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Low-cost catalysts for in-situ improvement of producer gas quality during direct gasification of biomass

Author

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  • Pio, D.T.
  • Tarelho, L.A.C.
  • Pinto, R.G.
  • Matos, M.A.A.
  • Frade, J.R.
  • Yaremchenko, A.
  • Mishra, G.S.
  • Pinto, P.C.R.

Abstract

In this work, the concept of biomass direct (air) gasification was demonstrated in a pilot-scale bubbling fluidized bed and the influence of in-situ application of low-cost catalytic materials on the produced gas characteristics and gasifier performance was analyzed. Three different low-cost catalysts were tested: bottom bed ashes resulting from combustion of residual forest biomass derived from eucalyptus, char particles resulting from wood pellets direct (air) gasification, and synthetic fayalite (Fe2SiO4). Without using catalysts, the produced gas composition was 7.7–16.9%v CO, 3.2–8.3%v H2, 0.5–3.4%v CH4 and 9.5–14.6%v CO2, with 2.4–4.3 MJ/Nm3 lower heating value, specific dry gas production between 1.0 and 1.8 Nm3 dry gas/kg biomass (dry basis), cold gas efficiency between 13.7 and 30.5% and carbon conversion efficiency between 30.7 and 50.9%. With the use of catalysts, the produced gas composition was 14.2–37.6%v CO, 9.5–14.7%v H2, 2.6–3.5%v CH4 and 3.6–14.8%v CO2, with 3.9–6.3 MJ/Nm3 lower heating value, specific dry gas production between 1.4 and 2.0 Nm3 dry gas/kg biomass (dry basis), cold gas efficiency between 38.1 and 66.3% and carbon conversion efficiency between 56.8 and 86.6%. The highest increase in H2 concentration (352% increase) was observed on experiments using wood pellets char as catalyst while the highest increase in CO (305% increase), lower heating value (123% increase), specific dry gas production (62% increase), cold gas efficiency (262% increase) and carbon conversion efficiency (174% increase), was observed on experiments using synthetic Fe2SiO4 as catalyst.

Suggested Citation

  • Pio, D.T. & Tarelho, L.A.C. & Pinto, R.G. & Matos, M.A.A. & Frade, J.R. & Yaremchenko, A. & Mishra, G.S. & Pinto, P.C.R., 2018. "Low-cost catalysts for in-situ improvement of producer gas quality during direct gasification of biomass," Energy, Elsevier, vol. 165(PB), pages 442-454.
    • Handle: RePEc:eee:energy:v:165:y:2018:i:pb:p:442-454
    DOI: 10.1016/j.energy.2018.09.119
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    3. Rey, J.R.C. & Pio, D.T. & Tarelho, L.A.C., 2021. "Biomass direct gasification for electricity generation and natural gas replacement in the lime kilns of the pulp and paper industry: A techno-economic analysis," Energy, Elsevier, vol. 237(C).
    4. Pio, D.T. & Tarelho, L.A.C., 2021. "Industrial gasification systems (>3 MWth) for bioenergy in Europe: Current status and future perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    5. Pio, D.T. & Tarelho, L.A.C., 2020. "Empirical and chemical equilibrium modelling for prediction of biomass gasification products in bubbling fluidized beds," Energy, Elsevier, vol. 202(C).
    6. Pio, D.T. & Gomes, H.G.M.F. & Tarelho, L.A.C. & Vilas-Boas, A.C.M. & Matos, M.A.A. & Lemos, F.M.S., 2022. "Superheated steam injection as primary measure to improve producer gas quality from biomass air gasification in an autothermal pilot-scale gasifier," Renewable Energy, Elsevier, vol. 181(C), pages 1223-1236.
    7. Helena G. M. F. Gomes & Manuel A. A. Matos & Luís A. C. Tarelho, 2023. "Influence of Oxygen/Steam Addition on the Quality of Producer Gas during Direct (Air) Gasification of Residual Forest Biomass," Energies, MDPI, vol. 16(5), pages 1-20, March.
    8. Pio, D.T. & Tarelho, L.A.C. & Pinto, P.C.R., 2020. "Gasification-based biorefinery integration in the pulp and paper industry: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 133(C).
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