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Preparation and characterization of a novel efficient catalyst based on molybdenum oxide supported over graphene oxide for biodiesel synthesis

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  • da Silva, Paula Maria Melo
  • Gonçalves, Matheus Arrais
  • da Luz Corrêa, Ana Paula
  • da Luz, Patrícia Teresa Souza
  • Zamian, José Roberto
  • da Rocha Filho, Geraldo Narciso
  • da Conceição, Leyvison Rafael Vieira

Abstract

In this study, a new catalyst for heterogeneous acid based on molybdenum oxide (MoO3) supported over graphene oxide (GO) was synthesized and applied in simultaneous esterification-transesterification reactions using waste cooking oil (WCO) to obtain biodiesel. In the catalyst synthesis, the GO support was synthesized from graphite oxidation, followed by wet MoO3 impregnation. The MoO3/GO catalyst was characterized by Surface Acidity, Thermogravimetric Analysis (TG/DTG), X-ray Diffraction (XRD), Fourier Transformation Infrared Spectroscopy (FTIR), Scanning Electron Microscope (SEM) and Energy Dispersion X-ray Spectroscopy (EDS). The application of the catalyst in the conversion of WCO into biodiesel had as parameters reaction temperature (120.0–160.0 °C), reaction time (1.0–5.0 h), catalyst loading of (2.0–10.0%) and methanol:oil molar ratio of (25:1–45:1). The results of the catalytic tests showed the best condition of biodiesel synthesis was 140.0 °C reaction temperature, 5.0 h of reaction time, 6.0% catalyst loading and 35:1 methanol:oil molar ratio, leading to a biodiesel with ester content of 95.6%. The catalyst showed good recovery and excellent catalytic performance in the reuse study, producing biodiesel with ester content above 70.0% after 5 reaction cycles. Thus, this study shows a promising new catalyst of heterogeneous acid with high catalytic activity and applicability in the biodiesel synthesis process.

Suggested Citation

  • da Silva, Paula Maria Melo & Gonçalves, Matheus Arrais & da Luz Corrêa, Ana Paula & da Luz, Patrícia Teresa Souza & Zamian, José Roberto & da Rocha Filho, Geraldo Narciso & da Conceição, Leyvison Rafa, 2023. "Preparation and characterization of a novel efficient catalyst based on molybdenum oxide supported over graphene oxide for biodiesel synthesis," Renewable Energy, Elsevier, vol. 211(C), pages 126-139.
    • Handle: RePEc:eee:renene:v:211:y:2023:i:c:p:126-139
    DOI: 10.1016/j.renene.2023.04.131
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    References listed on IDEAS

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    1. da Conceição, Leyvison Rafael V. & Carneiro, Livia M. & Giordani, Domingos S. & de Castro, Heizir F., 2017. "Synthesis of biodiesel from macaw palm oil using mesoporous solid catalyst comprising 12-molybdophosphoric acid and niobia," Renewable Energy, Elsevier, vol. 113(C), pages 119-128.
    2. Rocha, Pablo D. & Oliveira, Leandro S. & Franca, Adriana S., 2019. "Sulfonated activated carbon from corn cobs as heterogeneous catalysts for biodiesel production using microwave-assisted transesterification," Renewable Energy, Elsevier, vol. 143(C), pages 1710-1716.
    3. Jume, Binta Hadi & Gabris, Mohammad Ali & Rashidi Nodeh, Hamid & Rezania, Shahabaldin & Cho, Jinwoo, 2020. "Biodiesel production from waste cooking oil using a novel heterogeneous catalyst based on graphene oxide doped metal oxide nanoparticles," Renewable Energy, Elsevier, vol. 162(C), pages 2182-2189.
    4. Abdullah, Sharifah Hanis Yasmin Sayid & Hanapi, Nur Hanis Mohamad & Azid, Azman & Umar, Roslan & Juahir, Hafizan & Khatoon, Helena & Endut, Azizah, 2017. "A review of biomass-derived heterogeneous catalyst for a sustainable biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 1040-1051.
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    2. Zhang, Gaoqiang & Xie, Wenlei, 2024. "Hierarchical porous SAPO-34 decorated with Mo and W oxides for concurrent transesterification-esterifications for efficient biodiesel production from acidic soybean oil," Renewable Energy, Elsevier, vol. 222(C).

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