IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v104y2013icp503-509.html
   My bibliography  Save this article

Recoverable and reusable hydrochloric acid used as a homogeneous catalyst for biodiesel production

Author

Listed:
  • Su, Chia-Hung

Abstract

Several homogeneous acid catalysts (nitric, sulfuric, and hydrochloric acids), were selected to investigate their recoverability and reusability for esterifying enzyme-hydrolyzed FFAs and methanol to produce biodiesel. Although all of the three catalysts drove the reaction at high yield, hydrochloric acid is the only recoverable and reusable catalyst, as indicated by partitioning data. Hence, esterifying FFAs and methanol was catalyzed using hydrochloric acid; and the reaction conversion, which was affected by the reaction conditions, was optimized using response surface methodology. A maximal reaction conversion of 98.19% was obtained at 76.67°C, at a methanol/FFAs molar ratio of 7.92, a catalyst concentration of 0.54M, and after a reaction time of 103.57min. The catalyst could be reused at least five times to drive the reaction to a conversion of 97%. This study demonstrated that recoverable and reusable hydrochloric acid is promising for potential applications, including biodiesel production.

Suggested Citation

  • Su, Chia-Hung, 2013. "Recoverable and reusable hydrochloric acid used as a homogeneous catalyst for biodiesel production," Applied Energy, Elsevier, vol. 104(C), pages 503-509.
    • Handle: RePEc:eee:appene:v:104:y:2013:i:c:p:503-509
    DOI: 10.1016/j.apenergy.2012.11.026
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261912008197
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2012.11.026?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Hu, Shengyang & Guan, Yanping & Wang, Yun & Han, Heyou, 2011. "Nano-magnetic catalyst KF/CaO-Fe3O4 for biodiesel production," Applied Energy, Elsevier, vol. 88(8), pages 2685-2690, August.
    2. Guo, Feng & Xiu, Zhi-Long & Liang, Zhi-Xia, 2012. "Synthesis of biodiesel from acidified soybean soapstock using a lignin-derived carbonaceous catalyst," Applied Energy, Elsevier, vol. 98(C), pages 47-52.
    3. Iriarte, Alfredo & Rieradevall, Joan & Gabarrell, Xavier, 2012. "Transition towards a more environmentally sustainable biodiesel in South America: The case of Chile," Applied Energy, Elsevier, vol. 91(1), pages 263-273.
    4. Balat, Mustafa & Balat, Havva, 2010. "Progress in biodiesel processing," Applied Energy, Elsevier, vol. 87(6), pages 1815-1835, June.
    5. Li, Yuesong & Lian, Shuang & Tong, Dongmei & Song, Ruili & Yang, Wenyan & Fan, Yong & Qing, Renwei & Hu, Changwei, 2011. "One-step production of biodiesel from Nannochloropsis sp. on solid base Mg–Zr catalyst," Applied Energy, Elsevier, vol. 88(10), pages 3313-3317.
    6. Montefrio, Marvin Joseph & Xinwen, Tai & Obbard, Jeffrey Philip, 2010. "Recovery and pre-treatment of fats, oil and grease from grease interceptors for biodiesel production," Applied Energy, Elsevier, vol. 87(10), pages 3155-3161, October.
    7. Wen, Zhenzhong & Yu, Xinhai & Tu, Shan-Tung & Yan, Jinyue & Dahlquist, Erik, 2010. "Synthesis of biodiesel from vegetable oil with methanol catalyzed by Li-doped magnesium oxide catalysts," Applied Energy, Elsevier, vol. 87(3), pages 743-748, March.
    8. Melvin Jose, D.F. & Edwin Raj, R. & Durga Prasad, B. & Robert Kennedy, Z. & Mohammed Ibrahim, A., 2011. "A multi-variant approach to optimize process parameters for biodiesel extraction from rubber seed oil," Applied Energy, Elsevier, vol. 88(6), pages 2056-2063, June.
    9. Atadashi, I.M. & Aroua, M.K. & Aziz, A.R. Abdul & Sulaiman, N.M.N., 2011. "Refining technologies for the purification of crude biodiesel," Applied Energy, Elsevier, vol. 88(12), pages 4239-4251.
    10. Pandey, Krishan K. & Pragya, Namita & Sahoo, P.K., 2011. "Life cycle assessment of small-scale high-input Jatropha biodiesel production in India," Applied Energy, Elsevier, vol. 88(12), pages 4831-4839.
    11. Santori, Giulio & Di Nicola, Giovanni & Moglie, Matteo & Polonara, Fabio, 2012. "A review analyzing the industrial biodiesel production practice starting from vegetable oil refining," Applied Energy, Elsevier, vol. 92(C), pages 109-132.
    12. Lin, Lin & Cunshan, Zhou & Vittayapadung, Saritporn & Xiangqian, Shen & Mingdong, Dong, 2011. "Opportunities and challenges for biodiesel fuel," Applied Energy, Elsevier, vol. 88(4), pages 1020-1031, April.
    13. Leung, Dennis Y.C. & Wu, Xuan & Leung, M.K.H., 2010. "A review on biodiesel production using catalyzed transesterification," Applied Energy, Elsevier, vol. 87(4), pages 1083-1095, April.
    14. Yin, Xiulian & Ma, Haile & You, Qinghong & Wang, Zhenbin & Chang, Jinke, 2012. "Comparison of four different enhancing methods for preparing biodiesel through transesterification of sunflower oil," Applied Energy, Elsevier, vol. 91(1), pages 320-325.
    15. Shu, Qing & Gao, Jixian & Nawaz, Zeeshan & Liao, Yuhui & Wang, Dezheng & Wang, Jinfu, 2010. "Synthesis of biodiesel from waste vegetable oil with large amounts of free fatty acids using a carbon-based solid acid catalyst," Applied Energy, Elsevier, vol. 87(8), pages 2589-2596, August.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Chia-Hung Su & Hoang Chinh Nguyen & Uyen Khanh Pham & My Linh Nguyen & Horng-Yi Juan, 2018. "Biodiesel Production from a Novel Nonedible Feedstock, Soursop ( Annona muricata L.) Seed Oil," Energies, MDPI, vol. 11(10), pages 1-11, September.
    2. Muhammad, Gul & Potchamyou Ngatcha, Ange Douglas & Lv, Yongkun & Xiong, Wenlong & El-Badry, Yaser A. & Asmatulu, Eylem & Xu, Jingliang & Alam, Md Asraful, 2022. "Enhanced biodiesel production from wet microalgae biomass optimized via response surface methodology and artificial neural network," Renewable Energy, Elsevier, vol. 184(C), pages 753-764.
    3. R, Gopi & Thangarasu, Vinoth & Vinayakaselvi M, Angkayarkan & Ramanathan, Anand, 2022. "A critical review of recent advancements in continuous flow reactors and prominent integrated microreactors for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    4. Vávra, Aleš & Hájek, Martin & Skopal, Frantisek, 2017. "The removal of free fatty acids from methyl ester," Renewable Energy, Elsevier, vol. 103(C), pages 695-700.
    5. Avhad, M.R. & Marchetti, J.M., 2015. "A review on recent advancement in catalytic materials for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 696-718.
    6. Hoang Chinh Nguyen & Dinh Thi My Huong & Horng-Yi Juan & Chia-Hung Su & Chien-Chung Chien, 2018. "Liquid Lipase-Catalyzed Esterification of Oleic Acid with Methanol for Biodiesel Production in the Presence of Superabsorbent Polymer: Optimization by Using Response Surface Methodology," Energies, MDPI, vol. 11(5), pages 1-12, April.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Mazaheri, Hossein, 2013. "A review on novel processes of biodiesel production from waste cooking oil," Applied Energy, Elsevier, vol. 104(C), pages 683-710.
    2. Lian, Shuang & Li, Huijuan & Tang, Jinqiang & Tong, Dongmei & Hu, Changwei, 2012. "Integration of extraction and transesterification of lipid from jatropha seeds for the production of biodiesel," Applied Energy, Elsevier, vol. 98(C), pages 540-547.
    3. Liu, Chien-Hung & Huang, Chien-Chang & Wang, Yao-Wen & Lee, Duu-Jong & Chang, Jo-Shu, 2012. "Biodiesel production by enzymatic transesterification catalyzed by Burkholderia lipase immobilized on hydrophobic magnetic particles," Applied Energy, Elsevier, vol. 100(C), pages 41-46.
    4. Tan, Yie Hua & Abdullah, Mohammad Omar & Nolasco-Hipolito, Cirilo & Taufiq-Yap, Yun Hin, 2015. "Waste ostrich- and chicken-eggshells as heterogeneous base catalyst for biodiesel production from used cooking oil: Catalyst characterization and biodiesel yield performance," Applied Energy, Elsevier, vol. 160(C), pages 58-70.
    5. Li, Yuesong & Lian, Shuang & Tong, Dongmei & Song, Ruili & Yang, Wenyan & Fan, Yong & Qing, Renwei & Hu, Changwei, 2011. "One-step production of biodiesel from Nannochloropsis sp. on solid base Mg–Zr catalyst," Applied Energy, Elsevier, vol. 88(10), pages 3313-3317.
    6. Gong, Shu-wen & Lu, Jing & Wang, Hong-hong & Liu, Li-jun & Zhang, Qian, 2014. "Biodiesel production via esterification of oleic acid catalyzed by picolinic acid modified 12-tungstophosphoric acid," Applied Energy, Elsevier, vol. 134(C), pages 283-289.
    7. Guo, Feng & Xiu, Zhi-Long & Liang, Zhi-Xia, 2012. "Synthesis of biodiesel from acidified soybean soapstock using a lignin-derived carbonaceous catalyst," Applied Energy, Elsevier, vol. 98(C), pages 47-52.
    8. Singh, Veena & Bux, Faizal & Sharma, Yogesh Chandra, 2016. "A low cost one pot synthesis of biodiesel from waste frying oil (WFO) using a novel material, β-potassium dizirconate (β-K2Zr2O5)," Applied Energy, Elsevier, vol. 172(C), pages 23-33.
    9. Dawodu, Folasegun A. & Ayodele, Olubunmi & Xin, Jiayu & Zhang, Suojiang & Yan, Dongxia, 2014. "Effective conversion of non-edible oil with high free fatty acid into biodiesel by sulphonated carbon catalyst," Applied Energy, Elsevier, vol. 114(C), pages 819-826.
    10. Lin, Lin & Cunshan, Zhou & Vittayapadung, Saritporn & Xiangqian, Shen & Mingdong, Dong, 2011. "Opportunities and challenges for biodiesel fuel," Applied Energy, Elsevier, vol. 88(4), pages 1020-1031, April.
    11. Blanco-Marigorta, A.M. & Suárez-Medina, J. & Vera-Castellano, A., 2013. "Exergetic analysis of a biodiesel production process from Jatropha curcas," Applied Energy, Elsevier, vol. 101(C), pages 218-225.
    12. Atadashi, I.M. & Aroua, M.K. & Aziz, A.R. Abdul & Sulaiman, N.M.N., 2011. "Refining technologies for the purification of crude biodiesel," Applied Energy, Elsevier, vol. 88(12), pages 4239-4251.
    13. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Zarei, Alireza & Noshadi, Iman, 2013. "Transesterification of waste cooking oil by heteropoly acid (HPA) catalyst: Optimization and kinetic model," Applied Energy, Elsevier, vol. 102(C), pages 283-292.
    14. Borugadda, Venu Babu & Goud, Vaibhav V., 2012. "Biodiesel production from renewable feedstocks: Status and opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4763-4784.
    15. Zhang, Yue & Wong, Wing-Tak & Yung, Ka-Fu, 2014. "Biodiesel production via esterification of oleic acid catalyzed by chlorosulfonic acid modified zirconia," Applied Energy, Elsevier, vol. 116(C), pages 191-198.
    16. Rathmann, Régis & Szklo, Alexandre & Schaeffer, Roberto, 2012. "Targets and results of the Brazilian Biodiesel Incentive Program – Has it reached the Promised Land?," Applied Energy, Elsevier, vol. 97(C), pages 91-100.
    17. Boonyongmaneerat, Yuttanant & Sukjamsri, Chamaiporn & Sahapatsombut, Ukrit & Saenapitak, Sawalee & Sukkasi, Sittha, 2011. "Investigation of electrodeposited Ni-based coatings for biodiesel storage," Applied Energy, Elsevier, vol. 88(3), pages 909-913, March.
    18. Demirbas, Ayhan, 2011. "Competitive liquid biofuels from biomass," Applied Energy, Elsevier, vol. 88(1), pages 17-28, January.
    19. Yin, Xiulian & Ma, Haile & You, Qinghong & Wang, Zhenbin & Chang, Jinke, 2012. "Comparison of four different enhancing methods for preparing biodiesel through transesterification of sunflower oil," Applied Energy, Elsevier, vol. 91(1), pages 320-325.
    20. Maleki, Esmat & Aroua, Mohamed Kheireddine & Sulaiman, Nik Meriam Nik, 2013. "Improved yield of solvent free enzymatic methanolysis of palm and jatropha oils blended with castor oil," Applied Energy, Elsevier, vol. 104(C), pages 905-909.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:104:y:2013:i:c:p:503-509. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.