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Cobalt-doped CaO catalyst synthesized and applied for algal biodiesel production

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  • Das, Velentina
  • Tripathi, Abhishek Mani
  • Borah, Manash Jyoti
  • Dunford, Nurhan Turgut
  • Deka, Dhanapati

Abstract

Microalgal biomass is a potential feedstock for biofuel production because of its oleaginous nature and fast growth rate. Furthermore, its cultivation does not compete with crop producing land and thereby eliminating food vs. fuel dilemma. This study describes a low-cost nutrient mediated cultivation method for growing lipid enriched algal biomass from Scenedesmus quadricauda in BG11 media in a raceway pond. A renewable heterogeneous catalyst is synthesized using calcium oxide obtained from calcination of waste egg shells and modified using cobalt nitrate hexahydrate by co-precipitation method. The synthesized catalyst is characterized by XRD, SEM, EDX, FTIR, TEM techniques. Lipid extracted from the biomass is converted to biodiesel using the synthesized catalyst. The formation of biodiesel is confirmed using 1H NMR, 13C NMR and GC-MS techniques. The result demonstrated that the CaO–Co catalyst has very high catalytic activity for biodiesel production. The integrated process described in this study has potential for producing environmentally benign fuels and a heterogeneous catalyst from renewable sources.

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  • Das, Velentina & Tripathi, Abhishek Mani & Borah, Manash Jyoti & Dunford, Nurhan Turgut & Deka, Dhanapati, 2020. "Cobalt-doped CaO catalyst synthesized and applied for algal biodiesel production," Renewable Energy, Elsevier, vol. 161(C), pages 1110-1119.
    • Handle: RePEc:eee:renene:v:161:y:2020:i:c:p:1110-1119
    DOI: 10.1016/j.renene.2020.07.040
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    2. Aghababaeian, Shiva & Beygzadeh, Mojtaba & Dehghan, Maziar & Halek, Farah-Sadat & Aminy, Mohammad, 2024. "Energy and economic aspects of efficient radiative heating for biodiesel production: Prospects and challenges of using solid magnetic CaO/CoFe2O4 nano-catalyst," Energy, Elsevier, vol. 289(C).
    3. Jume, Binta Hadi & Gabris, Mohammad Ali & Rashidi Nodeh, Hamid & Rezania, Shahabaldin & Cho, Jinwoo, 2020. "Biodiesel production from waste cooking oil using a novel heterogeneous catalyst based on graphene oxide doped metal oxide nanoparticles," Renewable Energy, Elsevier, vol. 162(C), pages 2182-2189.
    4. Maleki, Basir & Kalanakoppal Venkatesh, Yatish & Esmaeili, Hossein & Haddadi, Masoumeh & Mithun Prakash, Ravikumar & Balakrishna, Geetha R., 2024. "Novel Co3O4 decorated with rGO nanocatalyst to boost microwave-assisted biodiesel production and as nano-additive to enhance the performance-emission characteristics of diesel engine," Energy, Elsevier, vol. 289(C).
    5. Mohadesi, Majid & Aghel, Babak & Gouran, Ashkan & Razmehgir, Mohammad Hamed, 2022. "Transesterification of waste cooking oil using Clay/CaO as a solid base catalyst," Energy, Elsevier, vol. 242(C).
    6. Panchal, Balaji & Bian, Kai & Chang, Tao & Zhu, Zheng & Wang, Jinxi & Qin, Shenjun & Zhao, Cunliang & Sun, Yuzhuang, 2021. "Synthesis of Generation-2 polyamidoamine based ionic liquid: Efficient dendrimer based catalytic green fuel production from yellow grease," Energy, Elsevier, vol. 219(C).
    7. He, Xin & Wang, Ning & Zhou, Qiaoqiao & Huang, Jun & Ramakrishna, Seeram & Li, Fanghua, 2024. "Smart aviation biofuel energy system coupling with machine learning technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    8. Xia, Shaige & Hu, Yongjie & Chen, Chao & Tao, Junyu & Yan, Beibei & Li, Wanqing & Zhu, Guangbin & Cheng, Zhanjun & Chen, Guanyi, 2022. "Electrolytic transesterification of waste cooking oil using magnetic Co/Fe–Ca based catalyst derived from waste shells: A promising approach towards sustainable biodiesel production," Renewable Energy, Elsevier, vol. 200(C), pages 1286-1299.
    9. Gao, Xiu & Chen, Chao & Zhang, Wenlu & Hong, Yanping & Wang, Chunrong & Wu, Guoqiang, 2022. "Sulfated TiO2 supported molybdenum-based catalysts for transesterification of Jatropha seed oil: Effect of molybdenum species and acidity properties," Renewable Energy, Elsevier, vol. 191(C), pages 357-369.

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