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Biodiesel production from refined coconut oil using hydroxide-impregnated calcium oxide by cosolvent method

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  • Bambase, Manolito E.
  • Almazan, Rober Angelo R.
  • Demafelis, Rex B.
  • Sobremisana, Marisa J.
  • Dizon, Lisa Stephanie H.

Abstract

The use of OH-impregnated CaO as heterogeneous catalyst in the conversion of refined coconut oil into crude biodiesel was investigated in this study. Wet impregnation method was used to study the effects of NaOH concentration (10–20% (w/v) solution), calcination temperature (550 °C–700 °C), and calcination time (2–5.5 h). Characterization of the OH-impregnated CaO catalyst was done using XRD, FTIR, and SEM. Conversion of refined coconut oil into biodiesel was performed via transesterification with methanol at 60 °C using OH-impregnated CaO as catalyst. Results show that a 66.36% conversion to biodiesel can be achieved in 10 min when 20% (w/v) NaOH solution was used during impregnation with calcination at 600 °C for 2 h. Addition of tetrahydrofuran as cosolvent increased the conversion further to 81.70% which is comparable to the 85.98% achieved when using NaOH as a catalyst under the same reaction conditions.

Suggested Citation

  • Bambase, Manolito E. & Almazan, Rober Angelo R. & Demafelis, Rex B. & Sobremisana, Marisa J. & Dizon, Lisa Stephanie H., 2021. "Biodiesel production from refined coconut oil using hydroxide-impregnated calcium oxide by cosolvent method," Renewable Energy, Elsevier, vol. 163(C), pages 571-578.
  • Handle: RePEc:eee:renene:v:163:y:2021:i:c:p:571-578
    DOI: 10.1016/j.renene.2020.08.115
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    References listed on IDEAS

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    1. Borges, M.E. & Díaz, L., 2012. "Recent developments on heterogeneous catalysts for biodiesel production by oil esterification and transesterification reactions: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2839-2849.
    2. Marinković, Dalibor M. & Stanković, Miroslav V. & Veličković, Ana V. & Avramović, Jelena M. & Miladinović, Marija R. & Stamenković, Olivera O. & Veljković, Vlada B. & Jovanović, Dušan M., 2016. "Calcium oxide as a promising heterogeneous catalyst for biodiesel production: Current state and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 1387-1408.
    3. Mutreja, Vishal & Singh, Satnam & Ali, Amjad, 2011. "Biodiesel from mutton fat using KOH impregnated MgO as heterogeneous catalysts," Renewable Energy, Elsevier, vol. 36(8), pages 2253-2258.
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    2. Yano Surya Pradana & I Gusti B. N. Makertihartha & Antonius Indarto & Tirto Prakoso & Tatang Hernas Soerawidjaja, 2024. "A Review of Biodiesel Cold Flow Properties and Its Improvement Methods: Towards Sustainable Biodiesel Application," Energies, MDPI, vol. 17(18), pages 1-43, September.
    3. Haris Mahmood Khan & Tanveer Iqbal & Saima Yasin & Muhammad Irfan & Muhammad Mujtaba Abbas & Ibham Veza & Manzoore Elahi M. Soudagar & Anas Abdelrahman & Md. Abul Kalam, 2022. "Heterogeneous Catalyzed Biodiesel Production Using Cosolvent: A Mini Review," Sustainability, MDPI, vol. 14(9), pages 1-11, April.
    4. Mamdouh T. Ghannam & Mohamed Y. E. Selim, 2021. "Rheological Properties of the Jojoba Biofuel," Sustainability, MDPI, vol. 13(11), pages 1-12, May.
    5. Loh, Jun Mann & Amelia, & Gourich, Wail & Chew, Chien Lye & Song, Cher Pin & Chan, Eng-Seng, 2021. "Improved biodiesel production from sludge palm oil catalyzed by a low-cost liquid lipase under low-input process conditions," Renewable Energy, Elsevier, vol. 177(C), pages 348-358.

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