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Aqueous phase reforming (APR) of glycerol over platinum supported on Al2O3 catalyst

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  • Seretis, A.
  • Tsiakaras, P.

Abstract

The glycerol's APR reaction over 5% Pt/Al2O3 catalyst for H2 production in a batch reactor is investigated in the present work. The effect of the operating parameters, such as the: i) reaction time, ii) operating temperature, iii) glycerol concentration and iv) catalyst concentration on: a) the gaseous and liquid products selectivity, b) the glycerol's conversion and c) the H2 yield is investigated. Initially, the glycerol's APR is studied at various temperature (200, 220, 240 °C) and reaction time (30, 60, 120, 240 min), using 1 wt.% or 10 wt.% glycerol solution and 0.5, 1, 2.5 g of 5% Pt/Al2O3 catalyst weight.

Suggested Citation

  • Seretis, A. & Tsiakaras, P., 2016. "Aqueous phase reforming (APR) of glycerol over platinum supported on Al2O3 catalyst," Renewable Energy, Elsevier, vol. 85(C), pages 1116-1126.
    • Handle: RePEc:eee:renene:v:85:y:2016:i:c:p:1116-1126
    DOI: 10.1016/j.renene.2015.07.068
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    References listed on IDEAS

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    Cited by:

    1. Bastan, Farzad & Kazemeini, Mohammad & Larimi, Afsaneh Sadat, 2017. "Aqueous-phase reforming of glycerol for production of alkanes over Ni/CexZr1-xO2 nano-catalyst: Effects of the support’s composition," Renewable Energy, Elsevier, vol. 108(C), pages 417-424.
    2. Kim, Min-Cheol & Kim, Tae-Wan & Kim, Hyung Ju & Kim, Chul-Ung & Bae, Jong Wook, 2016. "Aqueous phase reforming of polyols for hydrogen production using supported PtFe bimetallic catalysts," Renewable Energy, Elsevier, vol. 95(C), pages 396-403.
    3. Liu, Dashuai & Dou, Binlin & Zhang, Hua & Zhao, Longfei & Wu, Kai & Zeng, Pingchao & Chen, Haisheng & Xu, Yujie, 2022. "Comparison of gelatinous and calcined magnesia supported Ni or/and Co-based catalysts for aqueous phase reforming of glycerol," Renewable Energy, Elsevier, vol. 186(C), pages 656-666.
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    5. Justicia, Jéssica & Alberto Baeza, José & de Oliveira, Adriana S. & Calvo, Luisa & Heras, Francisco & Gilarranz, Miguel A., 2022. "Aqueous-phase reforming of water-soluble compounds from pyrolysis bio-oils," Renewable Energy, Elsevier, vol. 199(C), pages 895-907.

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