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Biodiesel production from waste cooking oil using a novel heterogeneous catalyst based on graphene oxide doped metal oxide nanoparticles

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  • Jume, Binta Hadi
  • Gabris, Mohammad Ali
  • Rashidi Nodeh, Hamid
  • Rezania, Shahabaldin
  • Cho, Jinwoo

Abstract

Waste cooking oil (WCO) is a potential and low-cost source for biodiesel production which has been used widely. In this study, novel nanocatalyst (GO@ZrO2–SrO) was synthesized via co-precipitation method by the combination of both potential graphene oxide and bimetal zirconium/strontium oxide nanoparticles. The proposed nanocomposite showed a promising ability as a heterogeneous catalyst for the transesterification of WCO to produce FAMEs as biodiesel. The FTIR, SEM/EDX and XRD were used for the characterization of nanocatalyst to evaluate the surface functional groups, nanostructure/elements and crystallinity, respectively. The effective parameters on the transesterification FAMEs yield including oil to alcohol ratio, reaction time, and reaction temperature were studied. Based on the results, the maximum FAMEs yield of 91% was obtained in the conditions of the material ratio of 1:0.5 (w/w) of GO:ZrO2–SrO, oil to methanol ratio (1:4), the reaction time of 90 min and the temperature of 120 °C. Therefore, this study showed that GO@ZrO2–SrO can be used as an alternative potential heterogeneous catalyst to produce biodiesel from WCO.

Suggested Citation

  • Jume, Binta Hadi & Gabris, Mohammad Ali & Rashidi Nodeh, Hamid & Rezania, Shahabaldin & Cho, Jinwoo, 2020. "Biodiesel production from waste cooking oil using a novel heterogeneous catalyst based on graphene oxide doped metal oxide nanoparticles," Renewable Energy, Elsevier, vol. 162(C), pages 2182-2189.
    • Handle: RePEc:eee:renene:v:162:y:2020:i:c:p:2182-2189
    DOI: 10.1016/j.renene.2020.10.046
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    4. Ebadinezhad, Behzad & Haghighi, Mohammad & Zeinalzadeh, Hossein, 2022. "Carbon-templated meso-design of nanostructured CeAPSO-34 for biodiesel production from free fatty acid and waste oil," Renewable Energy, Elsevier, vol. 195(C), pages 716-733.
    5. Aghel, Babak & Gouran, Ashkan & Parandi, Ehsan & Jumeh, Binta Hadi & Nodeh, Hamid Rashidi, 2022. "Production of biodiesel from high acidity waste cooking oil using nano GO@MgO catalyst in a microreactor," Renewable Energy, Elsevier, vol. 200(C), pages 294-302.
    6. Bora, Akash Pratim & Konda, Lutukurthi D.N.V.V. & Pasupuleti, Srinivas & Durbha, Krishna Sandilya, 2022. "Synthesis of MgO/MgSO4 nanocatalyst by thiourea–nitrate solution combustion for biodiesel production from waste cooking oil," Renewable Energy, Elsevier, vol. 190(C), pages 474-486.
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    9. Echaroj, Snunkhaem & Santikunaporn, Malee & Phan, Anh N., 2023. "Supercritical ethanol liquefaction of bamboo leaves using functionalized reduced graphene oxides for high quality bio-oil production," Renewable Energy, Elsevier, vol. 204(C), pages 848-857.
    10. Abdelmigeed, Mai O. & Al-Sakkari, Eslam G. & Hefney, Mahmoud S. & Ismail, Fatma M. & Ahmed, Tamer S. & Ismail, Ibrahim M., 2021. "Biodiesel production catalyzed by NaOH/Magnetized ZIF-8: Yield improvement using methanolysis and catalyst reusability enhancement," Renewable Energy, Elsevier, vol. 174(C), pages 253-261.
    11. Aisien, Felix Aibuedefe & Aisien, Eki Tina, 2023. "Modeling and optimization of transesterification of rubber seed oil using sulfonated CaO derived from giant African land snail (Achatina fulica) catalyst by response surface methodology," Renewable Energy, Elsevier, vol. 207(C), pages 137-146.
    12. Loh, Jun Mann & Amelia, & Gourich, Wail & Chew, Chien Lye & Song, Cher Pin & Chan, Eng-Seng, 2021. "Improved biodiesel production from sludge palm oil catalyzed by a low-cost liquid lipase under low-input process conditions," Renewable Energy, Elsevier, vol. 177(C), pages 348-358.
    13. Li, Ying & Niu, Shengli & Wang, Jun & Zhou, Wenbo & Wang, Yongzheng & Han, Kuihua & Lu, Chunmei, 2022. "Mesoporous SrTiO3 perovskite as a heterogeneous catalyst for biodiesel production: Experimental and DFT studies," Renewable Energy, Elsevier, vol. 184(C), pages 164-175.

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