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Recent Approaches to Achieve High Temperature Operation of Nafion Membranes

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  • Guoxiao Xu

    (School of Electronic Engineering, Guangxi University of Science and Technology, Guangxi 545006, China)

  • Xinwei Dong

    (School of Electronic Engineering, Guangxi University of Science and Technology, Guangxi 545006, China)

  • Bin Xue

    (School of Mechanical and Automotive Engineering, Guangxi University of Science and Technology, Guangxi 545006, China)

  • Jianyou Huang

    (School of Mechanical and Automotive Engineering, Guangxi University of Science and Technology, Guangxi 545006, China)

  • Junli Wu

    (School of Electronic Engineering, Guangxi University of Science and Technology, Guangxi 545006, China)

  • Weiwei Cai

    (Sustainable Energy Laboratory, Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430074, China)

Abstract

A proton exchange membrane fuel cell (PEMFC), as an efficient energy conversion device, has many advantages, such as high energy conversion efficiency and environmentally friendly zero emissions, and is expected to have great potential for addressing the uneven distribution of global green energy. As a core component, the performance of the proton exchange membrane (PEM) directly affects the overall output of the fuel cell system. At present, Nafion membranes with good, comprehensive properties are the most widely used commercial proton exchange membrane materials. However, Nafion membranes demonstrate a great inadaptability with an increase in operating temperatures, such as a rapid decay in proton conductivity. Therefore, enhancing the overall performance of Nafion membranes under high temperatures and low relative humidity (RH) has become an urgent problem. Although many efforts have been made to solve this problem, it is difficult to find the balance point between high-temperature conductivity and overall stability for researchers. In this paper, we summarize the recent approaches to improving the operating temperature of Nafion membranes from the following two perspectives: (1) using different materials for the modification of Nafion membranes, and (2) applying different modification methods to the Nafion membranes. Based on the structural and functional characteristics of Nafion, the non-destructive targeted filling of fillers and the efficient synergy of the two-phase region are two vital research directions for the preparation of high-performance composite membranes.

Suggested Citation

  • Guoxiao Xu & Xinwei Dong & Bin Xue & Jianyou Huang & Junli Wu & Weiwei Cai, 2023. "Recent Approaches to Achieve High Temperature Operation of Nafion Membranes," Energies, MDPI, vol. 16(4), pages 1-21, February.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:4:p:1565-:d:1057730
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    References listed on IDEAS

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    1. Qiu, Diankai & Peng, Linfa & Lai, Xinmin & Ni, Meng & Lehnert, Werner, 2019. "Mechanical failure and mitigation strategies for the membrane in a proton exchange membrane fuel cell," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    2. Lu, Chia-Lien & Chang, Cheng-Ping & Guo, Yi-Hsuan & Yeh, Tsung-Kuang & Su, Yu-Chuan & Wang, Pen-Cheng & Hsueh, Kan-Lin & Tseng, Fan-Gang, 2019. "High-performance and low-leakage phosphoric acid fuel cell with synergic composite membrane stacking of micro glass microfiber and nano PTFE," Renewable Energy, Elsevier, vol. 134(C), pages 982-988.
    3. El-Hay, Enas A. & El-Hameed, Mohamed A. & El-Fergany, Attia A., 2018. "Performance enhancement of autonomous system comprising proton exchange membrane fuel cells and switched reluctance motor," Energy, Elsevier, vol. 163(C), pages 699-711.
    4. Hasheminasab, M. & Kermani, M.J. & Nourazar, S.S. & Khodsiani, M.H., 2020. "A novel experimental based statistical study for water management in proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 264(C).
    5. A.G. Olabi & Tabbi Wilberforce & Enas Taha Sayed & Khaled Elsaid & Mohammad Ali Abdelkareem, 2020. "Prospects of Fuel Cell Combined Heat and Power Systems," Energies, MDPI, vol. 13(16), pages 1-20, August.
    6. Andújar, J.M. & Segura, F., 2009. "Fuel cells: History and updating. A walk along two centuries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(9), pages 2309-2322, December.
    7. Chakraborty, Uttara, 2016. "Fuel crossover and internal current in proton exchange membrane fuel cell modeling," Applied Energy, Elsevier, vol. 163(C), pages 60-62.
    8. Li, Jing & Xu, Guoxiao & Luo, Xingying & Xiong, Jie & Liu, Zhao & Cai, Weiwei, 2018. "Effect of nano-size of functionalized silica on overall performance of swelling-filling modified Nafion membrane for direct methanol fuel cell application," Applied Energy, Elsevier, vol. 213(C), pages 408-414.
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    1. Andrea Baricci & Andrea Casalegno, 2023. "Experimental Analysis of Catalyst Layer Operation in a High-Temperature Proton Exchange Membrane Fuel Cell by Electrochemical Impedance Spectroscopy," Energies, MDPI, vol. 16(12), pages 1-17, June.

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