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Liquid Lipase-Catalyzed Esterification of Oleic Acid with Methanol for Biodiesel Production in the Presence of Superabsorbent Polymer: Optimization by Using Response Surface Methodology

Author

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  • Hoang Chinh Nguyen

    (Faculty of Applied Sciences, Ton Duc Thang University, Ho Chi Minh City 700000, Vietnam
    These authors contributed equally to this work.)

  • Dinh Thi My Huong

    (Faculty of Chemical Engineering, University of Technology and Education—The University of Danang, Danang City 550000, Vietnam
    Department of Chemical Engineering, Ming Chi University of Technology, New Taipei City 24301, Taiwan
    These authors contributed equally to this work.)

  • Horng-Yi Juan

    (Department of Chemical Engineering, Ming Chi University of Technology, New Taipei City 24301, Taiwan
    These authors contributed equally to this work.)

  • Chia-Hung Su

    (Department of Chemical Engineering, Ming Chi University of Technology, New Taipei City 24301, Taiwan)

  • Chien-Chung Chien

    (Department of Chemical Engineering, Ming Chi University of Technology, New Taipei City 24301, Taiwan)

Abstract

Liquid lipase-catalyzed esterification of fatty acids with methanol is a promising process for biodiesel production. However, water by-product from this process favors the reverse reaction, thus reducing the reaction yield. To address this, superabsorbent polymer (SAP) was used as a water-removal agent in the esterification in this study. SAP significantly enhanced the conversion yield compared with the reaction without SAP. The lipase-catalyzed esterification in the presence of SAP was then optimized by response surface methodology to maximize the reaction conversion. A maximum conversion of 96.73% was obtained at a temperature of 35.25 °C, methanol to oleic acid molar ratio of 3.44:1, SAP loading of 10.55%, and enzyme loading of 11.98%. Under these conditions, the Eversa Transform lipase could only be reused once. This study suggests that the liquid lipase-catalyzed esterification of fatty acids using SAP as a water-removal agent is an efficient process for producing biodiesel.

Suggested Citation

  • Hoang Chinh Nguyen & Dinh Thi My Huong & Horng-Yi Juan & Chia-Hung Su & Chien-Chung Chien, 2018. "Liquid Lipase-Catalyzed Esterification of Oleic Acid with Methanol for Biodiesel Production in the Presence of Superabsorbent Polymer: Optimization by Using Response Surface Methodology," Energies, MDPI, vol. 11(5), pages 1-12, April.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:5:p:1085-:d:143693
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    Cited by:

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    2. Wei-Hsin Chen & Keat Teong Lee & Hwai Chyuan Ong, 2019. "Biofuel and Bioenergy Technology," Energies, MDPI, vol. 12(2), pages 1-12, January.
    3. Ibnu Maulana Hidayatullah & Frederick Soetandar & Pingkan Vanessa Sudiyasa & Patrick Cognet & Heri Hermansyah, 2023. "Ion Exchange Resin and Entrapped Candida rugosa Lipase for Biodiesel Synthesis in the Recirculating Packed-Bed Reactor: A Performance Comparison of Heterogeneous Catalysts," Energies, MDPI, vol. 16(12), pages 1-17, June.
    4. Wancura, João H.C. & Brondani, Michel & dos Santos, Maicon S.N. & Oro, Carolina E.D. & Wancura, Guilherme C. & Tres, Marcus V. & Oliveira, J. Vladimir, 2023. "Demystifying the enzymatic biodiesel: How lipases are contributing to its technological advances," Renewable Energy, Elsevier, vol. 216(C).
    5. Hoang Chinh Nguyen & Fu-Ming Wang & Kim Khue Dinh & Thanh Truc Pham & Horng-Yi Juan & Nguyen Phuong Nguyen & Hwai Chyuan Ong & Chia-Hung Su, 2020. "Microwave-Assisted Noncatalytic Esterification of Fatty Acid for Biodiesel Production: A Kinetic Study," Energies, MDPI, vol. 13(9), pages 1-15, May.

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