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Investigation on the hydrogen production by methanol aqueous phase reforming over Pt/CexMg1-xO2 catalyst: Synergistic effect of support basicity and oxygen vacancies

Author

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  • Tian, Zhipeng
  • Lu, Yongheng
  • Zhang, Weijie
  • Shu, Riyang
  • Luo, Xianglong
  • Song, Qingbin
  • Lei, Libin
  • Wang, Chao
  • Chen, Ying
  • Ma, Longlong

Abstract

Green hydrogen production from biomass oxygenated derivatives (methanol, ethanol, ethylene glycol, etc.) by low temperature aqueous phase reforming (APR) has the advantages of high hydrogen selectivity and low energy consumption. A series of CexMg1-xO2 mixed oxide supported catalysts were synthesized by a simple citric acid combustion method. The results show that these catalysts exhibit excellent water-gas shift reaction activity and CO is rarely detected in the products, which is due to their abundant oxygen vacancies of the mixed oxide supports of the Pt/CexMg1-xO2 catalysts. At the same time, the introduction of MgO provides more strong basic sites on the surface of mixed oxide support, and the methanol conversion and hydrogen yield show a volcano peak with the increasing number of basic sites and the hydrogen production reaches the highest (127.16 mmol) over Pt/Ce0·5Mg0·5O2 catalyst. The mixed oxide supported Pt/Ce0·5Mg0·5O2 catalyst enjoys the benefits of both oxygen vacancies in accelerating H2O adsorption/dissociation and strong basic sites in contributing to the formation of formate group (HCOO*), which improve the oxidation of CO* and APR activity. This synergistic effect is conducive to improve hydrogen yield of methanol APR and reduce CO selectivity to a minimum level.

Suggested Citation

  • Tian, Zhipeng & Lu, Yongheng & Zhang, Weijie & Shu, Riyang & Luo, Xianglong & Song, Qingbin & Lei, Libin & Wang, Chao & Chen, Ying & Ma, Longlong, 2024. "Investigation on the hydrogen production by methanol aqueous phase reforming over Pt/CexMg1-xO2 catalyst: Synergistic effect of support basicity and oxygen vacancies," Renewable Energy, Elsevier, vol. 230(C).
    • Handle: RePEc:eee:renene:v:230:y:2024:i:c:s0960148124008759
    DOI: 10.1016/j.renene.2024.120807
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    1. Lili Lin & Wu Zhou & Rui Gao & Siyu Yao & Xiao Zhang & Wenqian Xu & Shijian Zheng & Zheng Jiang & Qiaolin Yu & Yong-Wang Li & Chuan Shi & Xiao-Dong Wen & Ding Ma, 2017. "Low-temperature hydrogen production from water and methanol using Pt/α-MoC catalysts," Nature, Nature, vol. 544(7648), pages 80-83, April.
    2. R. D. Cortright & R. R. Davda & J. A. Dumesic, 2002. "Hydrogen from catalytic reforming of biomass-derived hydrocarbons in liquid water," Nature, Nature, vol. 418(6901), pages 964-967, August.
    3. Guo, Yong & Azmat, Muhammad Usman & Liu, Xiaohui & Wang, Yanqin & Lu, Guanzhong, 2012. "Effect of support’s basic properties on hydrogen production in aqueous-phase reforming of glycerol and correlation between WGS and APR," Applied Energy, Elsevier, vol. 92(C), pages 218-223.
    4. Menezes, André O. & Rodrigues, Michelly T. & Zimmaro, Adriana & Borges, Luiz E.P. & Fraga, Marco A., 2011. "Production of renewable hydrogen from aqueous-phase reforming of glycerol over Pt catalysts supported on different oxides," Renewable Energy, Elsevier, vol. 36(2), pages 595-599.
    5. Eugenio Meloni & Marco Martino & Giuseppina Iervolino & Concetta Ruocco & Simona Renda & Giovanni Festa & Vincenzo Palma, 2022. "The Route from Green H 2 Production through Bioethanol Reforming to CO 2 Catalytic Conversion: A Review," Energies, MDPI, vol. 15(7), pages 1-36, March.
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    1. Jiang, Daxin & Lin, Min & Yan, Yuhao & Zhan, Lulu & Li, Rui & Wu, Yulong, 2024. "The influence of CeO2 different morphologies effects on hydrodeoxygenation for guaiacol on Ni/CeO2 catalysts," Renewable Energy, Elsevier, vol. 237(PB).

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