IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v179y2021icp1262-1270.html
   My bibliography  Save this article

Promotional effect of F for Pd/HZSM-5 catalyst on selective HDO of biobased ketones

Author

Listed:
  • Jiang, Jingyun
  • Ding, Wentao
  • Li, Hao

Abstract

In this work, fluorine-enhanced Pd/HZSM-5 catalyst was synthesized for selective hydrodeoxygenation of biomass derived ketones by using polymethylhydrosiloxane (PMHS) as the hydrogen source under mild conditions. According to characterizations, the highly electronegative F can replace the OH group on the HZSM-5 to form a special F-Al structure over the Pd/HZSM-5 catalyst, thereby the surface morphology, hydrophobicity, acidity and electronic character of Pd/HZSM-5 catalyst can be regulated by the amount of fluorine doping. The Pd-F/HZSM-5(5) catalyst with F-doping at 5 wt% exhibited the best catalytic activity and water-resistance for acetophenone hydrodeoxygenation among a series of Pd-based catalysts, achieving >99% yield and 93.7% yield toward ethylbenzene at 65 °C for 3 h in ethanol and in 95 vt% ethanol, respectively. The F-Al structure formed by the F modification replaces the -OH on the HZSM-5, which inhibited the adsorption to water on the metal active site of the catalyst, thus effectively improving the catalytic performance for selective hydrodeoxygenation of biomass-derived ketones. In addition, the as-prepared Pd-F/HZSM-5(5) catalyst with an excellent circulation capability after 5 times use, and the >90% yield of deoxidation production can be obtained for the HDO of various biomass-derived ketones.

Suggested Citation

  • Jiang, Jingyun & Ding, Wentao & Li, Hao, 2021. "Promotional effect of F for Pd/HZSM-5 catalyst on selective HDO of biobased ketones," Renewable Energy, Elsevier, vol. 179(C), pages 1262-1270.
    • Handle: RePEc:eee:renene:v:179:y:2021:i:c:p:1262-1270
    DOI: 10.1016/j.renene.2021.07.065
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148121010703
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2021.07.065?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Fan, Xu-dong & Wu, Yu-jian & Li, Zhi-yu & Sun, Yan & Tu, Ren & Zhong, Pei-Dong & Jiang, En-chen & Xu, Xi-wei, 2020. "Benzene, toluene and xylene (BTX) from in-situ gas phase hydrodeoxygenation of guaiacol with liquid hydrogen donor over bifunctional non-noble-metal zeolite catalysts," Renewable Energy, Elsevier, vol. 152(C), pages 1391-1402.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Goyal, Reena & Abraham, B. Moses & Singh, Omvir & Sameer, Siddharth & Bal, Rajaram & Mondal, Prasenjit, 2022. "One-pot transformation of glucose into hydroxymethyl furfural in water over Pd decorated acidic ZrO2," Renewable Energy, Elsevier, vol. 183(C), pages 791-801.
    2. Yu, Yixuan & Liu, Huai & Zhang, Junhua & Zhang, Heng & Sun, Yong & Peng, Lincai, 2023. "Highly efficient, amorphous bimetal Ni-Fe borides-catalyzed hydrogenolysis of 5-hydroxymethylfurfural into 2,5-dimethylfuran," Renewable Energy, Elsevier, vol. 209(C), pages 453-461.
    3. Li, Tong & Li, Hao & Li, Chunli, 2022. "Self-support semi-hollow carbon nanosphere supported palladium catalyst for biomass upgrading," Renewable Energy, Elsevier, vol. 191(C), pages 101-109.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Gao, Xueying & Li, Helong & Wang, Shuizhong & Liu, Zhenzhen & Ma, Jian-feng & Liu, Xing-e & Song, Guoyong, 2022. "Hydrodeoxygenation of lignin biophenolics to cyclohexanes over sub-nanometric Ru multifunctional catalyst," Renewable Energy, Elsevier, vol. 201(P1), pages 724-733.
    2. Tai, Lingyu & Hamidi, Roya & de Caprariis, Benedetta & Damizia, Martina & Paglia, Laura & Scarsella, Marco & Karimzadeh, Ramin & De Filippis, Paolo, 2022. "Guaiacol hydrotreating with in-situ generated hydrogen over ni/modified zeolite supports," Renewable Energy, Elsevier, vol. 182(C), pages 647-658.
    3. Fan, Xu-dong & Wu, Yu-jian & Tu, Ren & Sun, Yan & Jiang, En-chen & Xu, Xi-wei, 2020. "Hydrodeoxygenation of guaiacol via rice husk char supported Ni based catalysts: The influence of char supports," Renewable Energy, Elsevier, vol. 157(C), pages 1035-1045.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:179:y:2021:i:c:p:1262-1270. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.