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Catalytic fast pyrolysis of waste pepper stems over HZSM-5

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  • Park, Young-Kwon
  • Yoo, Myung Lang
  • Jin, Sung Ho
  • Park, Sung Hoon

Abstract

Catalytic fast pyrolysis over HZSM-5 of red pepper stems, a representative agricultural residue material in the southern area of South Korea, was carried out. The SiO2/Al2O3 ratio of the catalyst were 23 and 280. Pyrolysis-gas chromatography/mass spectrometry was used to pyrolyze the pepper stem samples at 550 °C and directly analyze the product distribution. The main product species of the non-catalytic pyrolysis of pepper stems were phenolics, followed by oxygenates and acids. The production of aliphatic and aromatic hydrocarbons was marginal. On the contrary, catalytic pyrolysis over HZSM-5 reduced the fractions of phenolics and acids significantly, while considerably increasing the fractions of aliphatic and aromatic hydrocarbons. The catalytic activity of the HZSM-5 with a SiO2/Al2O3 ratio of 23 was much higher, owing to its much larger amount of strong Brønsted acid sites, than the one with a SiO2/Al2O3 ratio of 280. Conversion of carbohydrate via furans to aromatics over strong acid sites was observed, which was in good agreement with previous studies. This study suggests that the catalytic pyrolysis of lignin-rich biomass over acidic zeolite catalysts can be a promising method to produce valuable chemicals such as aromatic compounds.

Suggested Citation

  • Park, Young-Kwon & Yoo, Myung Lang & Jin, Sung Ho & Park, Sung Hoon, 2015. "Catalytic fast pyrolysis of waste pepper stems over HZSM-5," Renewable Energy, Elsevier, vol. 79(C), pages 20-27.
    • Handle: RePEc:eee:renene:v:79:y:2015:i:c:p:20-27
    DOI: 10.1016/j.renene.2014.10.005
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    References listed on IDEAS

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    1. Choi, Suek Joo & Park, Sung Hoon & Jeon, Jong-Ki & Lee, In Gu & Ryu, Changkook & Suh, Dong Jin & Park, Young-Kwon, 2013. "Catalytic conversion of particle board over microporous catalysts," Renewable Energy, Elsevier, vol. 54(C), pages 105-110.
    2. Park, Young-Kwon & Yoo, Myung Lang & Lee, Hyung Won & Park, Sung Hoon & Jung, Sang-Chul & Park, Sang-Sook & Kim, Sang-Chai, 2012. "Effects of operation conditions on pyrolysis characteristics of agricultural residues," Renewable Energy, Elsevier, vol. 42(C), pages 125-130.
    3. Kim, Jeong Wook & Lee, Hyung Won & Lee, In-Gu & Jeon, Jong-Ki & Ryu, Changkook & Park, Sung Hoon & Jung, Sang-Chul & Park, Young-Kwon, 2014. "Influence of reaction conditions on bio-oil production from pyrolysis of construction waste wood," Renewable Energy, Elsevier, vol. 65(C), pages 41-48.
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    Cited by:

    1. Balasundram, Vekes & Ibrahim, Norazana & Kasmani, Rafiziana Md. & Isha, Ruzinah & Hamid, Mohd. Kamaruddin Abd. & Hasbullah, Hasrinah & Ali, Roshafima Rasit, 2018. "Catalytic upgrading of sugarcane bagasse pyrolysis vapours over rare earth metal (Ce) loaded HZSM-5: Effect of catalyst to biomass ratio on the organic compounds in pyrolysis oil," Applied Energy, Elsevier, vol. 220(C), pages 787-799.
    2. Chaihad, Nichaboon & Situmorang, Yohanes Andre & Anniwaer, Aisikaer & Kurnia, Irwan & Karnjanakom, Surachai & Kasai, Yutaka & Abudula, Abuliti & Reubroycharoen, Prasert & Guan, Guoqing, 2021. "Preparation of various hierarchical HZSM-5 based catalysts for in-situ fast upgrading of bio-oil," Renewable Energy, Elsevier, vol. 169(C), pages 283-292.
    3. Ozbay, Nurgul & Yargic, Adife Seyda & Yarbay Sahin, Rahmiye Zerrin & Yaman, Elif, 2019. "Valorization of banana peel waste via in-situ catalytic pyrolysis using Al-Modified SBA-15," Renewable Energy, Elsevier, vol. 140(C), pages 633-646.
    4. Das, Bikashbindu & Mohanty, Kaustubha, 2019. "A review on advances in sustainable energy production through various catalytic processes by using catalysts derived from waste red mud," Renewable Energy, Elsevier, vol. 143(C), pages 1791-1811.
    5. Isah Yakub Mohammed & Feroz Kabir Kazi & Suzana Yusup & Peter Adeniyi Alaba & Yahaya Muhammad Sani & Yousif Abdalla Abakr, 2016. "Catalytic Intermediate Pyrolysis of Napier Grass in a Fixed Bed Reactor with ZSM-5, HZSM-5 and Zinc-Exchanged Zeolite-A as the Catalyst," Energies, MDPI, vol. 9(4), pages 1-17, March.
    6. Ly, Hoang Vu & Park, Jeong Woo & Kim, Seung-Soo & Hwang, Hyun Tae & Kim, Jinsoo & Woo, Hee Chul, 2020. "Catalytic pyrolysis of bamboo in a bubbling fluidized-bed reactor with two different catalysts: HZSM-5 and red mud for upgrading bio-oil," Renewable Energy, Elsevier, vol. 149(C), pages 1434-1445.

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