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Investigation of solid base catalysts for biodiesel production from fish oil

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  • Papargyriou, Despoina
  • Broumidis, Emmanouil
  • de Vere-Tucker, Matthew
  • Gavrielides, Stelios
  • Hilditch, Paul
  • Irvine, John T.S.
  • Bonaccorso, Alfredo D.

Abstract

A series of composite CaO-Ca3Al2O6 mixed oxides were investigated as potential catalysts for biodiesel synthesis from waste fish oil. Different Ca/Al ratios, in the range of 1.5–6 were studied, alongside pure CaO. The catalysts were characterised by X-ray diffraction (XRD), scanning electron microscopy (SEM) and CO2-Temperature Program Desorption (TPD). The catalytic activity of the materials was studied for the transesterification reaction of cod liver oil with methanol at 65 °C, with 1:12 oil to methanol molar ratio and 10 wt% of catalyst. Over 97% conversion of the triglycerides to methyl esters was achieved for the 6Ca/Al catalyst after 2 h reaction time. This was similar to the performance of CaO. However, 6Ca/Al catalyst was reused successfully for seven consecutive tests, in contrast to CaO that was reused for only five tests, before it deactivated. Therefore, by incorporating the Ca3Al2O6, it was possible to enhance the stability of the catalytically active species and improve the lifetime of the catalyst. Post-test catalyst characterisation showed the formation of an intermediate phase (calcium diglyceroxide) that enhanced the catalyst’s performance and tolerance to air exposure and humidity. Finally, the catalyst deactivation, after seven cycles, took place due to the formation of Ca(OH)2 and CaCO3 species.

Suggested Citation

  • Papargyriou, Despoina & Broumidis, Emmanouil & de Vere-Tucker, Matthew & Gavrielides, Stelios & Hilditch, Paul & Irvine, John T.S. & Bonaccorso, Alfredo D., 2019. "Investigation of solid base catalysts for biodiesel production from fish oil," Renewable Energy, Elsevier, vol. 139(C), pages 661-669.
    • Handle: RePEc:eee:renene:v:139:y:2019:i:c:p:661-669
    DOI: 10.1016/j.renene.2019.02.124
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    4. Helmi, Fatemeh & Helmi, Maryam & Hemmati, Alireza, 2022. "Phosphomolybdic acid/chitosan as acid solid catalyst using for biodiesel production from pomegranate seed oil via microwave heating system: RSM optimization and kinetic study," Renewable Energy, Elsevier, vol. 189(C), pages 881-898.
    5. Ebadinezhad, Behzad & Haghighi, Mohammad & Zeinalzadeh, Hossein, 2021. "Influence of carbon casting loading and ultrasound irradiation on catalytic design of Al–Si–P zeotype nanostructure for biofuel production," Renewable Energy, Elsevier, vol. 177(C), pages 290-307.
    6. Dahdah, Eliane & Estephane, Jane & Haydar, Reem & Youssef, Yara & El Khoury, Bilal & Gennequin, Cedric & Aboukaïs, Antoine & Abi-Aad, Edmond & Aouad, Samer, 2020. "Biodiesel production from refined sunflower oil over Ca–Mg–Al catalysts: Effect of the composition and the thermal treatment," Renewable Energy, Elsevier, vol. 146(C), pages 1242-1248.

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