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Electrolytic transesterification of waste cooking oil using magnetic Co/Fe–Ca based catalyst derived from waste shells: A promising approach towards sustainable biodiesel production

Author

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  • Xia, Shaige
  • Hu, Yongjie
  • Chen, Chao
  • Tao, Junyu
  • Yan, Beibei
  • Li, Wanqing
  • Zhu, Guangbin
  • Cheng, Zhanjun
  • Chen, Guanyi

Abstract

Biodiesel production is a promising approach to producing renewable liquid fuel and disposing of waste cooking oil (WCO). While the high energy consumption during the conventional thermal transesterification process and the difficulty of reusing the transesterification catalyst are two important factors affecting its development. In this research, biodiesel production by electrolytic transesterification of WCO using reusable magnetic waste shells derived Co/Fe–Ca based catalysts were evaluated. Catalysts were prepared by one-step hydrothermal method. Their properties were characterized by XRD, SEM, XPS, etc, catalytic performances were investigated, and catalytic mechanisms were also explored. Response surface methodology (RSM) based on the Box-Behnken design (BBD) approach was used to optimize the electrolytic transesterification parameters and investigate the interactions of independent parameters. An optimal Fatty acid methyl ester (FAME) content of 92.12% was obtained under a 12:1 methanol to oil molar ratio, 0.25 wt% catalyst dosage, and 29 V electrolytic voltage for 50 min at room temperature. The conversion of WCO is more dependent on electrolytic voltage as compared to the other parameters. And the reaction time has been significantly decreased, energy efficiency was effectively improved compared to conventional thermal catalytic transesterification. Moreover, the WCO biodiesel properties were measured and they all met the ASTM standard. It's hoped that the results of this work could promisingly benefit the sustainable biodiesel production and disposal of WCO.

Suggested Citation

  • Xia, Shaige & Hu, Yongjie & Chen, Chao & Tao, Junyu & Yan, Beibei & Li, Wanqing & Zhu, Guangbin & Cheng, Zhanjun & Chen, Guanyi, 2022. "Electrolytic transesterification of waste cooking oil using magnetic Co/Fe–Ca based catalyst derived from waste shells: A promising approach towards sustainable biodiesel production," Renewable Energy, Elsevier, vol. 200(C), pages 1286-1299.
  • Handle: RePEc:eee:renene:v:200:y:2022:i:c:p:1286-1299
    DOI: 10.1016/j.renene.2022.10.071
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    1. Mardhiah, H. Haziratul & Ong, Hwai Chyuan & Masjuki, H.H. & Lim, Steven & Lee, H.V., 2017. "A review on latest developments and future prospects of heterogeneous catalyst in biodiesel production from non-edible oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 1225-1236.
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    1. Yadav, Nidhi & Yadav, Gaurav & Ahmaruzzaman, Md., 2023. "Fabrication of surface-modified dual waste-derived biochar for biodiesel production by microwave-assisted esterification of oleic acid: Optimization, kinetics, and mechanistic studies," Renewable Energy, Elsevier, vol. 218(C).
    2. Zhang, Yujiao & Niu, Shengli & Xia, Sunwen & Liu, Sitong & Liu, Jisen, 2023. "One-step conversion of acidified oil to biodiesel by novel bifunctional SrZr1-xFexO3 catalyst," Renewable Energy, Elsevier, vol. 217(C).

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