IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v96y2016icp314-324.html
   My bibliography  Save this article

Synergistic effect of boron/nitrogen co-doping into graphene and intercalation of carbon black for Pt-BCN-Gr/CB hybrid catalyst on cell performance of polymer electrolyte membrane fuel cell

Author

Listed:
  • Lee, W.H.
  • Yang, H.N.
  • Park, K.W.
  • Choi, B.S.
  • Yi, S.C.
  • Kim, W.J.

Abstract

Boron and nitrogen were successfully co-doped into graphene (Gr) nanosheets to which Pt nanoparticles with ∼3.7 nm are uniformly deposited on BCN-Gr. Pt content on BCN-Gr is estimated to be 50 wt.% by TG/DTA analysis. Pt-BCN-Gr is intercalated by different amount of CB (carbon black), and it is designated as Pt-BCN-Gr/CBx (x = 0.0, 0.3, 0.4, 0.5 and 0.6). The membrane electrode assembly is fabricated with commercial Pt-C and Pt-BCN-Gr/CBx as anode and cathode catalysts, respectively. The cell performance is highly consistent with electrochemical active surface area and the best cell performance of 0.54 W/cm2 in power density is achieved for Pt-BCN-Gr/CB0.5. The results show that positive effect of B and N co-doping on cell performance becomes more significant for lower intercalated CB content. Direct comparison between Pt-BCN-Gr/CB and Pt-Gr/CB clearly exhibits that Pt-BCN-Gr/CB shows better cell performance for Pt-BCN-Gr/CB than Pt-Gr/CB at lower CB content. About 28%–157% in cell performance at 0.6 V has been enhanced by B and N co-doping compared with that of Pt-Gr/CB. The enhancement in cell performance and durability is probably attributed to the synergistic effect by B and N co-doping and intercalation by CB.

Suggested Citation

  • Lee, W.H. & Yang, H.N. & Park, K.W. & Choi, B.S. & Yi, S.C. & Kim, W.J., 2016. "Synergistic effect of boron/nitrogen co-doping into graphene and intercalation of carbon black for Pt-BCN-Gr/CB hybrid catalyst on cell performance of polymer electrolyte membrane fuel cell," Energy, Elsevier, vol. 96(C), pages 314-324.
    • Handle: RePEc:eee:energy:v:96:y:2016:i:c:p:314-324
    DOI: 10.1016/j.energy.2015.12.088
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544215017338
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2015.12.088?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Chou, Chang-Chen & Liu, Cheng-Hong & Chen, Bing-Hung, 2014. "Effects of reduction temperature and pH value of polyol process on reduced graphene oxide supported Pt electrocatalysts for oxygen reduction reaction," Energy, Elsevier, vol. 70(C), pages 231-238.
    2. Ok-Hee Kim & Yong-Hun Cho & Soon Hyung Kang & Hee-Young Park & Minhyoung Kim & Ju Wan Lim & Dong Young Chung & Myeong Jae Lee & Heeman Choe & Yung-Eun Sung, 2013. "Ordered macroporous platinum electrode and enhanced mass transfer in fuel cells using inverse opal structure," Nature Communications, Nature, vol. 4(1), pages 1-9, December.
    3. Carton, J.G. & Lawlor, V. & Olabi, A.G. & Hochenauer, C. & Zauner, G., 2012. "Water droplet accumulation and motion in PEM (Proton Exchange Membrane) fuel cell mini-channels," Energy, Elsevier, vol. 39(1), pages 63-73.
    4. Wang, Yun & Chen, Ken S. & Mishler, Jeffrey & Cho, Sung Chan & Adroher, Xavier Cordobes, 2011. "A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research," Applied Energy, Elsevier, vol. 88(4), pages 981-1007, April.
    5. Wang, Kai & Li, Liwei & Zhang, Tiezhu & Liu, Zaifei, 2014. "Nitrogen-doped graphene for supercapacitor with long-term electrochemical stability," Energy, Elsevier, vol. 70(C), pages 612-617.
    6. Djilali, N., 2007. "Computational modelling of polymer electrolyte membrane (PEM) fuel cells: Challenges and opportunities," Energy, Elsevier, vol. 32(4), pages 269-280.
    7. Rahimi, Sahand & Meratizaman, Mousa & Monadizadeh, Sina & Amidpour, Majid, 2014. "Techno-economic analysis of wind turbine–PEM (polymer electrolyte membrane) fuel cell hybrid system in standalone area," Energy, Elsevier, vol. 67(C), pages 381-396.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Han, Chaoling & Chen, Zhenqian, 2021. "Study on the synergism of thermal transport and electrochemical of PEMFC based on N, P co-doped graphene substrate electrode," Energy, Elsevier, vol. 214(C).
    2. Dasari, Bhagya Lakshmi & Nouri, Jamshid M. & Brabazon, Dermot & Naher, Sumsun, 2017. "Graphene and derivatives – Synthesis techniques, properties and their energy applications," Energy, Elsevier, vol. 140(P1), pages 766-778.
    3. Kiyani, Roya & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Nitrogen doped graphene supported palladium-cobalt as a promising catalyst for methanol oxidation reaction: Synthesis, characterization and electrocatalytic performance," Energy, Elsevier, vol. 113(C), pages 1162-1173.
    4. Beltrán-Gastélum, M. & Salazar-Gastélum, M.I. & Flores-Hernández, J.R. & Botte, G.G. & Pérez-Sicairos, S. & Romero-Castañon, T. & Reynoso-Soto, E. & Félix-Navarro, R.M., 2019. "Pt-Au nanoparticles on graphene for oxygen reduction reaction: Stability and performance on proton exchange membrane fuel cell," Energy, Elsevier, vol. 181(C), pages 1225-1234.
    5. Ji, Zhaoqi & Perez-Page, Maria & Chen, Jianuo & Rodriguez, Romeo Gonzalez & Cai, Rongsheng & Haigh, Sarah J. & Holmes, Stuart M., 2021. "A structured catalyst support combining electrochemically exfoliated graphene oxide and carbon black for enhanced performance and durability in low-temperature hydrogen fuel cells," Energy, Elsevier, vol. 226(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Junye, 2015. "Theory and practice of flow field designs for fuel cell scaling-up: A critical review," Applied Energy, Elsevier, vol. 157(C), pages 640-663.
    2. Xing, Lei & Du, Shangfeng & Chen, Rui & Mamlouk, Mohamed & Scott, Keith, 2016. "Anode partial flooding modelling of proton exchange membrane fuel cells: Model development and validation," Energy, Elsevier, vol. 96(C), pages 80-95.
    3. Stoševski, Ivan & Krstić, Jelena & Milikić, Jadranka & Šljukić, Biljana & Kačarević-Popović, Zorica & Mentus, Slavko & Miljanić, Šćepan, 2016. "Radiolitically synthesized nano Ag/C catalysts for oxygen reduction and borohydride oxidation reactions in alkaline media, for potential applications in fuel cells," Energy, Elsevier, vol. 101(C), pages 79-90.
    4. Bruni, G. & Cordiner, S. & Mulone, V., 2014. "Domestic distributed power generation: Effect of sizing and energy management strategy on the environmental efficiency of a photovoltaic-battery-fuel cell system," Energy, Elsevier, vol. 77(C), pages 133-143.
    5. Xing, Lei & Cai, Qiong & Xu, Chenxi & Liu, Chunbo & Scott, Keith & Yan, Yongsheng, 2016. "Numerical study of the effect of relative humidity and stoichiometric flow ratio on PEM (proton exchange membrane) fuel cell performance with various channel lengths: An anode partial flooding modelli," Energy, Elsevier, vol. 106(C), pages 631-645.
    6. Xing, Lei & Liu, Xiaoteng & Alaje, Taiwo & Kumar, Ravi & Mamlouk, Mohamed & Scott, Keith, 2014. "A two-phase flow and non-isothermal agglomerate model for a proton exchange membrane (PEM) fuel cell," Energy, Elsevier, vol. 73(C), pages 618-634.
    7. Yin, Cong & Gao, Jianlong & Wen, Xuhui & Xie, Guangyou & Yang, Chunhua & Fang, Honglin & Tang, Hao, 2016. "In situ investigation of proton exchange membrane fuel cell performance with novel segmented cell design and a two-phase flow model," Energy, Elsevier, vol. 113(C), pages 1071-1089.
    8. Zhang, Xiaoqing & Yang, Jiapei & Ma, Xiao & Zhuge, Weilin & Shuai, Shijin, 2022. "Modelling and analysis on effects of penetration of microporous layer into gas diffusion layer in PEM fuel cells: Focusing on mass transport," Energy, Elsevier, vol. 254(PA).
    9. Abdollahzadeh, M. & Ribeirinha, P. & Boaventura, M. & Mendes, A., 2018. "Three-dimensional modeling of PEMFC with contaminated anode fuel," Energy, Elsevier, vol. 152(C), pages 939-959.
    10. Sun, Zhe & Wang, Ning & Bi, Yunrui & Srinivasan, Dipti, 2015. "Parameter identification of PEMFC model based on hybrid adaptive differential evolution algorithm," Energy, Elsevier, vol. 90(P2), pages 1334-1341.
    11. Bruni, G. & Cordiner, S. & Mulone, V. & Sinisi, V. & Spagnolo, F., 2016. "Energy management in a domestic microgrid by means of model predictive controllers," Energy, Elsevier, vol. 108(C), pages 119-131.
    12. Xu, Liangfei & Fang, Chuan & Hu, Junming & Cheng, Siliang & Li, Jianqiu & Ouyang, Minggao & Lehnert, Werner, 2017. "Parameter extraction of polymer electrolyte membrane fuel cell based on quasi-dynamic model and periphery signals," Energy, Elsevier, vol. 122(C), pages 675-690.
    13. Yang, H.N. & Lee, W.H. & Choi, B.S. & Ko, Y.D. & Yi, S.C. & Kim, W.J., 2017. "Self-humidifying Pt-C/Pt-TiO2 dual-catalyst electrode membrane assembly for proton-exchange membrane fuel cells," Energy, Elsevier, vol. 120(C), pages 12-19.
    14. Rahnavard, Aylin & Rowshanzamir, Soosan & Parnian, Mohammad Javad & Amirkhanlou, Gholam Reza, 2015. "The effect of sulfonated poly (ether ether ketone) as the electrode ionomer for self-humidifying nanocomposite proton exchange membrane fuel cells," Energy, Elsevier, vol. 82(C), pages 746-757.
    15. Kong, Im Mo & Jung, Aeri & Kim, Young Sang & Kim, Min Soo, 2017. "Numerical investigation on double gas diffusion backing layer functionalized on water removal in a proton exchange membrane fuel cell," Energy, Elsevier, vol. 120(C), pages 478-487.
    16. Carton, J.G. & Olabi, A.G., 2017. "Three-dimensional proton exchange membrane fuel cell model: Comparison of double channel and open pore cellular foam flow plates," Energy, Elsevier, vol. 136(C), pages 185-195.
    17. Mirzaei, Farokh & Parnian, Mohammad Javad & Rowshanzamir, Soosan, 2017. "Durability investigation and performance study of hydrothermal synthesized platinum-multi walled carbon nanotube nanocomposite catalyst for proton exchange membrane fuel cell," Energy, Elsevier, vol. 138(C), pages 696-705.
    18. Iranzo, Alfredo & Boillat, Pierre & Oberholzer, Pierre & Guerra, José, 2014. "A novel approach coupling neutron imaging and numerical modelling for the analysis of the impact of water on fuel cell performance," Energy, Elsevier, vol. 68(C), pages 971-981.
    19. Bizon, Nicu & Radut, Marin & Oproescu, Mihai, 2015. "Energy control strategies for the Fuel Cell Hybrid Power Source under unknown load profile," Energy, Elsevier, vol. 86(C), pages 31-41.
    20. Boyacı San, Fatma Gül & İyigün Karadağ, Çiğdem & Okur, Osman & Okumuş, Emin, 2016. "Optimization of the catalyst loading for the direct borohydride fuel cell," Energy, Elsevier, vol. 114(C), pages 214-224.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:96:y:2016:i:c:p:314-324. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.