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Numerical investigation of hydrogen addition effects on methanol-air mixtures combustion in premixed laminar flames under lean burn conditions

Author

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  • Gong, Changming
  • Li, Zhaohui
  • Li, Dong
  • Liu, Jiajun
  • Si, Xiankai
  • Yu, Jiawei
  • Huang, Wei
  • Liu, Fenghua
  • Han, Yongqiang

Abstract

Based on the methanol oxidation and NOX reaction mechanisms, we explored the effect of hydrogen addition on the methanol oxidation reaction mechanism. We used the PREMIX subroutine in Chemkin chemical reaction dynamics analysis software, and studied the effect of hydrogen addition numerically on the main intermediate and final products in methanol premixed laminar flames under lean burn and given initial conditions such as temperature and pressure. The combustion and emission parameters in the methanol engine were researched for the addition of hydrogen in different volume ratios. The simulation results show that hydrogen addition can accelerate the methanol oxidation reaction rate and that the reaction rate increased with increase in hydrogen addition in methanol premixed laminar flames. H, O, and OH radicals can accelerate the chemical reaction rate in the flame. The maximum mole fraction of CH2O decreases with increase in hydrogen addition, which shows that hydrogen addition can reduce CH2O and has a positive influence on the environment. Temperature has little effect on NO formation in the methanol–hydrogen premixed laminar flames; the mole fraction of NO decreases with increase in hydrogen addition.

Suggested Citation

  • Gong, Changming & Li, Zhaohui & Li, Dong & Liu, Jiajun & Si, Xiankai & Yu, Jiawei & Huang, Wei & Liu, Fenghua & Han, Yongqiang, 2018. "Numerical investigation of hydrogen addition effects on methanol-air mixtures combustion in premixed laminar flames under lean burn conditions," Renewable Energy, Elsevier, vol. 127(C), pages 56-63.
    • Handle: RePEc:eee:renene:v:127:y:2018:i:c:p:56-63
    DOI: 10.1016/j.renene.2018.04.047
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    References listed on IDEAS

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    2. Gong, Changming & Li, Dong & Liu, Jiajun & Liu, Fenghua, 2024. "Numerical evaluation of ignition timing influences on performance of a stratified-charge H2/methanol dual-injection automobile engine under lean-burn condition," Energy, Elsevier, vol. 290(C).
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    4. Yangxun Liu & Weinan Liu & Huihong Liao & Wenhua Zhou & Cangsu Xu, 2021. "An Experimental and Kinetic Modelling Study on Laminar Premixed Flame Characteristics of Ethanol/Acetone Mixtures," Energies, MDPI, vol. 14(20), pages 1-18, October.
    5. Fekadu Mosisa Wako & Gianmaria Pio & Ernesto Salzano, 2020. "The Effect of Hydrogen Addition on Low-Temperature Combustion of Light Hydrocarbons and Alcohols," Energies, MDPI, vol. 13(15), pages 1-14, July.
    6. Xiao, Peng & Lee, Chia-fon & Wu, Han & Liu, Fushui, 2020. "Effects of hydrogen addition on the laminar methanol-air flame under different initial temperatures," Renewable Energy, Elsevier, vol. 154(C), pages 209-222.

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