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Comprehensive modeling of tubular solid oxide electrolysis cell for co-electrolysis of steam and carbon dioxide

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  • Luo, Yu
  • Shi, Yixiang
  • Li, Wenying
  • Cai, Ningsheng

Abstract

A two-dimensional (2D) model is developed to analyze the performance and efficiency of H2O/CO2 co-electrolysis in tubular SOEC (solid oxide electrolysis cell). The model fully considers the fluid flow, heat/mass transfer and electrochemical/chemical reactions in the SOEC. The results show that RWGSR (reversed water-gas shift reaction) significantly promotes CO2 conversion ratio. The effect of important operating parameters was comprehensively studied and optimal operating condition was determined. When the inlet gas flows in parallel flow mode with the velocity of 1 m s−1, TSOEC with the H2O/CO2 molar ratio of 1 at 700 °C at 1.4 V achieves the highest efficiency of 59.4% and the syngas conversion ratio of 43.8%. Lowering gas flow velocity decreases the syngas yield but promotes H2O/CO2 convert ratio and efficiency. Finally, calculation found that counter flow is superior to parallel flow.

Suggested Citation

  • Luo, Yu & Shi, Yixiang & Li, Wenying & Cai, Ningsheng, 2014. "Comprehensive modeling of tubular solid oxide electrolysis cell for co-electrolysis of steam and carbon dioxide," Energy, Elsevier, vol. 70(C), pages 420-434.
    • Handle: RePEc:eee:energy:v:70:y:2014:i:c:p:420-434
    DOI: 10.1016/j.energy.2014.04.019
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    16. Xu, Haoran & Chen, Bin & Tan, Peng & Cai, Weizi & Wu, Yiyang & Zhang, Houcheng & Ni, Meng, 2018. "A feasible way to handle the heat management of direct carbon solid oxide fuel cells," Applied Energy, Elsevier, vol. 226(C), pages 881-890.
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    18. Luo, Yu & Wu, Xiao-yu & Shi, Yixiang & Ghoniem, Ahmed F. & Cai, Ningsheng, 2018. "Exergy analysis of an integrated solid oxide electrolysis cell-methanation reactor for renewable energy storage," Applied Energy, Elsevier, vol. 215(C), pages 371-383.
    19. Xiao, Gang & Sun, Anwei & Liu, Hongwei & Ni, Meng & Xu, Haoran, 2023. "Thermal management of reversible solid oxide cells in the dynamic mode switching," Applied Energy, Elsevier, vol. 331(C).
    20. Xu, Haoran & Chen, Bin & Tan, Peng & Xuan, Jin & Maroto-Valer, M. Mercedes & Farrusseng, David & Sun, Qiong & Ni, Meng, 2019. "Modeling of all-porous solid oxide fuel cells with a focus on the electrolyte porosity design," Applied Energy, Elsevier, vol. 235(C), pages 602-611.
    21. Xu, Haoran & Chen, Bin & Tan, Peng & Cai, Weizi & He, Wei & Farrusseng, David & Ni, Meng, 2018. "Modeling of all porous solid oxide fuel cells," Applied Energy, Elsevier, vol. 219(C), pages 105-113.
    22. Sun, Yi & Qian, Tang & Zhu, Jingdong & Zheng, Nan & Han, Yu & Xiao, Gang & Ni, Meng & Xu, Haoran, 2023. "Dynamic simulation of a reversible solid oxide cell system for efficient H2 production and power generation," Energy, Elsevier, vol. 263(PA).
    23. Luo, Yu & Shi, Yixiang & Zheng, Yi & Gang, Zhongxue & Cai, Ningsheng, 2017. "Mutual information for evaluating renewable power penetration impacts in a distributed generation system," Energy, Elsevier, vol. 141(C), pages 290-303.
    24. Jianguo Zhao & Zihan Lin & Mingjue Zhou, 2022. "Three-Dimensional Modeling and Performance Study of High Temperature Solid Oxide Electrolysis Cell with Metal Foam," Sustainability, MDPI, vol. 14(12), pages 1-17, June.
    25. Nielsen, Anders S. & Peppley, Brant A. & Burheim, Odne S., 2023. "Controlling the contribution of transport mechanisms in solid oxide co-electrolysis cells to improve product selectivity and performance: A theoretical framework," Applied Energy, Elsevier, vol. 344(C).

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