production plant, has been explored recently for fuel additive production. One of the most prospective fuel additives is solketal, which is produced from glycerol and acetone via an acetalization reaction. This manuscript reviewed recent progress on heterogeneous catalysts used in the exploratory stage of glycerol conversion to solketal. The effects of acidity strength, hydrophobicity, confinement effect, and others are discussed to find the most critical parameters to design better catalysts for solketal production. Among the heterogeneous catalysts, resins, hierarchical zeolites, mesoporous silica materials, and clays have been explored as effective catalysts for acetalization of glycerol. Challenges with each popular catalytic material are elaborated. Future works on glycerol to solketal will be improved by considering the stability of the catalysts in the presence of water as a byproduct. The presence of water and salt in the feed is certainly destructive to the activity and the stability of the catalysts.

Suggested Citation

  • Is Fatimah & Imam Sahroni & Ganjar Fadillah & Muhammad Miqdam Musawwa & Teuku Meurah Indra Mahlia & Oki Muraza, 2019. "Glycerol to Solketal for Fuel Additive: Recent Progress in Heterogeneous Catalysts," Energies, MDPI, vol. 12(15), pages 1-14, July.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:15:p:2872-:d:251777
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    References listed on IDEAS

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    2. Aby Cheruvathoor Poulose & Miroslav Medveď & Vasudeva Rao Bakuru & Akashdeep Sharma & Deepika Singh & Suresh Babu Kalidindi & Hugo Bares & Michal Otyepka & Kolleboyina Jayaramulu & Aristides Bakandrit, 2023. "Acidic graphene organocatalyst for the superior transformation of wastes into high-added-value chemicals," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Sedghi, Reza & Shahbeik, Hossein & Rastegari, Hajar & Rafiee, Shahin & Peng, Wanxi & Nizami, Abdul-Sattar & Gupta, Vijai Kumar & Chen, Wei-Hsin & Lam, Su Shiung & Pan, Junting & Tabatabaei, Meisam & A, 2022. "Turning biodiesel glycerol into oxygenated fuel additives and their effects on the behavior of internal combustion engines: A comprehensive systematic review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    4. Imtisal Zahid & Muhammad Ayoub & Bawadi Bin Abdullah & Muhammad Hamza Nazir & Zulqarnain & Mariam Ameen Kaimkhani & Farooq Sher, 2021. "Activation of Nano Kaolin Clay for Bio-Glycerol Conversion to a Valuable Fuel Additive," Sustainability, MDPI, vol. 13(5), pages 1-17, March.

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