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Lanthanum phosphate foam as novel heterogeneous nanocatalyst for biodiesel production from waste cooking oil

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  • Rezania, Shahabaldin
  • Korrani, Zahra Sotoudehnia
  • Gabris, Mohammad Ali
  • Cho, Jinwoo
  • Yadav, Krishna Kumar
  • Cabral-Pinto, Marina M.S.
  • Alam, Javed
  • Ahamed, Maqusood
  • Nodeh, Hamid Rashidi

Abstract

In this study, the potential of LaPO4 foam as a heterogeneous catalyst to produce biodiesel from highly acidic waste cooking oil (WCO) was investigated. The LaPO4 supported nickel foam was characterized by scanning electron microscopy (SEM), energy dispersive X-ray mapping analysis (EDX), X-ray diffraction, and Fourier transform infrared (FT-IR). In addition, the effect of different parameters such as the molar ratio of feedstock to methanol, contact time and the reaction temperature. Under the study conditions, with methanol to oil molar ratio of 5:1, and a reaction temperature of 90 °C, 91% FAME yield was obtained within 120 min with 2.5 wt % of LaPO4. The obtained results demonstrated that LaPO4 foam can be used effectively as a heterogeneous catalyst with superior catalytic efficiency (>90%) with easy separation and excellent stability.

Suggested Citation

  • Rezania, Shahabaldin & Korrani, Zahra Sotoudehnia & Gabris, Mohammad Ali & Cho, Jinwoo & Yadav, Krishna Kumar & Cabral-Pinto, Marina M.S. & Alam, Javed & Ahamed, Maqusood & Nodeh, Hamid Rashidi, 2021. "Lanthanum phosphate foam as novel heterogeneous nanocatalyst for biodiesel production from waste cooking oil," Renewable Energy, Elsevier, vol. 176(C), pages 228-236.
    • Handle: RePEc:eee:renene:v:176:y:2021:i:c:p:228-236
    DOI: 10.1016/j.renene.2021.05.060
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    1. Rattanaphra, Dussadee & Soodjit, Phansiri & Thanapimmetha, Anusith & Saisriyoot, Maythee & Srinophakun, Penjit, 2019. "Synthesis, characterization and catalytic activity studies of lanthanum oxide from Thai monazite ore for biodiesel production," Renewable Energy, Elsevier, vol. 131(C), pages 1128-1137.
    2. Balajii, Muthusamy & Niju, Subramaniapillai, 2020. "Banana peduncle – A green and renewable heterogeneous base catalyst for biodiesel production from Ceiba pentandra oil," Renewable Energy, Elsevier, vol. 146(C), pages 2255-2269.
    3. Jume, Binta Hadi & Gabris, Mohammad Ali & Rashidi Nodeh, Hamid & Rezania, Shahabaldin & Cho, Jinwoo, 2020. "Biodiesel production from waste cooking oil using a novel heterogeneous catalyst based on graphene oxide doped metal oxide nanoparticles," Renewable Energy, Elsevier, vol. 162(C), pages 2182-2189.
    4. Abdullah, Sharifah Hanis Yasmin Sayid & Hanapi, Nur Hanis Mohamad & Azid, Azman & Umar, Roslan & Juahir, Hafizan & Khatoon, Helena & Endut, Azizah, 2017. "A review of biomass-derived heterogeneous catalyst for a sustainable biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 1040-1051.
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    1. Maleki, Basir & Esmaeili, Hossein, 2023. "Ultrasound-assisted conversion of waste frying oil into biodiesel using Al-doped ZnO nanocatalyst: Box-Behnken design-based optimization," Renewable Energy, Elsevier, vol. 209(C), pages 10-26.
    2. Peng, Lizeng & Bahadoran, Ashkan & Sheidaei, Sina & Joolaei Ahranjani, Parham & Kamyab, Hesam & Oryani, Bahareh & Sadia Arain, Sadaf & Rezania, Shahabaldin, 2024. "Magnetic graphene oxide supported tin oxide (SnO) nanocomposite as a heterogeneous catalyst for biodiesel production from soybean oil," Renewable Energy, Elsevier, vol. 224(C).
    3. Maleki, Basir & Ashraf Talesh, S. Siamak, 2022. "Optimization of ZnO incorporation to αFe2O3 nanoparticles as an efficient catalyst for biodiesel production in a sonoreactor: Application on the CI engine," Renewable Energy, Elsevier, vol. 182(C), pages 43-59.
    4. El-sherif, Ahmed A. & Hamad, Amany M. & Shams-Eldin, Engy & Mohamed, Heba Allah Abdelnabi Eid & Ahmed, Asmaa M. & Mohamed, Maha A. & Abdelaziz, Youssef S. & Sayed, Fatma Al-Zahraa & El qassem Mahmoud,, 2023. "Power of recycling waste cooking oil into biodiesel via green CaO-based eggshells/Ag heterogeneous nanocatalyst," Renewable Energy, Elsevier, vol. 202(C), pages 1412-1423.
    5. Panchal, Balaji & Zhu, Zheng & Qin, Shenjun & Chang, Tao & Zhao, Qiaojing & Sun, Yuzhuang & Zhao, Cunliang & Wang, Jinxi & Bian, Kai & Rankhamb, Santosh, 2022. "The current state applications of ethyl carbonate with ionic liquid in sustainable biodiesel production: A review," Renewable Energy, Elsevier, vol. 181(C), pages 341-354.
    6. Maleki, Basir & Ashraf Talesh, S. Siamak, 2024. "Sustainable biodiesel production from wild oak (Quercus brantii Lindl) oil as a novel and potential feedstock via highly efficient Co@CuO nanocatalyst: RSM optimization and CI engine assessment," Renewable Energy, Elsevier, vol. 224(C).
    7. Atelge, M.R., 2022. "Production of biodiesel and hydrogen by using a double-function heterogeneous catalyst derived from spent coffee grounds and its thermodynamic analysis," Renewable Energy, Elsevier, vol. 198(C), pages 1-15.
    8. Zeeshan, Muhammad & Ghazanfar, Sadia & Tariq, Muhammad & Asif, Hafiz Muhammad & Hussain, Ajaz & Usman, Muhamamd & Khan, Muhammad Ali & Mahmood, Khalid & Sirajuddin, Muhammad & Imran, Muhammad, 2023. "Synthesis of novel ternary NiO–CdO-Nd2O3 nanocomposite for biodiesel production," Renewable Energy, Elsevier, vol. 210(C), pages 800-809.

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