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Effects of engine misfire on regulated, unregulated emissions from a methanol-fueled vehicle and its ozone forming potential

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  • Wang, Xin
  • Ge, Yunshan
  • Zhang, Chuanzhen
  • Tan, Jianwei
  • Hao, Lijun
  • Liu, Jia
  • Gong, Huiming

Abstract

Methanol is a feasible and promising alternative fuel for passenger cars, particularly in China. However, methanol-fueled vehicles struggle with stronger low-temperature operating instability and increased chance of misfire. In prior publications, the impacts of engine misfire on the regulated and unregulated emissions from methanol-fueled vehicles have been merely discussed. In this paper, regulated emissions, unburned methanol, carbonyl and VOC emissions from a China-5 (equivalent to Euro-5b+IUPR) certificated methanol-fueled car were measured over new European driving cycle (NEDC). By using a SAE J2901-compatible generator, two misfire rates (6% and 9%) were employed to mimic ordinary and severe engine malfunction statuses. Emission results were also put into comparison with the current Euro-5 and the upcoming Euro-6c OBD threshold limits, and used to estimate Carter MIR-based ozone forming potential. The results demonstrated that, both CO and THC emissions increased with misfire rate while NOx emission persistently decreased with intensified engine misfire. Even with a misfire rate up to 9%, all the regulated emissions were significantly lower than their thresholds regulated in Euro-5 and Euro-6c, which meant the current OBD requirements were too tolerant for methanol vehicles. It is proposed that, countries regarding methanol as a future option, shall promulgate methanol-specific emission standards in advance. Unburned methanol emission increased by at least 1.6 and 5.7 times when misfire rates of 6% and 9% were used. Both carbonyl and VOC emissions increased corresponding to higher misfire rates. Formaldehyde and toluene were found the key pollutants of carbonyls and VOCs. An increase in anticipated ozone forming potential (OFP) together with a decrease in specific reactivity (SR) was also noticed with the rising of misfire rate. Among all the pollutants, CO, toluene, xylene and formaldehyde were the chief species contributing to secondary ozone formation.

Suggested Citation

  • Wang, Xin & Ge, Yunshan & Zhang, Chuanzhen & Tan, Jianwei & Hao, Lijun & Liu, Jia & Gong, Huiming, 2016. "Effects of engine misfire on regulated, unregulated emissions from a methanol-fueled vehicle and its ozone forming potential," Applied Energy, Elsevier, vol. 177(C), pages 187-195.
    • Handle: RePEc:eee:appene:v:177:y:2016:i:c:p:187-195
    DOI: 10.1016/j.apenergy.2016.05.092
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    1. Clairotte, M. & Adam, T.W. & Zardini, A.A. & Manfredi, U. & Martini, G. & Krasenbrink, A. & Vicet, A. & Tournié, E. & Astorga, C., 2013. "Effects of low temperature on the cold start gaseous emissions from light duty vehicles fuelled by ethanol-blended gasoline," Applied Energy, Elsevier, vol. 102(C), pages 44-54.
    2. Turner, J.W.G. & Pearson, R.J. & Dekker, E. & Iosefa, B. & Johansson, K. & ac Bergström, K., 2013. "Extending the role of alcohols as transport fuels using iso-stoichiometric ternary blends of gasoline, ethanol and methanol," Applied Energy, Elsevier, vol. 102(C), pages 72-86.
    3. Vancoillie, J. & Demuynck, J. & Sileghem, L. & Van De Ginste, M. & Verhelst, S. & Brabant, L. & Van Hoorebeke, L., 2013. "The potential of methanol as a fuel for flex-fuel and dedicated spark-ignition engines," Applied Energy, Elsevier, vol. 102(C), pages 140-149.
    4. Gong, Changming & Huang, Kuo & Deng, Baoqing & Liu, Xunjun, 2011. "Catalyst light-off behavior of a spark-ignition LPG (liquefied petroleum gas) engine during cold start," Energy, Elsevier, vol. 36(1), pages 53-59.
    5. Liang, Chen & Ji, Changwei & Liu, Xiaolong, 2011. "Combustion and emissions performance of a DME-enriched spark-ignited methanol engine at idle condition," Applied Energy, Elsevier, vol. 88(11), pages 3704-3711.
    6. Qi, D.H. & Chen, H. & Geng, L.M. & Bian, Y.ZH. & Ren, X.CH., 2010. "Performance and combustion characteristics of biodiesel-diesel-methanol blend fuelled engine," Applied Energy, Elsevier, vol. 87(5), pages 1679-1686, May.
    7. Liang, Chen & Ji, Changwei & Gao, Binbin, 2013. "Load characteristics of a spark-ignited ethanol engine with DME enrichment," Applied Energy, Elsevier, vol. 112(C), pages 500-506.
    8. Pérez-Fortes, Mar & Schöneberger, Jan C. & Boulamanti, Aikaterini & Tzimas, Evangelos, 2016. "Methanol synthesis using captured CO2 as raw material: Techno-economic and environmental assessment," Applied Energy, Elsevier, vol. 161(C), pages 718-732.
    9. Vancoillie, J. & Sileghem, L. & Verhelst, S., 2014. "Development and validation of a quasi-dimensional model for methanol and ethanol fueled SI engines," Applied Energy, Elsevier, vol. 132(C), pages 412-425.
    10. Bahri, Bahram & Aziz, Azhar Abdul & Shahbakhti, Mahdi & Muhamad Said, Mohd Farid, 2013. "Understanding and detecting misfire in an HCCI engine fuelled with ethanol," Applied Energy, Elsevier, vol. 108(C), pages 24-33.
    11. Chmielniak, Tomasz & Sciazko, Marek, 2003. "Co-gasification of biomass and coal for methanol synthesis," Applied Energy, Elsevier, vol. 74(3-4), pages 393-403, March.
    12. Poran, Arnon & Tartakovsky, Leonid, 2015. "Energy efficiency of a direct-injection internal combustion engine with high-pressure methanol steam reforming," Energy, Elsevier, vol. 88(C), pages 506-514.
    13. Wang, Xin & Ge, Yunshan & Liu, Linlin & Peng, Zihang & Hao, Lijun & Yin, Hang & Ding, Yan & Wang, Junfang, 2015. "Evaluation on toxic reduction and fuel economy of a gasoline direct injection- (GDI-) powered passenger car fueled with methanol–gasoline blends with various substitution ratios," Applied Energy, Elsevier, vol. 157(C), pages 134-143.
    14. Zhang, Bo & Ji, Changwei & Wang, Shuofeng & Liu, Xiaolong, 2014. "Combustion and emissions characteristics of a spark-ignition engine fueled with hydrogen–methanol blends under lean and various loads conditions," Energy, Elsevier, vol. 74(C), pages 829-835.
    15. Mat Yasin, M.H. & Yusaf, Talal & Mamat, R. & Fitri Yusop, A., 2014. "Characterization of a diesel engine operating with a small proportion of methanol as a fuel additive in biodiesel blend," Applied Energy, Elsevier, vol. 114(C), pages 865-873.
    16. Agarwal, Avinash Kumar & Shukla, Pravesh Chandra & Gupta, Jai Gopal & Patel, Chetankumar & Prasad, Rajesh Kumar & Sharma, Nikhil, 2015. "Unregulated emissions from a gasohol (E5, E15, M5, and M15) fuelled spark ignition engine," Applied Energy, Elsevier, vol. 154(C), pages 732-741.
    17. Li, Yaopeng & Jia, Ming & Liu, Yaodong & Xie, Maozhao, 2013. "Numerical study on the combustion and emission characteristics of a methanol/diesel reactivity controlled compression ignition (RCCI) engine," Applied Energy, Elsevier, vol. 106(C), pages 184-197.
    18. Costagliola, M.A. & De Simio, L. & Iannaccone, S. & Prati, M.V., 2013. "Combustion efficiency and engine out emissions of a S.I. engine fueled with alcohol/gasoline blends," Applied Energy, Elsevier, vol. 111(C), pages 1162-1171.
    19. Yao, Yung-Chen & Tsai, Jiun-Horng & Wang, I-Ting, 2013. "Emissions of gaseous pollutant from motorcycle powered by ethanol–gasoline blend," Applied Energy, Elsevier, vol. 102(C), pages 93-100.
    20. Zhou, D.Z. & Yang, W.M. & An, H. & Li, J., 2015. "Application of CFD-chemical kinetics approach in detecting RCCI engine knocking fuelled with biodiesel/methanol," Applied Energy, Elsevier, vol. 145(C), pages 255-264.
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