IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v123y2014icp75-81.html
   My bibliography  Save this article

A new continuous-flow process for catalytic conversion of glycerol to oxygenated fuel additive: Catalyst screening

Author

Listed:
  • Nanda, Malaya R.
  • Yuan, Zhongshun
  • Qin, Wensheng
  • Ghaziaskar, Hassan S.
  • Poirier, Marc-Andre
  • Xu, Chunbao (Charles)

Abstract

A new continuous-flow reactor was designed for the conversion of glycerol to solketal, an oxygenated fuel additive, through ketalization with acetone. Six heterogeneous catalysts were investigated with respect to their catalytic activity and stability in a flow reactor. The acidity of the catalysts positively influences the catalyst’s activity. Among all the solid acid catalysts tested, the maximum solketal yield from experiments at 40°C, 600 psi and WHSV of 4h−1 attained 73% and 88% at the acetone/glycerol molar ratio of 2.0 and 6.0, respectively, with Amberlyst Wet. Based on the solketal yield and glycerol conversion results, the activity of all catalysts tested follows the following order of sequence: Amberlyst Wet≈Zeolite≈Amberlyst Dry>Zirconium Sulfate>Montmorillonite>Polymax. An increase in acetone/glycerol molar ratio or a decrease in WHSV enhanced the glycerol conversion as expected. This process offers an attractive route for converting glycerol, the main by-product of biodiesel, to solketal – a value-added green product with potential industrial applications as a valuable fuel additive or combustion promoter for gasoline engines.

Suggested Citation

  • Nanda, Malaya R. & Yuan, Zhongshun & Qin, Wensheng & Ghaziaskar, Hassan S. & Poirier, Marc-Andre & Xu, Chunbao (Charles), 2014. "A new continuous-flow process for catalytic conversion of glycerol to oxygenated fuel additive: Catalyst screening," Applied Energy, Elsevier, vol. 123(C), pages 75-81.
  • Handle: RePEc:eee:appene:v:123:y:2014:i:c:p:75-81
    DOI: 10.1016/j.apenergy.2014.02.055
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261914001998
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.apenergy.2014.02.055?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Fantozzi, F. & Frassoldati, A. & Bartocci, P. & Cinti, G. & Quagliarini, F. & Bidini, G. & Ranzi, E.M., 2016. "An experimental and kinetic modeling study of glycerol pyrolysis," Applied Energy, Elsevier, vol. 184(C), pages 68-76.
    2. Is Fatimah & Imam Sahroni & Ganjar Fadillah & Muhammad Miqdam Musawwa & Teuku Meurah Indra Mahlia & Oki Muraza, 2019. "Glycerol to Solketal for Fuel Additive: Recent Progress in Heterogeneous Catalysts," Energies, MDPI, vol. 12(15), pages 1-14, July.
    3. Nanda, Malaya R. & Zhang, Yongsheng & Yuan, Zhongshun & Qin, Wensheng & Ghaziaskar, Hassan S. & Xu, Chunbao (Charles), 2016. "Catalytic conversion of glycerol for sustainable production of solketal as a fuel additive: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 1022-1031.
    4. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Rajaei, Kourosh & Tarighi, Sara, 2018. "Oxidation of bio-renewable glycerol to value-added chemicals through catalytic and electro-chemical processes," Applied Energy, Elsevier, vol. 230(C), pages 1347-1379.
    5. Ribeiro, Mariana B. & Cavalcante, Raquel M. & Young, André F., 2022. "Simulation and economic evaluation of fuel additives production from glycerol," Renewable Energy, Elsevier, vol. 181(C), pages 1081-1099.
    6. Cornejo, A. & Barrio, I. & Campoy, M. & Lázaro, J. & Navarrete, B., 2017. "Oxygenated fuel additives from glycerol valorization. Main production pathways and effects on fuel properties and engine performance: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1400-1413.
    7. Aghbashlo, Mortaza & Hosseinpour, Soleiman & Tabatabaei, Meisam & Rastegari, Hajar & Ghaziaskar, Hassan S., 2019. "Multi-objective exergoeconomic and exergoenvironmental optimization of continuous synthesis of solketal through glycerol ketalization with acetone in the presence of ethanol as co-solvent," Renewable Energy, Elsevier, vol. 130(C), pages 735-748.
    8. Trifoi, Ancuţa Roxana & Agachi, Paul Şerban & Pap, Timea, 2016. "Glycerol acetals and ketals as possible diesel additives. A review of their synthesis protocols," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 804-814.
    9. Sedghi, Reza & Shahbeik, Hossein & Rastegari, Hajar & Rafiee, Shahin & Peng, Wanxi & Nizami, Abdul-Sattar & Gupta, Vijai Kumar & Chen, Wei-Hsin & Lam, Su Shiung & Pan, Junting & Tabatabaei, Meisam & A, 2022. "Turning biodiesel glycerol into oxygenated fuel additives and their effects on the behavior of internal combustion engines: A comprehensive systematic review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    10. Imtisal Zahid & Muhammad Ayoub & Bawadi Bin Abdullah & Muhammad Hamza Nazir & Zulqarnain & Mariam Ameen Kaimkhani & Farooq Sher, 2021. "Activation of Nano Kaolin Clay for Bio-Glycerol Conversion to a Valuable Fuel Additive," Sustainability, MDPI, vol. 13(5), pages 1-17, March.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:123:y:2014:i:c:p:75-81. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.