IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v230y2018icp1573-1584.html
   My bibliography  Save this article

Numerical model of planar anode supported solid oxide fuel cell fed with fuel containing H2S operated in direct internal reforming mode (DIR-SOFC)

Author

Listed:
  • Kupecki, Jakub
  • Papurello, Davide
  • Lanzini, Andrea
  • Naumovich, Yevgeniy
  • Motylinski, Konrad
  • Blesznowski, Marcin
  • Santarelli, Massimo

Abstract

Experimental analysis of a planar 100 mm × 100 mm SOFC cell was conducted during operation at 1173 K in direct internal reforming (DIR) mode. In the first phase the rate of direct internal reforming was varied from 0 to 100% what corresponds to complete external reforming and complete DIR, respectively. In the second phase 1.2 ppm(v) of H2S was introduced to the feeding gas and the variation of the rate of direct internal reforming was repeated. Following the experimental analysis the numerical model was proposed to determine the correlation between the presence of the poisoning agent and the electrochemical performance. The effect on the resistance of the cell was studied. The lumped volume model was applied to predict the cell voltage. With the use of the experimental data it was possible to determine the relative change of the model parameters which describe the ionic and electronic conductivity of the SOFC. Model was adopted for predictive modeling of the solid oxide fuel cell, operated in DIR-SOFC mode with and without the presence of hydrogen sulfide. Additionally, literature data measured for a cell operated in complete internal reforming mode with variation of the sulfur content in the feeding gas were analyzed to define the effect of H2S content on the performance drop. Relative change of the resistance of a cell was correlated with the rate of internal reforming and the content of sulfur.

Suggested Citation

  • Kupecki, Jakub & Papurello, Davide & Lanzini, Andrea & Naumovich, Yevgeniy & Motylinski, Konrad & Blesznowski, Marcin & Santarelli, Massimo, 2018. "Numerical model of planar anode supported solid oxide fuel cell fed with fuel containing H2S operated in direct internal reforming mode (DIR-SOFC)," Applied Energy, Elsevier, vol. 230(C), pages 1573-1584.
    • Handle: RePEc:eee:appene:v:230:y:2018:i:c:p:1573-1584
    DOI: 10.1016/j.apenergy.2018.09.092
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S030626191831403X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2018.09.092?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Lyu, Zewei & Shi, Wangying & Han, Minfang, 2018. "Electrochemical characteristics and carbon tolerance of solid oxide fuel cells with direct internal dry reforming of methane," Applied Energy, Elsevier, vol. 228(C), pages 556-567.
    2. Ud Din, Zia & Zainal, Z.A., 2017. "The fate of SOFC anodes under biomass producer gas contaminants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 1050-1066.
    3. Papurello, Davide & Lanzini, Andrea & Drago, Davide & Leone, Pierluigi & Santarelli, Massimo, 2016. "Limiting factors for planar solid oxide fuel cells under different trace compound concentrations," Energy, Elsevier, vol. 95(C), pages 67-78.
    4. Kupecki, Jakub & Motylinski, Konrad & Milewski, Jaroslaw, 2018. "Dynamic analysis of direct internal reforming in a SOFC stack with electrolyte-supported cells using a quasi-1D model," Applied Energy, Elsevier, vol. 227(C), pages 198-205.
    5. Papurello, Davide & Lanzini, Andrea & Tognana, Lorenzo & Silvestri, Silvia & Santarelli, Massimo, 2015. "Waste to energy: Exploitation of biogas from organic waste in a 500 Wel solid oxide fuel cell (SOFC) stack," Energy, Elsevier, vol. 85(C), pages 145-158.
    6. Erdinc, Ozan & Paterakis, Nikolaos G. & Catalão, João P.S., 2015. "Overview of insular power systems under increasing penetration of renewable energy sources: Opportunities and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 333-346.
    7. Seungdoo Park & John M. Vohs & Raymond J. Gorte, 2000. "Direct oxidation of hydrocarbons in a solid-oxide fuel cell," Nature, Nature, vol. 404(6775), pages 265-267, March.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Königshofer, Benjamin & Boškoski, Pavle & Nusev, Gjorgji & Koroschetz, Markus & Hochfellner, Martin & Schwaiger, Marcel & Juričić, Đani & Hochenauer, Christoph & Subotić, Vanja, 2021. "Performance assessment and evaluation of SOC stacks designed for application in a reversible operated 150 kW rSOC power plant," Applied Energy, Elsevier, vol. 283(C).
    2. Szczęśniak, Arkadiusz & Milewski, Jarosław & Szabłowski, Łukasz & Bujalski, Wojciech & Dybiński, Olaf, 2020. "Dynamic model of a molten carbonate fuel cell 1 kW stack," Energy, Elsevier, vol. 200(C).
    3. Wang, Chao & Liao, Mingzheng & Liang, Bo & Jiang, Zhiqiang & Zhong, Weilin & Chen, Ying & Luo, Xianglong & Shu, Riyang & Tian, Zhipeng & Lei, Libin, 2021. "Enhancement effect of catalyst support on indirect hydrogen production from propane partial oxidation towards commercial solid oxide fuel cell (SOFC) applications," Applied Energy, Elsevier, vol. 288(C).
    4. Zarabi Golkhatmi, Sanaz & Asghar, Muhammad Imran & Lund, Peter D., 2022. "A review on solid oxide fuel cell durability: Latest progress, mechanisms, and study tools," Renewable and Sustainable Energy Reviews, Elsevier, vol. 161(C).
    5. Preininger, Michael & Stoeckl, Bernhard & Subotić, Vanja & Mittmann, Frank & Hochenauer, Christoph, 2019. "Performance of a ten-layer reversible Solid Oxide Cell stack (rSOC) under transient operation for autonomous application," Applied Energy, Elsevier, vol. 254(C).
    6. Tomasz Banaszkiewicz & Maciej Chorowski & Wojciech Gizicki & Artur Jedrusyna & Jakub Kielar & Ziemowit Malecha & Agnieszka Piotrowska & Jaroslaw Polinski & Zbigniew Rogala & Korneliusz Sierpowski & Ja, 2020. "Liquefied Natural Gas in Mobile Applications—Opportunities and Challenges," Energies, MDPI, vol. 13(21), pages 1-35, October.
    7. Sean O’Connor & Ehiaze Ehimen & Suresh C. Pillai & Gary Lyons & John Bartlett, 2020. "Economic and Environmental Analysis of Small-Scale Anaerobic Digestion Plants on Irish Dairy Farms," Energies, MDPI, vol. 13(3), pages 1-20, February.
    8. Dai, Huidong & Besser, R.S., 2022. "Understanding hydrogen sulfide impact on a portable, commercial, propane-powered solid-oxide fuel cell," Applied Energy, Elsevier, vol. 307(C).
    9. Guk, Erdogan & Ranaweera, Manoj & Venkatesan, Vijay & Kim, Jung-Sik & Jung, WooChul, 2020. "In-situ temperature monitoring directly from cathode surface of an operating solid oxide fuel cell," Applied Energy, Elsevier, vol. 280(C).
    10. Wang, Yang & Wu, Chengru & Zhao, Siyuan & Wang, Jian & Zu, Bingfeng & Han, Minfang & Du, Qing & Ni, Meng & Jiao, Kui, 2022. "Coupling deep learning and multi-objective genetic algorithms to achieve high performance and durability of direct internal reforming solid oxide fuel cell," Applied Energy, Elsevier, vol. 315(C).
    11. Pongratz, G. & Subotić, V. & Schroettner, H. & Hochenauer, C. & Skrzypkiewicz, M. & Kupecki, Jakub & Anca-Couce, A. & Scharler, R., 2021. "Analysis of H2S-related short-term degradation and regeneration of anode- and electrolyte supported solid oxide fuel cells fueled with biomass steam gasifier product gas," Energy, Elsevier, vol. 218(C).
    12. Wu, Xiao-long & Xu, Yuan-Wu & Xue, Tao & Zhao, Dong-qi & Jiang, Jianhua & Deng, Zhonghua & Fu, Xiaowei & Li, Xi, 2019. "Health state prediction and analysis of SOFC system based on the data-driven entire stage experiment," Applied Energy, Elsevier, vol. 248(C), pages 126-140.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Fan, Liyuan & Li, Chao'en & van Biert, Lindert & Zhou, Shou-Han & Tabish, Asif Nadeem & Mokhov, Anatoli & Aravind, Purushothaman Vellayani & Cai, Weiwei, 2022. "Advances on methane reforming in solid oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 166(C).
    2. Abdelkareem, Mohammad Ali & Tanveer, Waqas Hassan & Sayed, Enas Taha & Assad, M. El Haj & Allagui, Anis & Cha, S.W., 2019. "On the technical challenges affecting the performance of direct internal reforming biogas solid oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 101(C), pages 361-375.
    3. Tanveer, Waqas Hassan & Rezk, Hegazy & Nassef, Ahmed & Abdelkareem, Mohammad Ali & Kolosz, Ben & Karuppasamy, K. & Aslam, Jawad & Gilani, Syed Omer, 2020. "Improving fuel cell performance via optimal parameters identification through fuzzy logic based-modeling and optimization," Energy, Elsevier, vol. 204(C).
    4. Papurello, Davide & Chiodo, Vitaliano & Maisano, Susanna & Lanzini, Andrea & Santarelli, Massimo, 2018. "Catalytic stability of a Ni-Catalyst towards biogas reforming in the presence of deactivating trace compounds," Renewable Energy, Elsevier, vol. 127(C), pages 481-494.
    5. Rayner, Addison J. & Briggs, Johnathan & Tremback, Reed & Clemmer, Ryan M.C., 2017. "Design of an organic waste power plant coupling anaerobic digestion and solid oxide fuel cell technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 563-571.
    6. Papurello, Davide & Iafrate, Chiara & Lanzini, Andrea & Santarelli, Massimo, 2017. "Trace compounds impact on SOFC performance: Experimental and modelling approach," Applied Energy, Elsevier, vol. 208(C), pages 637-654.
    7. Papurello, Davide & Boschetti, Andrea & Silvestri, Silvia & Khomenko, Iuliia & Biasioli, Franco, 2018. "Real-time monitoring of removal of trace compounds with PTR-MS: Biochar experimental investigation," Renewable Energy, Elsevier, vol. 125(C), pages 344-355.
    8. Giovanni Coppola & Davide Papurello, 2018. "Biogas Cleaning: Activated Carbon Regeneration for H 2 S Removal," Clean Technol., MDPI, vol. 1(1), pages 1-18, June.
    9. Mehran, Muhammad Taqi & Khan, Muhammad Zubair & Song, Rak-Hyun & Lim, Tak-Hyoung & Naqvi, Muhammad & Raza, Rizwan & Zhu, Bin & Hanif, Muhammad Bilal, 2023. "A comprehensive review on durability improvement of solid oxide fuel cells for commercial stationary power generation systems," Applied Energy, Elsevier, vol. 352(C).
    10. Davide Papurello & Massimo Santarelli & Sonia Fiorilli, 2018. "Physical Activation of Waste-Derived Materials for Biogas Cleaning," Energies, MDPI, vol. 11(9), pages 1-12, September.
    11. Papurello, Davide & Lanzini, Andrea & Leone, Pierluigi & Santarelli, Massimo, 2016. "The effect of heavy tars (toluene and naphthalene) on the electrochemical performance of an anode-supported SOFC running on bio-syngas," Renewable Energy, Elsevier, vol. 99(C), pages 747-753.
    12. Briguglio, Marie & Formosa, Glenn, 2017. "When households go solar: Determinants of uptake of a Photovoltaic Scheme and policy insights," Energy Policy, Elsevier, vol. 108(C), pages 154-162.
    13. Wen, Xin & Abbes, Dhaker & Francois, Bruno, 2021. "Modeling of photovoltaic power uncertainties for impact analysis on generation scheduling and cost of an urban micro grid," Mathematics and Computers in Simulation (MATCOM), Elsevier, vol. 183(C), pages 116-128.
    14. Segurado, R. & Madeira, J.F.A. & Costa, M. & Duić, N. & Carvalho, M.G., 2016. "Optimization of a wind powered desalination and pumped hydro storage system," Applied Energy, Elsevier, vol. 177(C), pages 487-499.
    15. Psarros, Georgios N. & Papathanassiou, Stavros A., 2023. "Generation scheduling in island systems with variable renewable energy sources: A literature review," Renewable Energy, Elsevier, vol. 205(C), pages 1105-1124.
    16. Polleux, Louis & Guerassimoff, Gilles & Marmorat, Jean-Paul & Sandoval-Moreno, John & Schuhler, Thierry, 2022. "An overview of the challenges of solar power integration in isolated industrial microgrids with reliability constraints," Renewable and Sustainable Energy Reviews, Elsevier, vol. 155(C).
    17. Andrychowicz, Mateusz & Olek, Blazej & Przybylski, Jakub, 2017. "Review of the methods for evaluation of renewable energy sources penetration and ramping used in the Scenario Outlook and Adequacy Forecast 2015. Case study for Poland," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 703-714.
    18. Silverman, Rochelle E. & Flores, Robert J. & Brouwer, Jack, 2020. "Energy and economic assessment of distributed renewable gas and electricity generation in a small disadvantaged urban community," Applied Energy, Elsevier, vol. 280(C).
    19. Georg Göhler & Anna-Lena Klingler & Florian Klausmann & Dieter Spath, 2021. "Integrated Modelling of Decentralised Energy Supply in Combination with Electric Vehicle Charging in a Real-Life Case Study," Energies, MDPI, vol. 14(21), pages 1-19, October.
    20. Yu, Fangyong & Xiao, Jie & Zhang, Yapeng & Cai, Weizi & Xie, Yongmin & Yang, Naitao & Liu, Jiang & Liu, Meilin, 2019. "New insights into carbon deposition mechanism of nickel/yttrium-stabilized zirconia cermet from methane by in situ investigation," Applied Energy, Elsevier, vol. 256(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:230:y:2018:i:c:p:1573-1584. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.