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An Overview of the Production of Oxygenated Fuel Additives by Glycerol Etherification, Either with Isobutene or tert -Butyl Alcohol, over Heterogeneous Catalysts

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  • Rafael Estevez

    (Departamento de Química Orgánica, Ed. Marie Curie, Campus de Rabanales, Instituto Universitario de Nanoquímica (IUNAN), Universidad de Córdoba, 14071 Córdoba, Spain)

  • Laura Aguado-Deblas

    (Departamento de Química Orgánica, Ed. Marie Curie, Campus de Rabanales, Instituto Universitario de Nanoquímica (IUNAN), Universidad de Córdoba, 14071 Córdoba, Spain)

  • Diego Luna

    (Departamento de Química Orgánica, Ed. Marie Curie, Campus de Rabanales, Instituto Universitario de Nanoquímica (IUNAN), Universidad de Córdoba, 14071 Córdoba, Spain)

  • Felipa M. Bautista

    (Departamento de Química Orgánica, Ed. Marie Curie, Campus de Rabanales, Instituto Universitario de Nanoquímica (IUNAN), Universidad de Córdoba, 14071 Córdoba, Spain)

Abstract

Biodiesel production has considerably increased in recent decades, generating a surplus of crude glycerol, which is the main drawback for the economy of the process. To overcome this, many scientists have directed their efforts to transform glycerol, which has great potential as a platform molecule, into value-added products. A promising option is the preparation of oxygenate additives for fuel, in particular those obtained by the etherification reaction of glycerol with alcohols or olefins, mainly using heterogeneous catalysis. This review collects up-to-date research findings in the etherification of glycerol, either with isobutene (IB) or tert -Butyl alcohol (TBA), highlighting the best catalytic performances reported. Furthermore, the experimental sets employed for these reactions have been included in the present manuscript. Likewise, the characteristics of the glycerol ethers–(bio)fuel blends as well as their performances (e.g., quality of emissions, technical advantages or disadvantages, etc.) have been also compiled and discussed.

Suggested Citation

  • Rafael Estevez & Laura Aguado-Deblas & Diego Luna & Felipa M. Bautista, 2019. "An Overview of the Production of Oxygenated Fuel Additives by Glycerol Etherification, Either with Isobutene or tert -Butyl Alcohol, over Heterogeneous Catalysts," Energies, MDPI, vol. 12(12), pages 1-20, June.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:12:p:2364-:d:241366
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    References listed on IDEAS

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    Cited by:

    1. Diego Luna & Rafael Estevez, 2022. "Optimization of Biodiesel and Biofuel Process," Energies, MDPI, vol. 15(16), pages 1-4, August.

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