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Comparison of high-temperature and low-temperature polymer electrolyte membrane fuel cell systems with glycerol reforming process for stationary applications

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  • Authayanun, Suthida
  • Mamlouk, Mohamed
  • Scott, Keith
  • Arpornwichanop, Amornchai

Abstract

A high-temperature polymer electrolyte membrane fuel cell (HT-PEMFC) has a major advantage over a low-temperature polymer electrolyte fuel cell (LT-PEMFC) demonstrated by a tolerance to a higher CO content in the hydrogen feed and thus a simpler fuel processing. In this study, a direct comparison between the performance of HT-PEMFC and LT-PEMFC systems integrated with a glycerol steam reformer with and without a water gas shift reactor is shown. Under pure hydrogen operation, the LT-PEMFC performance is superior to the HT-PEMFC. However, the HT-PEMFC system shows good performance over the LT-PEMFC system when operated under high current density and high pressure (3atm) and using the reformate gas derived from the glycerol processor as fuel. At high current density, the high concentration of CO is the major limitation for the operation of HT-PEMFC system without water gas shift reactor, whereas the LT-PEMFC suffers from CO poisoning and restricted oxygen mass transport. Considering the system efficiency with co-heat and power generation, the HT-PEMFC system with water gas shift reactor shows the highest overall system efficiency (approximately 60%) and therefore one of the most suitable technologies for stationary applications.

Suggested Citation

  • Authayanun, Suthida & Mamlouk, Mohamed & Scott, Keith & Arpornwichanop, Amornchai, 2013. "Comparison of high-temperature and low-temperature polymer electrolyte membrane fuel cell systems with glycerol reforming process for stationary applications," Applied Energy, Elsevier, vol. 109(C), pages 192-201.
    • Handle: RePEc:eee:appene:v:109:y:2013:i:c:p:192-201
    DOI: 10.1016/j.apenergy.2013.04.009
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    References listed on IDEAS

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    2. Fantozzi, F. & Frassoldati, A. & Bartocci, P. & Cinti, G. & Quagliarini, F. & Bidini, G. & Ranzi, E.M., 2016. "An experimental and kinetic modeling study of glycerol pyrolysis," Applied Energy, Elsevier, vol. 184(C), pages 68-76.
    3. Li, Yan & Shi, Yan & Mehio, Nada & Tan, Mingsheng & Wang, Zhiyong & Hu, Xiaohong & Chen, George Z. & Dai, Sheng & Jin, Xianbo, 2016. "More sustainable electricity generation in hot and dry fuel cells with a novel hybrid membrane of Nafion/nano-silica/hydroxyl ionic liquid," Applied Energy, Elsevier, vol. 175(C), pages 451-458.
    4. Gabriele Loreti & Andrea Luigi Facci & Stefano Ubertini, 2021. "High-Efficiency Combined Heat and Power through a High-Temperature Polymer Electrolyte Membrane Fuel Cell and Gas Turbine Hybrid System," Sustainability, MDPI, vol. 13(22), pages 1-24, November.
    5. Chen, Huicui & Zhang, Ruirui & Xia, Zhifeng & Weng, Qianyao & Zhang, Tong & Pei, Pucheng, 2023. "Experimental investigation on PEM fuel cell flooding mitigation under heavy loading condition," Applied Energy, Elsevier, vol. 349(C).
    6. Löbberding, Laurens & Madlener, Reinhard, 2019. "Techno-economic analysis of micro fuel cell cogeneration and storage in Germany," Applied Energy, Elsevier, vol. 235(C), pages 1603-1613.
    7. Víctor Sanz i López & Ramon Costa-Castelló & Carles Batlle, 2022. "Literature Review of Energy Management in Combined Heat and Power Systems Based on High-Temperature Proton Exchange Membrane Fuel Cells for Residential Comfort Applications," Energies, MDPI, vol. 15(17), pages 1-22, September.
    8. Bae, Suk Joo & Kim, Seong-Joon & Lee, Jin-Hwa & Song, Inseob & Kim, Nam-In & Seo, Yongho & Kim, Ki Buem & Lee, Naesung & Park, Jun-Young, 2014. "Degradation pattern prediction of a polymer electrolyte membrane fuel cell stack with series reliability structure via durability data of single cells," Applied Energy, Elsevier, vol. 131(C), pages 48-55.
    9. Zhang, Xiaofeng & Liu, Wenjing & Pan, Jinjun & Zhao, Bin & Yi, Zhengyuan & He, Xu & Liu, Yuting & Li, Hongqiang, 2024. "Comprehensive performance assessment of a novel biomass-based CCHP system integrated with SOFC and HT-PEMFC," Energy, Elsevier, vol. 295(C).
    10. Authayanun, Suthida & Saebea, Dang & Patcharavorachot, Yaneeporn & Arpornwichanop, Amornchai, 2014. "Effect of different fuel options on performance of high-temperature PEMFC (proton exchange membrane fuel cell) systems," Energy, Elsevier, vol. 68(C), pages 989-997.
    11. Xing, Lei & Das, Prodip K. & Song, Xueguan & Mamlouk, Mohamed & Scott, Keith, 2015. "Numerical analysis of the optimum membrane/ionomer water content of PEMFCs: The interaction of Nafion® ionomer content and cathode relative humidity," Applied Energy, Elsevier, vol. 138(C), pages 242-257.

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