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Recent Advances on the Valorization of Glycerol into Alcohols

Author

Listed:
  • Louise R. Smith

    (Max Planck-Cardiff Centre on the Fundamentals of Heterogeneous Catalysis FUNCAT, Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UK)

  • Mark Douthwaite

    (Max Planck-Cardiff Centre on the Fundamentals of Heterogeneous Catalysis FUNCAT, Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UK)

  • Karl Mugford

    (Max Planck-Cardiff Centre on the Fundamentals of Heterogeneous Catalysis FUNCAT, Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UK)

  • Nicholas F. Dummer

    (Max Planck-Cardiff Centre on the Fundamentals of Heterogeneous Catalysis FUNCAT, Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UK)

  • David J. Willock

    (Max Planck-Cardiff Centre on the Fundamentals of Heterogeneous Catalysis FUNCAT, Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UK)

  • Graham J. Hutchings

    (Max Planck-Cardiff Centre on the Fundamentals of Heterogeneous Catalysis FUNCAT, Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UK)

  • Stuart H. Taylor

    (Max Planck-Cardiff Centre on the Fundamentals of Heterogeneous Catalysis FUNCAT, Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UK)

Abstract

Glycerol, a highly functionalised polyol, can be used as a platform molecule to produce a variety of high-value chemicals. As glycerol production is projected to increase over the coming years, it’s critically important that technology and infrastructure are developed to make use of the inevitable surplus. The catalytic production of ‘green’ mono alcohols from glycerol, in the absence of H 2 , is an emerging area of research that, in recent years, has generated significant industrial interest. Herein, we provide an update on recent advances in this field and discuss challenges which need to be overcome if this approach is to be considered viable industrially. The economic significance of using crude glycerol as a feedstock for glycerol valorisation strategies is also addressed and suggestions for improving the impact of research conducted in this field are proposed.

Suggested Citation

  • Louise R. Smith & Mark Douthwaite & Karl Mugford & Nicholas F. Dummer & David J. Willock & Graham J. Hutchings & Stuart H. Taylor, 2022. "Recent Advances on the Valorization of Glycerol into Alcohols," Energies, MDPI, vol. 15(17), pages 1-22, August.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:17:p:6250-:d:899217
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    References listed on IDEAS

    as
    1. Paul J. Smith & Louise Smith & Nicholas F. Dummer & Mark Douthwaite & David J. Willock & Mark Howard & David W. Knight & Stuart H. Taylor & Graham J. Hutchings, 2019. "Investigating the Influence of Reaction Conditions and the Properties of Ceria for the Valorisation of Glycerol," Energies, MDPI, vol. 12(7), pages 1-14, April.
    2. Macedo, M. Salomé & Soria, M.A. & Madeira, Luis M., 2021. "Process intensification for hydrogen production through glycerol steam reforming," Renewable and Sustainable Energy Reviews, Elsevier, vol. 146(C).
    3. Nanda, Malaya R. & Zhang, Yongsheng & Yuan, Zhongshun & Qin, Wensheng & Ghaziaskar, Hassan S. & Xu, Chunbao (Charles), 2016. "Catalytic conversion of glycerol for sustainable production of solketal as a fuel additive: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 1022-1031.
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