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High-performance and low-leakage phosphoric acid fuel cell with synergic composite membrane stacking of micro glass microfiber and nano PTFE

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  • Lu, Chia-Lien
  • Chang, Cheng-Ping
  • Guo, Yi-Hsuan
  • Yeh, Tsung-Kuang
  • Su, Yu-Chuan
  • Wang, Pen-Cheng
  • Hsueh, Kan-Lin
  • Tseng, Fan-Gang

Abstract

A novel composite membrane consisting glass microfiber (GMF) and polytetrafluoroethylene (PTFE) nanoporous film is applied to phosphoric acid fuel cell (PAFC) for performance enhancement and reducing electrolyte leakage. With 93% high porosity, the GMF can fully load phosphoric acid to maintain high proton conductivity. However, the large opening of the GMF membrane cannot effectively prevent the leakage of phosphoric acid. Therefore, in this study, a 25 μm thick PTFE thin film with pore size 50–400 nm is employed to cover the surface of GMF for preventing phosphoric acid leakage. This composite proton exchange membrane possesses both thermal and chemical stability at the working temperature of phosphoric acid fuel cell, while providing high proton conductivity. The proton conductivity of the composite membrane (0.71 S/cm at 150 °C) is much higher than those of reported phosphoric acid porous membranes (∼10−2 S/cm at 150 °C). The fuel cell using the composite membrane with Pt/C catalyst exhibits excellent performance with peak power density of 614 mW/cm2 and current density of 1761 mA/cm2 at 140 °C under pure H2 and O2 supply, while proton conductivity is maintained 2.6 times higher than that of the pure GMF membrane due to the less phosphoric acid leakage by using PTFE film.

Suggested Citation

  • Lu, Chia-Lien & Chang, Cheng-Ping & Guo, Yi-Hsuan & Yeh, Tsung-Kuang & Su, Yu-Chuan & Wang, Pen-Cheng & Hsueh, Kan-Lin & Tseng, Fan-Gang, 2019. "High-performance and low-leakage phosphoric acid fuel cell with synergic composite membrane stacking of micro glass microfiber and nano PTFE," Renewable Energy, Elsevier, vol. 134(C), pages 982-988.
    • Handle: RePEc:eee:renene:v:134:y:2019:i:c:p:982-988
    DOI: 10.1016/j.renene.2018.11.011
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    References listed on IDEAS

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    1. Authayanun, Suthida & Mamlouk, Mohamed & Scott, Keith & Arpornwichanop, Amornchai, 2013. "Comparison of high-temperature and low-temperature polymer electrolyte membrane fuel cell systems with glycerol reforming process for stationary applications," Applied Energy, Elsevier, vol. 109(C), pages 192-201.
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    Cited by:

    1. Guoxiao Xu & Xinwei Dong & Bin Xue & Jianyou Huang & Junli Wu & Weiwei Cai, 2023. "Recent Approaches to Achieve High Temperature Operation of Nafion Membranes," Energies, MDPI, vol. 16(4), pages 1-21, February.
    2. Guo, Xinru & Zhang, Houcheng & Hu, Ziyang & Hou, Shujin & Ni, Meng & Liao, Tianjun, 2021. "Energetic, exergetic and ecological evaluations of a hybrid system based on a phosphoric acid fuel cell and an organic Rankine cycle," Energy, Elsevier, vol. 217(C).
    3. Kannan, Vishvak & Xue, Hansong & Raman, K. Ashoke & Chen, Jiasheng & Fisher, Adrian & Birgersson, Erik, 2020. "Quantifying operating uncertainties of a PEMFC – Monte Carlo-machine learning based approach," Renewable Energy, Elsevier, vol. 158(C), pages 343-359.
    4. Chang, Cheng-Ping & Wu, Yen-Chih & Chen, Wei-Yen & Pan, Chin & Su, Yu-Chuan & Huang, Yuh-Jeen & Tseng, Fan-Gang, 2020. "A hybrid phosphorus-acid fuel cell system incorporated with oxidative steam reforming of methanol (OSRM) reformer," Renewable Energy, Elsevier, vol. 153(C), pages 530-538.

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