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One-step conversion of acidified oil to biodiesel by novel bifunctional SrZr1-xFexO3 catalyst

Author

Listed:
  • Zhang, Yujiao
  • Niu, Shengli
  • Xia, Sunwen
  • Liu, Sitong
  • Liu, Jisen

Abstract

The novel heterogeneous catalysts of SrZr1-xFexO3 (x = 0, 0.05, 0.10, 0.15, 0.20, 0.25, 0.30 or 0.40) with acid-base bifunctional property are prepared through the sol-gel method and applied in catalyzing transesterification and esterification from acidified oil to produce biodiesel. The substitution of Zr by Fe in the SrZrO3 perovskite results in the lattice distortion to generate abundant surface oxygen vacancies. Also, the enhancement of electron density on active sites improves the acidity and basicity of catalyst to construct the acid-base pair sites for high efficiency of biodiesel production. The SrZr0.75Fe0.25O3 catalyst shows the strongest catalytic activity and the maximum FAME yield of 99.5% is achieved at the reaction temperature of 178 °C, catalyst amount of 4.5 wt%, methanol to oil molar ratio of 19:1 and reaction duration of 3.4 h through optimizing reaction parameters by convolutional neural network. The catalyst exhibits strong acid resistance and the FAME yield of 93.9% is achieved with 30 wt% oleic acid addition, where methanol is readily adsorbed to Sr site for transesterification and free fatty acids are readily adsorbed to Fe site for esterification. In addition, the SrZr0.75Fe0.25O3 catalyst shows satisfactory reusability and the FAME yield of 96.2% is maintained for the fifth reused cycle.

Suggested Citation

  • Zhang, Yujiao & Niu, Shengli & Xia, Sunwen & Liu, Sitong & Liu, Jisen, 2023. "One-step conversion of acidified oil to biodiesel by novel bifunctional SrZr1-xFexO3 catalyst," Renewable Energy, Elsevier, vol. 217(C).
    • Handle: RePEc:eee:renene:v:217:y:2023:i:c:s0960148123010534
    DOI: 10.1016/j.renene.2023.119139
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    1. Xia, Shaige & Hu, Yongjie & Chen, Chao & Tao, Junyu & Yan, Beibei & Li, Wanqing & Zhu, Guangbin & Cheng, Zhanjun & Chen, Guanyi, 2022. "Electrolytic transesterification of waste cooking oil using magnetic Co/Fe–Ca based catalyst derived from waste shells: A promising approach towards sustainable biodiesel production," Renewable Energy, Elsevier, vol. 200(C), pages 1286-1299.
    2. Lee, H.V. & Juan, J.C. & Taufiq-Yap, Y.H., 2015. "Preparation and application of binary acid–base CaO–La2O3 catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 74(C), pages 124-132.
    3. Ning, Yilin & Niu, Shengli & Wang, Yongzheng & Zhao, Jianli & Lu, Chunmei, 2021. "Sono-modified halloysite nanotube with NaAlO2 as novel heterogeneous catalyst for biodiesel production: Optimization via GA_BP neural network," Renewable Energy, Elsevier, vol. 175(C), pages 391-404.
    4. Zhang, Heng & Li, Hu & Hu, Yulin & Venkateswara Rao, Kasanneni Tirumala & Xu, Chunbao (Charles) & Yang, Song, 2019. "Advances in production of bio-based ester fuels with heterogeneous bifunctional catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 114(C), pages 1-1.
    5. Zhang, Yujiao & Niu, Shengli & Hao, Yanan & Liu, Sitong & Liu, Jisen & Han, Kuihua & Wang, Yongzheng & Lu, Chunmei, 2023. "Preparation of SrZrAl multiple oxide catalyst for produce biodiesel from acidified palm oil," Renewable Energy, Elsevier, vol. 207(C), pages 116-127.
    6. Li, Ying & Niu, Shengli & Hao, Yanan & Zhou, Wenbo & Wang, Jun & Liu, Jiangwei, 2022. "Role of oxygen vacancy on activity of Fe-doped SrTiO3 perovskite bifunctional catalysts for biodiesel production," Renewable Energy, Elsevier, vol. 199(C), pages 1258-1271.
    7. Yu, Hewei & Cao, Yunlong & Li, Heyao & Zhao, Gaiju & Zhang, Xingyu & Cheng, Shen & Wei, Wei, 2021. "An efficient heterogeneous acid catalyst derived from waste ginger straw for biodiesel production," Renewable Energy, Elsevier, vol. 176(C), pages 533-542.
    8. Jinbo Peng & Duanyun Cao & Zhili He & Jing Guo & Prokop Hapala & Runze Ma & Bowei Cheng & Ji Chen & Wen Jun Xie & Xin-Zheng Li & Pavel Jelínek & Li-Mei Xu & Yi Qin Gao & En-Ge Wang & Ying Jiang, 2018. "The effect of hydration number on the interfacial transport of sodium ions," Nature, Nature, vol. 557(7707), pages 701-705, May.
    9. Kumar, Dipesh & Singh, Bhaskar, 2019. "BaZrO3 and Cs-BaZrO3 catalysed transesterification of Millettia Pinnata oil and optimisation of reaction variables by response surface Box-Behnken design," Renewable Energy, Elsevier, vol. 133(C), pages 411-421.
    10. Jinbo Peng & Duanyun Cao & Zhili He & Jing Guo & Prokop Hapala & Runze Ma & Bowei Cheng & Ji Chen & Wen Jun Xie & Xin-Zheng Li & Pavel Jelínek & Li-Mei Xu & Yi Qin Gao & En-Ge Wang & Ying Jiang, 2018. "Publisher Correction: The effect of hydration number on the interfacial transport of sodium ions," Nature, Nature, vol. 563(7729), pages 18-18, November.
    11. Atadashi, I.M. & Aroua, M.K. & Abdul Aziz, A.R. & Sulaiman, N.M.N., 2012. "The effects of water on biodiesel production and refining technologies: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 3456-3470.
    12. Li, Ying & Niu, Shengli & Wang, Jun & Zhou, Wenbo & Wang, Yongzheng & Han, Kuihua & Lu, Chunmei, 2022. "Mesoporous SrTiO3 perovskite as a heterogeneous catalyst for biodiesel production: Experimental and DFT studies," Renewable Energy, Elsevier, vol. 184(C), pages 164-175.
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