IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v66y2014icp881-890.html
   My bibliography  Save this article

Nano-encapsulated organic phase change material based on copolymer nanocomposites for thermal energy storage

Author

Listed:
  • Tumirah, K.
  • Hussein, M.Z.
  • Zulkarnain, Z.
  • Rafeadah, R.

Abstract

This study deals with fabrication, physico–chemical characterizations and thermal properties of n-octadecane nanocapsules as organic PCM (phase change materials) for TES (thermal energy storage). Nano-encapsulated organic PCM was fabricated by encapsulation of n-octadecane as a core with St (styrene) – MMA (methylmethacrylate) copolymer shell using miniemulsion in-situ polymerization method. The influence of St/MMA and n-octadecane/copolymer mass ratio on the encapsulation processes, physico–chemical and thermal properties of the resulting nanocapsules has been studied systematically. DSC (differential scanning calorimeter) analysis indicated that the n-octadecane in the nanocapsules form melts at 29.5 °C and crystallize at 24.6 °C. N-octadecane nanocapsules has an enthalpy of 107.9 and 104.9 Jg-1 for melting and crystallization, respectively. TGA (thermal gravimetric analysis) thermograms showed that the nano-encapsulated organic PCM degraded in two distinguishable steps and has a good chemical stability. The thermal cycling test of the nanocapsules was carried out for 360 heating/cooling cycles and indicates that the developed nanomaterial has good chemical stability and thermal reliability. Based on all the results obtained, it can be concluded that n-octadecane/St-MMA nanocapsules have potential for thermal energy storage for buildings and other applications.

Suggested Citation

  • Tumirah, K. & Hussein, M.Z. & Zulkarnain, Z. & Rafeadah, R., 2014. "Nano-encapsulated organic phase change material based on copolymer nanocomposites for thermal energy storage," Energy, Elsevier, vol. 66(C), pages 881-890.
    • Handle: RePEc:eee:energy:v:66:y:2014:i:c:p:881-890
    DOI: 10.1016/j.energy.2014.01.033
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544214000413
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2014.01.033?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Regin, A. Felix & Solanki, S.C. & Saini, J.S., 2008. "Heat transfer characteristics of thermal energy storage system using PCM capsules: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(9), pages 2438-2458, December.
    2. Medrano, Marc & Gil, Antoni & Martorell, Ingrid & Potau, Xavi & Cabeza, Luisa F., 2010. "State of the art on high-temperature thermal energy storage for power generation. Part 2--Case studies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(1), pages 56-72, January.
    3. Li, Wei & Song, Guolin & Tang, Guoyi & Chu, Xiaodong & Ma, Sude & Liu, Caifeng, 2011. "Morphology, structure and thermal stability of microencapsulated phase change material with copolymer shell," Energy, Elsevier, vol. 36(2), pages 785-791.
    4. Tyagi, V.V. & Kaushik, S.C. & Tyagi, S.K. & Akiyama, T., 2011. "Development of phase change materials based microencapsulated technology for buildings: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(2), pages 1373-1391, February.
    5. Qiu, Xiaolin & Li, Wei & Song, Guolin & Chu, Xiaodong & Tang, Guoyi, 2012. "Microencapsulated n-octadecane with different methylmethacrylate-based copolymer shells as phase change materials for thermal energy storage," Energy, Elsevier, vol. 46(1), pages 188-199.
    6. SarI, Ahmet & Alkan, Cemil & Karaipekli, Ali, 2010. "Preparation, characterization and thermal properties of PMMA/n-heptadecane microcapsules as novel solid-liquid microPCM for thermal energy storage," Applied Energy, Elsevier, vol. 87(5), pages 1529-1534, May.
    7. Koca, Ahmet & Oztop, Hakan F. & Koyun, Tansel & Varol, Yasin, 2008. "Energy and exergy analysis of a latent heat storage system with phase change material for a solar collector," Renewable Energy, Elsevier, vol. 33(4), pages 567-574.
    8. Hawlader, M. N. A. & Uddin, M. S. & Khin, Mya Mya, 2003. "Microencapsulated PCM thermal-energy storage system," Applied Energy, Elsevier, vol. 74(1-2), pages 195-202, January.
    9. Kenisarin, Murat & Mahkamov, Khamid, 2007. "Solar energy storage using phase change materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(9), pages 1913-1965, December.
    10. Jegadheeswaran, S. & Pohekar, Sanjay D., 2009. "Performance enhancement in latent heat thermal storage system: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(9), pages 2225-2244, December.
    11. Pasupathy, A. & Velraj, R. & Seeniraj, R.V., 2008. "Phase change material-based building architecture for thermal management in residential and commercial establishments," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(1), pages 39-64, January.
    12. Tahan Latibari, Sara & Mehrali, Mohammad & Mehrali, Mehdi & Indra Mahlia, Teuku Meurah & Cornelis Metselaar, Hendrik Simon, 2013. "Synthesis, characterization and thermal properties of nanoencapsulated phase change materials via sol–gel method," Energy, Elsevier, vol. 61(C), pages 664-672.
    13. Xia, L. & Zhang, P. & Wang, R.Z., 2010. "Numerical heat transfer analysis of the packed bed latent heat storage system based on an effective packed bed model," Energy, Elsevier, vol. 35(5), pages 2022-2032.
    14. Gil, Antoni & Medrano, Marc & Martorell, Ingrid & Lázaro, Ana & Dolado, Pablo & Zalba, Belén & Cabeza, Luisa F., 2010. "State of the art on high temperature thermal energy storage for power generation. Part 1--Concepts, materials and modellization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(1), pages 31-55, January.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Tahan Latibari, Sara & Mehrali, Mohammad & Mehrali, Mehdi & Afifi, Amalina Binti Muhammad & Mahlia, Teuku Meurah Indra & Akhiani, Amir Reza & Metselaar, Hendrik Simon Cornelis, 2015. "Facile synthesis and thermal performances of stearic acid/titania core/shell nanocapsules by sol–gel method," Energy, Elsevier, vol. 85(C), pages 635-644.
    2. Dubey, Abhayjeet kumar & Sun, Jingyi & Choudhary, Tushar & Dash, Madhusmita & Rakshit, Dibakar & Ansari, M Zahid & Ramakrishna, Seeram & Liu, Yong & Nanda, Himansu Sekhar, 2023. "Emerging phase change materials with improved thermal efficiency for a clean and sustainable environment: An approach towards net zero," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).
    3. Nassima Radouane, 2022. "A Comprehensive Review of Composite Phase Change Materials (cPCMs) for Thermal Management Applications, Including Manufacturing Processes, Performance, and Applications," Energies, MDPI, vol. 15(21), pages 1-28, November.
    4. Ma, F. & Chen, J. & Zhang, P., 2018. "Experimental study of the hydraulic and thermal performances of nano-sized phase change emulsion in horizontal mini-tubes," Energy, Elsevier, vol. 149(C), pages 944-953.
    5. Zhang, Nan & Yuan, Yanping & Du, Yanxia & Cao, Xiaoling & Yuan, Yaguang, 2014. "Preparation and properties of palmitic-stearic acid eutectic mixture/expanded graphite composite as phase change material for energy storage," Energy, Elsevier, vol. 78(C), pages 950-956.
    6. Wang, Jin & Yu, Kai & Duan, Runze & Xie, Gongnan & Sundén, Bengt, 2021. "Enhanced thermal management by introducing nanoparticle composite phase change materials for cooling multiple heat sources systems," Energy, Elsevier, vol. 227(C).
    7. Ke, Huizhen & Ghulam, Mohy uddin Hafiz & Li, Yonggui & Wang, Jing & Peng, Bin & Cai, Yibing & Wei, Qufu, 2016. "Ag-coated polyurethane fibers membranes absorbed with quinary fatty acid eutectics solid-liquid phase change materials for storage and retrieval of thermal energy," Renewable Energy, Elsevier, vol. 99(C), pages 1-9.
    8. Obai Younis & Sameh E. Ahmed & Aissa Abderrahmane & Abdulaziz Alenazi & Ahmed M. Hassan, 2023. "Hydrothermal Mixed Convection in a Split-Lid-Driven Triangular Cavity Suspended by NEPCM," Mathematics, MDPI, vol. 11(6), pages 1-17, March.
    9. Koide, Hiroaki & Kurniawan, Ade & Takahashi, Tatsuya & Kawaguchi, Takahiro & Sakai, Hiroki & Sato, Yusuke & Chiu, Justin NW. & Nomura, Takahiro, 2022. "Performance analysis of packed bed latent heat storage system for high-temperature thermal energy storage using pellets composed of micro-encapsulated phase change material," Energy, Elsevier, vol. 238(PC).
    10. Xinghui Zhang & Qili Shi & Lingai Luo & Yilin Fan & Qian Wang & Guanguan Jia, 2021. "Research Progress on the Phase Change Materials for Cold Thermal Energy Storage," Energies, MDPI, vol. 14(24), pages 1-46, December.
    11. Sarı, Ahmet & Alkan, Cemil & Bilgin, Cahit, 2014. "Micro/nano encapsulation of some paraffin eutectic mixtures with poly(methyl methacrylate) shell: Preparation, characterization and latent heat thermal energy storage properties," Applied Energy, Elsevier, vol. 136(C), pages 217-227.
    12. Zhang, H.L. & Baeyens, J. & Degrève, J. & Cáceres, G. & Segal, R. & Pitié, F., 2014. "Latent heat storage with tubular-encapsulated phase change materials (PCMs)," Energy, Elsevier, vol. 76(C), pages 66-72.
    13. Tafavogh, Mahyar & Zahedi, Alireza, 2022. "Improving the performance of home heating system with the help of optimally produced heat storage nanocapsules," Renewable Energy, Elsevier, vol. 181(C), pages 1276-1293.
    14. Nourani, Moloud & Hamdami, Nasser & Keramat, Javad & Moheb, Ahmad & Shahedi, Mohammad, 2016. "Thermal behavior of paraffin-nano-Al2O3 stabilized by sodium stearoyl lactylate as a stable phase change material with high thermal conductivity," Renewable Energy, Elsevier, vol. 88(C), pages 474-482.
    15. Yu, Jinghua & Leng, Kangxin & Ye, Hong & Xu, Xinhua & Luo, Yongqiang & Wang, Jinbo & Yang, Xie & Yang, Qingchen & Gang, Wenjie, 2020. "Study on thermal insulation characteristics and optimized design of pipe-embedded ventilation roof with outer-layer shape-stabilized PCM in different climate zones," Renewable Energy, Elsevier, vol. 147(P1), pages 1609-1622.
    16. He, Yayue & Li, Wei & Han, Na & Wang, Jianping & Zhang, Xingxiang, 2019. "Facile flexible reversible thermochromic membranes based on micro/nanoencapsulated phase change materials for wearable temperature sensor," Applied Energy, Elsevier, vol. 247(C), pages 615-629.
    17. Li, Wenqiang & Zhang, Duo & Jing, Tingting & Gao, Mingyu & Liu, Peijin & He, Guoqiang & Qin, Fei, 2018. "Nano-encapsulated phase change material slurry (Nano-PCMS) saturated in metal foam: A new stable and efficient strategy for passive thermal management," Energy, Elsevier, vol. 165(PA), pages 743-751.
    18. Xia, Mingzhu & Yuan, Yanping & Zhao, Xudong & Cao, Xiaoling & Tang, Zhonghua, 2016. "Cold storage condensation heat recovery system with a novel composite phase change material," Applied Energy, Elsevier, vol. 175(C), pages 259-268.
    19. Alam, Tanvir E. & Dhau, Jaspreet S. & Goswami, D. Yogi & Stefanakos, Elias, 2015. "Macroencapsulation and characterization of phase change materials for latent heat thermal energy storage systems," Applied Energy, Elsevier, vol. 154(C), pages 92-101.
    20. Tafavogh, Mahyar & Zahedi, Alireza, 2021. "Design and production of a novel encapsulated nano phase change materials to improve thermal efficiency of a quintuple renewable geothermal/hydro/biomass/solar/wind hybrid system," Renewable Energy, Elsevier, vol. 169(C), pages 358-378.
    21. Nikpourian, Hediyeh & Bahramian, Ahmad Reza & Abdollahi, Mahdi, 2020. "On the thermal performance of a novel PCM nanocapsule: The effect of core/shell," Renewable Energy, Elsevier, vol. 151(C), pages 322-331.
    22. Gupta, Rajan & Shinde, Shraddha & Yella, Aswani & Subramaniam, C. & Saha, Sandip K., 2020. "Thermomechanical characterisations of PTFE, PEEK, PEKK as encapsulation materials for medium temperature solar applications," Energy, Elsevier, vol. 194(C).
    23. Han, Pengju & Lu, Lixin & Qiu, Xiaolin & Tang, Yali & Wang, Jun, 2015. "Preparation and characterization of macrocapsules containing microencapsulated PCMs (phase change materials) for thermal energy storage," Energy, Elsevier, vol. 91(C), pages 531-539.
    24. Bi, Yuehong & Liu, Xiao & Jiang, Minghe, 2014. "Exergy analysis of a gas-hydrate cool storage system," Energy, Elsevier, vol. 73(C), pages 908-915.
    25. Royo, Patricia & Ferreira, Víctor J. & López-Sabirón, Ana M. & Ferreira, Germán, 2016. "Hybrid diagnosis to characterise the energy and environmental enhancement of photovoltaic modules using smart materials," Energy, Elsevier, vol. 101(C), pages 174-189.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Qiu, Xiaolin & Li, Wei & Song, Guolin & Chu, Xiaodong & Tang, Guoyi, 2012. "Microencapsulated n-octadecane with different methylmethacrylate-based copolymer shells as phase change materials for thermal energy storage," Energy, Elsevier, vol. 46(1), pages 188-199.
    2. Zeinelabdein, Rami & Omer, Siddig & Gan, Guohui, 2018. "Critical review of latent heat storage systems for free cooling in buildings," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2843-2868.
    3. Fernandes, D. & Pitié, F. & Cáceres, G. & Baeyens, J., 2012. "Thermal energy storage: “How previous findings determine current research priorities”," Energy, Elsevier, vol. 39(1), pages 246-257.
    4. Mohamed, Shamseldin A. & Al-Sulaiman, Fahad A. & Ibrahim, Nasiru I. & Zahir, Md. Hasan & Al-Ahmed, Amir & Saidur, R. & Yılbaş, B.S. & Sahin, A.Z., 2017. "A review on current status and challenges of inorganic phase change materials for thermal energy storage systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 1072-1089.
    5. Sarı, Ahmet & Alkan, Cemil & Bilgin, Cahit, 2014. "Micro/nano encapsulation of some paraffin eutectic mixtures with poly(methyl methacrylate) shell: Preparation, characterization and latent heat thermal energy storage properties," Applied Energy, Elsevier, vol. 136(C), pages 217-227.
    6. Memon, Shazim Ali, 2014. "Phase change materials integrated in building walls: A state of the art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 870-906.
    7. Ge, Haoshan & Li, Haiyan & Mei, Shengfu & Liu, Jing, 2013. "Low melting point liquid metal as a new class of phase change material: An emerging frontier in energy area," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 331-346.
    8. Kenisarin, Murat & Mahkamov, Khamid, 2016. "Passive thermal control in residential buildings using phase change materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 371-398.
    9. Islam, Md. Parvez & Morimoto, Tetsuo, 2018. "Advances in low to medium temperature non-concentrating solar thermal technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2066-2093.
    10. Li, Y.Q. & He, Y.L. & Song, H.J. & Xu, C. & Wang, W.W., 2013. "Numerical analysis and parameters optimization of shell-and-tube heat storage unit using three phase change materials," Renewable Energy, Elsevier, vol. 59(C), pages 92-99.
    11. Salunkhe, Pramod B. & Shembekar, Prashant S., 2012. "A review on effect of phase change material encapsulation on the thermal performance of a system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 5603-5616.
    12. Giro-Paloma, Jessica & Martínez, Mònica & Cabeza, Luisa F. & Fernández, A. Inés, 2016. "Types, methods, techniques, and applications for microencapsulated phase change materials (MPCM): A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1059-1075.
    13. Gupta, Rajan & Shinde, Shraddha & Yella, Aswani & Subramaniam, C. & Saha, Sandip K., 2020. "Thermomechanical characterisations of PTFE, PEEK, PEKK as encapsulation materials for medium temperature solar applications," Energy, Elsevier, vol. 194(C).
    14. Yataganbaba, Alptug & Ozkahraman, Bengi & Kurtbas, Irfan, 2017. "Worldwide trends on encapsulation of phase change materials: A bibliometric analysis (1990–2015)," Applied Energy, Elsevier, vol. 185(P1), pages 720-731.
    15. M. Mofijur & Teuku Meurah Indra Mahlia & Arridina Susan Silitonga & Hwai Chyuan Ong & Mahyar Silakhori & Muhammad Heikal Hasan & Nandy Putra & S.M. Ashrafur Rahman, 2019. "Phase Change Materials (PCM) for Solar Energy Usages and Storage: An Overview," Energies, MDPI, vol. 12(16), pages 1-20, August.
    16. Soares, N. & Bastos, J. & Pereira, L. Dias & Soares, A. & Amaral, A.R. & Asadi, E. & Rodrigues, E. & Lamas, F.B. & Monteiro, H. & Lopes, M.A.R. & Gaspar, A.R., 2017. "A review on current advances in the energy and environmental performance of buildings towards a more sustainable built environment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 845-860.
    17. Yin, Dezhong & Ma, Li & Liu, Jinjie & Zhang, Qiuyu, 2014. "Pickering emulsion: A novel template for microencapsulated phase change materials with polymer–silica hybrid shell," Energy, Elsevier, vol. 64(C), pages 575-581.
    18. Cao, Lei & Su, Di & Tang, Yaojie & Fang, Guiyin & Tang, Fang, 2015. "Properties evaluation and applications of thermal energystorage materials in buildings," Renewable and Sustainable Energy Reviews, Elsevier, vol. 48(C), pages 500-522.
    19. He, Fang & Wang, Xiaodong & Wu, Dezhen, 2014. "New approach for sol–gel synthesis of microencapsulated n-octadecane phase change material with silica wall using sodium silicate precursor," Energy, Elsevier, vol. 67(C), pages 223-233.
    20. Jamekhorshid, A. & Sadrameli, S.M. & Farid, M., 2014. "A review of microencapsulation methods of phase change materials (PCMs) as a thermal energy storage (TES) medium," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 531-542.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:66:y:2014:i:c:p:881-890. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.