IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v211y2023icp126-139.html
   My bibliography  Save this article

Preparation and characterization of a novel efficient catalyst based on molybdenum oxide supported over graphene oxide for biodiesel synthesis

Author

Listed:
  • da Silva, Paula Maria Melo
  • Gonçalves, Matheus Arrais
  • da Luz Corrêa, Ana Paula
  • da Luz, Patrícia Teresa Souza
  • Zamian, José Roberto
  • da Rocha Filho, Geraldo Narciso
  • da Conceição, Leyvison Rafael Vieira

Abstract

In this study, a new catalyst for heterogeneous acid based on molybdenum oxide (MoO3) supported over graphene oxide (GO) was synthesized and applied in simultaneous esterification-transesterification reactions using waste cooking oil (WCO) to obtain biodiesel. In the catalyst synthesis, the GO support was synthesized from graphite oxidation, followed by wet MoO3 impregnation. The MoO3/GO catalyst was characterized by Surface Acidity, Thermogravimetric Analysis (TG/DTG), X-ray Diffraction (XRD), Fourier Transformation Infrared Spectroscopy (FTIR), Scanning Electron Microscope (SEM) and Energy Dispersion X-ray Spectroscopy (EDS). The application of the catalyst in the conversion of WCO into biodiesel had as parameters reaction temperature (120.0–160.0 °C), reaction time (1.0–5.0 h), catalyst loading of (2.0–10.0%) and methanol:oil molar ratio of (25:1–45:1). The results of the catalytic tests showed the best condition of biodiesel synthesis was 140.0 °C reaction temperature, 5.0 h of reaction time, 6.0% catalyst loading and 35:1 methanol:oil molar ratio, leading to a biodiesel with ester content of 95.6%. The catalyst showed good recovery and excellent catalytic performance in the reuse study, producing biodiesel with ester content above 70.0% after 5 reaction cycles. Thus, this study shows a promising new catalyst of heterogeneous acid with high catalytic activity and applicability in the biodiesel synthesis process.

Suggested Citation

  • da Silva, Paula Maria Melo & Gonçalves, Matheus Arrais & da Luz Corrêa, Ana Paula & da Luz, Patrícia Teresa Souza & Zamian, José Roberto & da Rocha Filho, Geraldo Narciso & da Conceição, Leyvison Rafa, 2023. "Preparation and characterization of a novel efficient catalyst based on molybdenum oxide supported over graphene oxide for biodiesel synthesis," Renewable Energy, Elsevier, vol. 211(C), pages 126-139.
    • Handle: RePEc:eee:renene:v:211:y:2023:i:c:p:126-139
    DOI: 10.1016/j.renene.2023.04.131
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148123005967
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2023.04.131?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Rocha, Pablo D. & Oliveira, Leandro S. & Franca, Adriana S., 2019. "Sulfonated activated carbon from corn cobs as heterogeneous catalysts for biodiesel production using microwave-assisted transesterification," Renewable Energy, Elsevier, vol. 143(C), pages 1710-1716.
    2. Jume, Binta Hadi & Gabris, Mohammad Ali & Rashidi Nodeh, Hamid & Rezania, Shahabaldin & Cho, Jinwoo, 2020. "Biodiesel production from waste cooking oil using a novel heterogeneous catalyst based on graphene oxide doped metal oxide nanoparticles," Renewable Energy, Elsevier, vol. 162(C), pages 2182-2189.
    3. da Conceição, Leyvison Rafael V. & Carneiro, Livia M. & Giordani, Domingos S. & de Castro, Heizir F., 2017. "Synthesis of biodiesel from macaw palm oil using mesoporous solid catalyst comprising 12-molybdophosphoric acid and niobia," Renewable Energy, Elsevier, vol. 113(C), pages 119-128.
    4. Abdullah, Sharifah Hanis Yasmin Sayid & Hanapi, Nur Hanis Mohamad & Azid, Azman & Umar, Roslan & Juahir, Hafizan & Khatoon, Helena & Endut, Azizah, 2017. "A review of biomass-derived heterogeneous catalyst for a sustainable biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 1040-1051.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ghasemi, Iman & Haghighi, Mohammad & Bekhradinassab, Ensie & Ebrahimi, Alireza, 2024. "Ultrasound-assisted dispersion of bifunctional CaO-ZrO2 nanocatalyst over acidified kaolin for production of biodiesel from waste cooking oil," Renewable Energy, Elsevier, vol. 225(C).
    2. Zhang, Gaoqiang & Xie, Wenlei, 2024. "Hierarchical porous SAPO-34 decorated with Mo and W oxides for concurrent transesterification-esterifications for efficient biodiesel production from acidic soybean oil," Renewable Energy, Elsevier, vol. 222(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ella Cebisa Linganiso & Boitumelo Tlhaole & Lindokuhle Precious Magagula & Silas Dziike & Linda Zikhona Linganiso & Tshwafo Elias Motaung & Nosipho Moloto & Zikhona Nobuntu Tetana, 2022. "Biodiesel Production from Waste Oils: A South African Outlook," Sustainability, MDPI, vol. 14(4), pages 1-21, February.
    2. Aisien, Felix Aibuedefe & Aisien, Eki Tina, 2023. "Modeling and optimization of transesterification of rubber seed oil using sulfonated CaO derived from giant African land snail (Achatina fulica) catalyst by response surface methodology," Renewable Energy, Elsevier, vol. 207(C), pages 137-146.
    3. Zailan, Zarifah & Tahir, Muhammad & Jusoh, Mazura & Zakaria, Zaki Yamani, 2021. "A review of sulfonic group bearing porous carbon catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 175(C), pages 430-452.
    4. Rezania, Shahabaldin & Korrani, Zahra Sotoudehnia & Gabris, Mohammad Ali & Cho, Jinwoo & Yadav, Krishna Kumar & Cabral-Pinto, Marina M.S. & Alam, Javed & Ahamed, Maqusood & Nodeh, Hamid Rashidi, 2021. "Lanthanum phosphate foam as novel heterogeneous nanocatalyst for biodiesel production from waste cooking oil," Renewable Energy, Elsevier, vol. 176(C), pages 228-236.
    5. Gualberto Zavarize, Danilo & Braun, Heder & Diniz de Oliveira, Jorge, 2021. "Methanolysis of low-FFA waste cooking oil with novel carbon-based heterogeneous acid catalyst derived from Amazon açaí berry seeds," Renewable Energy, Elsevier, vol. 171(C), pages 621-634.
    6. Karmakar, Bisheswar & Pal, Sucharita & Gopikrishna, Konga & Tiwari, Onkar Nath & Halder, Gopinath, 2022. "Injection of superheated C1 and C3 alcohols in non-edible Pongamia pinnata oil for semi-continuous uncatalyzed biodiesel synthesis," Renewable Energy, Elsevier, vol. 185(C), pages 850-861.
    7. Li, Ying & Niu, Shengli & Wang, Jun & Zhou, Wenbo & Wang, Yongzheng & Han, Kuihua & Lu, Chunmei, 2022. "Mesoporous SrTiO3 perovskite as a heterogeneous catalyst for biodiesel production: Experimental and DFT studies," Renewable Energy, Elsevier, vol. 184(C), pages 164-175.
    8. de Brito, Vitor Lima & Gonçalves, Matheus Arrais & dos Santos, Hiarla Cristina Lima & da Rocha Filho, Geraldo Narciso & da Conceição, Leyvison Rafael Vieira, 2023. "Biodiesel production from waste frying oil using molybdenum over niobia as heterogeneous acid catalyst: Process optimization and kinetics study," Renewable Energy, Elsevier, vol. 215(C).
    9. Saikia, Kankana & Das, Arpita & Sema, Atoholi H. & Basumatary, Sanjay & Shaemningwar Moyon, N. & Mathimani, Thangavel & Rokhum, Samuel Lalthazuala, 2024. "Response surface optimization, kinetics, thermodynamics, and life cycle cost analysis of biodiesel production from Jatropha curcas oil using biomass-based functional activated carbon catalyst," Renewable Energy, Elsevier, vol. 229(C).
    10. Atelge, M.R., 2022. "Production of biodiesel and hydrogen by using a double-function heterogeneous catalyst derived from spent coffee grounds and its thermodynamic analysis," Renewable Energy, Elsevier, vol. 198(C), pages 1-15.
    11. Das, Arpita & Li, Hui & Kataki, Rupam & Agrawal, Pratibha S. & Moyon, N.S. & Gurunathan, Baskar & Rokhum, Samuel Lalthazuala, 2023. "Terminalia arjuna bark – A highly efficient renewable heterogeneous base catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 212(C), pages 185-196.
    12. Xie, Wenlei & Huang, Mengyun, 2020. "Fabrication of immobilized Candida rugosa lipase on magnetic Fe3O4-poly(glycidyl methacrylate-co-methacrylic acid) composite as an efficient and recyclable biocatalyst for enzymatic production of biod," Renewable Energy, Elsevier, vol. 158(C), pages 474-486.
    13. Zhang-Chun Tang & Yanjun Xia & Qi Xue & Jie Liu, 2018. "A Non-Probabilistic Solution for Uncertainty and Sensitivity Analysis on Techno-Economic Assessments of Biodiesel Production with Interval Uncertainties," Energies, MDPI, vol. 11(3), pages 1-17, March.
    14. Ebadinezhad, Behzad & Haghighi, Mohammad & Zeinalzadeh, Hossein, 2022. "Carbon-templated meso-design of nanostructured CeAPSO-34 for biodiesel production from free fatty acid and waste oil," Renewable Energy, Elsevier, vol. 195(C), pages 716-733.
    15. Shen, Feng & Xiong, Xinni & Fu, Junyan & Yang, Jirui & Qiu, Mo & Qi, Xinhua & Tsang, Daniel C.W., 2020. "Recent advances in mechanochemical production of chemicals and carbon materials from sustainable biomass resources," Renewable and Sustainable Energy Reviews, Elsevier, vol. 130(C).
    16. Aghel, Babak & Biabani, Arash, 2024. "Using solar microreactors and photocatalysts to synthesize biodiesel," Renewable Energy, Elsevier, vol. 220(C).
    17. Ali, Adnan Hayel & Wanderlind, Eduardo H. & Almerindo, Gizelle I., 2024. "Activated carbon obtained from malt bagasse as a support in heterogeneous catalysis for biodiesel production," Renewable Energy, Elsevier, vol. 220(C).
    18. Ruatpuia, Joseph V.L. & Changmai, Bishwajit & Pathak, Ayush & Alghamdi, Lana A. & Kress, Thomas & Halder, Gopinath & Wheatley, Andrew E.H. & Rokhum, Samuel Lalthazuala, 2023. "Green biodiesel production from Jatropha curcas oil using a carbon-based solid acid catalyst: A process optimization study," Renewable Energy, Elsevier, vol. 206(C), pages 597-608.
    19. Sulaiman, Nur Fatin & Wan Abu Bakar, Wan Azelee & Toemen, Susilawati & Kamal, Norhasyimah Mohd & Nadarajan, Renugambaal, 2019. "In depth investigation of bi-functional, Cu/Zn/γ-Al2O3 catalyst in biodiesel production from low-grade cooking oil: Optimization using response surface methodology," Renewable Energy, Elsevier, vol. 135(C), pages 408-416.
    20. Borah, Manash Jyoti & Devi, Anuchaya & Borah, Raju & Deka, Dhanapati, 2019. "Synthesis and application of Co doped ZnO as heterogeneous nanocatalyst for biodiesel production from non-edible oil," Renewable Energy, Elsevier, vol. 133(C), pages 512-519.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:211:y:2023:i:c:p:126-139. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.