IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v174y2021icp253-261.html
   My bibliography  Save this article

Biodiesel production catalyzed by NaOH/Magnetized ZIF-8: Yield improvement using methanolysis and catalyst reusability enhancement

Author

Listed:
  • Abdelmigeed, Mai O.
  • Al-Sakkari, Eslam G.
  • Hefney, Mahmoud S.
  • Ismail, Fatma M.
  • Ahmed, Tamer S.
  • Ismail, Ibrahim M.

Abstract

The current study investigates the methanolysis reaction to increase biodiesel yield using the recently developed NaOH/magnetized ZIF-8 catalyst. The effects of methanol to oil ratio and catalyst dose on oil conversion with their interaction were studied by employing full factorial design and response surface methodology. Two-factor interaction model was selected as the best model to fit the experimental data with a determination coefficient (R2) of 0.97 where all the model’s parameters were significant. The two factors were found positively influencing the reaction conversion. The maximum observed conversion reached almost 100% at 21:1 M methanol to oil ratio and 3 wt% catalyst/oil ratio. Additionally, the kinetic study revealed that pseudo-second order kinetic model fits the experimental data well. In addition, the Arrhenius equation analysis showed lower activation energy and higher pre-exponential factor for methanolysis in comparison with ethanolysis indicating the faster kinetics. Besides, ASTM standard testing techniques confirmed that the produced esters at optimum conditions can be used as biodiesel sustainable fuel. Finally, several modifications in the catalyst preparation conditions or procedure showed their ability to increase catalyst stability and reusability characteristics.

Suggested Citation

  • Abdelmigeed, Mai O. & Al-Sakkari, Eslam G. & Hefney, Mahmoud S. & Ismail, Fatma M. & Ahmed, Tamer S. & Ismail, Ibrahim M., 2021. "Biodiesel production catalyzed by NaOH/Magnetized ZIF-8: Yield improvement using methanolysis and catalyst reusability enhancement," Renewable Energy, Elsevier, vol. 174(C), pages 253-261.
    • Handle: RePEc:eee:renene:v:174:y:2021:i:c:p:253-261
    DOI: 10.1016/j.renene.2021.04.057
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148121005759
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2021.04.057?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Abdelmigeed, Mai O. & Al-Sakkari, Eslam G. & Hefney, Mahmoud S. & Ismail, Fatma M. & Abdelghany, Amr & Ahmed, Tamer S. & Ismail, Ibrahim M., 2021. "Magnetized ZIF-8 impregnated with sodium hydroxide as a heterogeneous catalyst for high-quality biodiesel production," Renewable Energy, Elsevier, vol. 165(P1), pages 405-419.
    2. Nayebzadeh, Hamed & Haghighi, Mohammad & Saghatoleslami, Naser & Alaei, Shervin & Yousefi, Sina, 2019. "Texture/phase evolution during plasma treatment of microwave-combustion synthesized KOH/Ca12Al14O33-C nanocatalyst for reusability enhancement in conversion of canola oil to biodiesel," Renewable Energy, Elsevier, vol. 139(C), pages 28-39.
    3. Yatish, K.V. & Lalithamba, H.S. & Suresh, R. & Latha, H.K.E., 2020. "Ochrocarpus longifolius assisted green synthesis of CaTiO3 nanoparticle for biodiesel production and its kinetic study," Renewable Energy, Elsevier, vol. 147(P1), pages 310-321.
    4. Jume, Binta Hadi & Gabris, Mohammad Ali & Rashidi Nodeh, Hamid & Rezania, Shahabaldin & Cho, Jinwoo, 2020. "Biodiesel production from waste cooking oil using a novel heterogeneous catalyst based on graphene oxide doped metal oxide nanoparticles," Renewable Energy, Elsevier, vol. 162(C), pages 2182-2189.
    5. Suresh, T. & Sivarajasekar, N. & Balasubramani, K., 2021. "Enhanced ultrasonic assisted biodiesel production from meat industry waste (pig tallow) using green copper oxide nanocatalyst: Comparison of response surface and neural network modelling," Renewable Energy, Elsevier, vol. 164(C), pages 897-907.
    6. Seffati, Kambiz & Esmaeili, Hossein & Honarvar, Bizhan & Esfandiari, Nadia, 2020. "AC/CuFe2O4@CaO as a novel nanocatalyst to produce biodiesel from chicken fat," Renewable Energy, Elsevier, vol. 147(P1), pages 25-34.
    7. Wang, Yi-Tong & Yang, Xing-Xia & Xu, Jie & Wang, Hong-Li & Wang, Zi-Bing & Zhang, Lei & Wang, Shao-Long & Liang, Jing-Long, 2019. "Biodiesel production from esterification of oleic acid by a sulfonated magnetic solid acid catalyst," Renewable Energy, Elsevier, vol. 139(C), pages 688-695.
    8. Mohamed, Mohamed Mokhatr & Bayoumy, W.A. & El-Faramawy, Hossam & El-Dogdog, Wagdy & Mohamed, Ashraf A., 2020. "A novel α-Fe2O3/AlOOH(γ-Al2O3) nanocatalyst for efficient biodiesel production from waste oil: Kinetic and thermal studies," Renewable Energy, Elsevier, vol. 160(C), pages 450-464.
    9. Ahmad, Shamshad & Chaudhary, Shalini & Pathak, Vinayak V. & Kothari, Richa & Tyagi, V.V., 2020. "Optimization of direct transesterification of Chlorella pyrenoidosa catalyzed by waste egg shell based heterogenous nano – CaO catalyst," Renewable Energy, Elsevier, vol. 160(C), pages 86-97.
    10. Veljković, Vlada B. & Banković-Ilić, Ivana B. & Stamenković, Olivera S., 2015. "Purification of crude biodiesel obtained by heterogeneously-catalyzed transesterification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 49(C), pages 500-516.
    11. Borah, Manash Jyoti & Devi, Anuchaya & Borah, Raju & Deka, Dhanapati, 2019. "Synthesis and application of Co doped ZnO as heterogeneous nanocatalyst for biodiesel production from non-edible oil," Renewable Energy, Elsevier, vol. 133(C), pages 512-519.
    12. di Bitonto, Luigi & Reynel-Ávila, Hilda Elizabeth & Mendoza-Castillo, Didilia Ileana & Bonilla-Petriciolet, Adrián & Durán-Valle, Carlos J. & Pastore, Carlo, 2020. "Synthesis and characterization of nanostructured calcium oxides supported onto biochar and their application as catalysts for biodiesel production," Renewable Energy, Elsevier, vol. 160(C), pages 52-66.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Sahar, Juma & Farooq, Muhammad & Ramli, Anita & Naeem, Abdul & Khattak, Noor Saeed & Ghazi, Zahid Ali, 2022. "Highly efficient heteropoly acid decorated SnO2@Co-ZIF nanocatalyst for sustainable biodiesel production from Nannorrhops ritchiana seeds oil," Renewable Energy, Elsevier, vol. 198(C), pages 306-318.
    2. Feng, Weiliang & Tie, Xinlong & Duan, Xiaoling & Yan, Su & Fang, Si & Sun, Peiyong & Gan, Lin & Wang, Tielin, 2023. "Covalent immobilization of phosphotungstic acid and amino acid on metal-organic frameworks with different structures: Acid-base bifunctional heterogeneous catalyst for the production of biodiesel from," Renewable Energy, Elsevier, vol. 210(C), pages 26-39.
    3. Sun, Chihe & Hu, Yun & Sun, Fubao & Sun, Yahui & Song, Guojie & Chang, Haixing & Lunprom, Siriporn, 2022. "Comparison of biodiesel production using a novel porous Zn/Al/Co complex oxide prepared from different methods: Physicochemical properties, reaction kinetic and thermodynamic studies," Renewable Energy, Elsevier, vol. 181(C), pages 1419-1430.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Aghel, Babak & Gouran, Ashkan & Parandi, Ehsan & Jumeh, Binta Hadi & Nodeh, Hamid Rashidi, 2022. "Production of biodiesel from high acidity waste cooking oil using nano GO@MgO catalyst in a microreactor," Renewable Energy, Elsevier, vol. 200(C), pages 294-302.
    2. Li, Ying & Niu, Shengli & Wang, Jun & Zhou, Wenbo & Wang, Yongzheng & Han, Kuihua & Lu, Chunmei, 2022. "Mesoporous SrTiO3 perovskite as a heterogeneous catalyst for biodiesel production: Experimental and DFT studies," Renewable Energy, Elsevier, vol. 184(C), pages 164-175.
    3. Duan, Xiaoling & Yan, Su & Tie, Xinlong & Lei, Xidan & Liu, Zhiyi & Ma, Zhichao & Wang, Tielin & Feng, Weiliang, 2024. "Bimetallic Ce-Cr doped metal-organic frameworks as a heterogeneous catalyst for highly efficient biodiesel production from insect lipids," Renewable Energy, Elsevier, vol. 224(C).
    4. Maleki, Basir & Esmaeili, Hossein, 2023. "Ultrasound-assisted conversion of waste frying oil into biodiesel using Al-doped ZnO nanocatalyst: Box-Behnken design-based optimization," Renewable Energy, Elsevier, vol. 209(C), pages 10-26.
    5. Kazemi Shariat Panahi, Hamed & Hosseinzadeh-Bandbafha, Homa & Dehhaghi, Mona & Orooji, Yasin & Mahian, Omid & Shahbeik, Hossein & Kiehbadroudinezhad, Mohammadali & Kalam, Md Abul & Karimi-Maleh, Hassa, 2024. "Nanotechnology applications in biodiesel processing and production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 192(C).
    6. Aisien, Felix Aibuedefe & Aisien, Eki Tina, 2023. "Modeling and optimization of transesterification of rubber seed oil using sulfonated CaO derived from giant African land snail (Achatina fulica) catalyst by response surface methodology," Renewable Energy, Elsevier, vol. 207(C), pages 137-146.
    7. Ebadinezhad, Behzad & Haghighi, Mohammad & Zeinalzadeh, Hossein, 2022. "Carbon-templated meso-design of nanostructured CeAPSO-34 for biodiesel production from free fatty acid and waste oil," Renewable Energy, Elsevier, vol. 195(C), pages 716-733.
    8. Aghel, Babak & Biabani, Arash, 2024. "Using solar microreactors and photocatalysts to synthesize biodiesel," Renewable Energy, Elsevier, vol. 220(C).
    9. Ali, Hamdy Elsayed Ahmed & El-fayoumy, Eman A. & Soliman, Ramadan M. & Elkhatat, Ahmed & Al-Meer, Saeed & Elsaid, Khaled & Hussein, Hanaa Ali & Zul Helmi Rozaini, Mohd & Azmuddin Abdullah, Mohd, 2024. "Nanoparticle applications in Algal-biorefinery for biofuel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 192(C).
    10. Maleki, Basir & Ashraf Talesh, S. Siamak, 2022. "Optimization of ZnO incorporation to αFe2O3 nanoparticles as an efficient catalyst for biodiesel production in a sonoreactor: Application on the CI engine," Renewable Energy, Elsevier, vol. 182(C), pages 43-59.
    11. Maleki, Basir & Ashraf Talesh, S. Siamak, 2024. "Sustainable biodiesel production from wild oak (Quercus brantii Lindl) oil as a novel and potential feedstock via highly efficient Co@CuO nanocatalyst: RSM optimization and CI engine assessment," Renewable Energy, Elsevier, vol. 224(C).
    12. Shelare, Sagar D. & Belkhode, Pramod N. & Nikam, Keval Chandrakant & Jathar, Laxmikant D. & Shahapurkar, Kiran & Soudagar, Manzoore Elahi M. & Veza, Ibham & Khan, T.M. Yunus & Kalam, M.A. & Nizami, Ab, 2023. "Biofuels for a sustainable future: Examining the role of nano-additives, economics, policy, internet of things, artificial intelligence and machine learning technology in biodiesel production," Energy, Elsevier, vol. 282(C).
    13. Zhao, Xiqiang & Zhou, Xing & Wang, Guoxiu & Zhou, Ping & Wang, Wenlong & Song, Zhanlong, 2022. "Evaluating the effect of torrefaction on the pyrolysis of biomass and the biochar catalytic performance on dry reforming of methane," Renewable Energy, Elsevier, vol. 192(C), pages 313-325.
    14. Karmakar, Bisheswar & Pal, Sucharita & Gopikrishna, Konga & Tiwari, Onkar Nath & Halder, Gopinath, 2022. "Injection of superheated C1 and C3 alcohols in non-edible Pongamia pinnata oil for semi-continuous uncatalyzed biodiesel synthesis," Renewable Energy, Elsevier, vol. 185(C), pages 850-861.
    15. Liu, Shasha & Wu, Gang & Gao, Yi & Li, Bin & Feng, Yu & Zhou, Jianbin & Hu, Xun & Huang, Yong & Zhang, Shu & Zhang, Hong, 2021. "Understanding the catalytic upgrading of bio-oil from pine pyrolysis over CO2-activated biochar," Renewable Energy, Elsevier, vol. 174(C), pages 538-546.
    16. Sahar, Juma & Farooq, Muhammad & Ramli, Anita & Naeem, Abdul & Khattak, Noor Saeed & Ghazi, Zahid Ali, 2022. "Highly efficient heteropoly acid decorated SnO2@Co-ZIF nanocatalyst for sustainable biodiesel production from Nannorrhops ritchiana seeds oil," Renewable Energy, Elsevier, vol. 198(C), pages 306-318.
    17. Sannagoudar Basanagoudar, Arun & Maleki, Basir & Prakash Ravikumar, Mithun & Mounesh, & Kuppe, Pramoda & Kalanakoppal Venkatesh, Yatish, 2024. "Exploitation of Annona reticulata leaf extract for the synthesis of CeO2 nanoparticles as catalyst for the production of biodiesel using seed oil thereof," Energy, Elsevier, vol. 298(C).
    18. Saikia, Kankana & Das, Arpita & Sema, Atoholi H. & Basumatary, Sanjay & Shaemningwar Moyon, N. & Mathimani, Thangavel & Rokhum, Samuel Lalthazuala, 2024. "Response surface optimization, kinetics, thermodynamics, and life cycle cost analysis of biodiesel production from Jatropha curcas oil using biomass-based functional activated carbon catalyst," Renewable Energy, Elsevier, vol. 229(C).
    19. Al-Hamamre, Zayed & Sandouqa, Arwa & Al-Saida, Basel & Shawabkeh, Reyad A. & Alnaief, Mohammad, 2023. "Biodiesel production from waste cooking oil using heterogeneous KNO3/Oil shale ash catalyst," Renewable Energy, Elsevier, vol. 211(C), pages 470-483.
    20. Saengprachum, Nisakorn & Cai, Dongren & Li, Mantian & Li, Ling & Lin, Xiaocheng & Qiu, Ting, 2019. "Acidic chitosan membrane as an efficient catalyst for biodiesel production from oleic acid," Renewable Energy, Elsevier, vol. 143(C), pages 1488-1499.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:174:y:2021:i:c:p:253-261. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.