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Preparation and properties of palmitic-stearic acid eutectic mixture/expanded graphite composite as phase change material for energy storage

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  • Zhang, Nan
  • Yuan, Yanping
  • Du, Yanxia
  • Cao, Xiaoling
  • Yuan, Yaguang

Abstract

A novel composite PCM (phase change material) with PA-SA (palmitic-stearic acid) eutectic mixture as PCM and EG (expanded graphite) as supporting material was prepared. The optimum absorption ratio of PA-SA/EG (Palmitic-stearic acid/expanded graphite) composite PCM was determined as PA-SA:EG = 13:1 (by mass). Scanning electron microscope and Fourier transformation infrared spectroscopy results show that PA-SA was uniformly distributed in the porous network structure of EG due to the physical action. Thermal property and thermal stability of the PA-SA/EG composite PCM were characterized by DSC (differential scanning calorimetry) and TGA (thermogravimetric analysis). DSC results indicated that the melting and freezing temperatures and latent heats of PA-SA/EG were measured as 53.89 °C and 54.37 °C, and 166.27 J/g and 166.13 J/g. TGA test results revealed that PA-SA/EG had a good thermal stability in working temperature range. Thermal cycling test results showed PA-SA/EG had a good thermal reliability after 720 thermal cycles. Thermal conductivity of the composite PCM was measured as 2.51 W/m K, much higher than that of PA-SA. The thermal energy storage and release rates of PA-SA/EG were also increased due to the high thermal conductivity of EG. In conclusion, the prepared PA-SA/EG composite PCM can be acted as a potential material for thermal energy storage due to the acceptable thermal properties, good thermal reliability and stability, high thermal conductivity.

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  • Zhang, Nan & Yuan, Yanping & Du, Yanxia & Cao, Xiaoling & Yuan, Yaguang, 2014. "Preparation and properties of palmitic-stearic acid eutectic mixture/expanded graphite composite as phase change material for energy storage," Energy, Elsevier, vol. 78(C), pages 950-956.
    • Handle: RePEc:eee:energy:v:78:y:2014:i:c:p:950-956
    DOI: 10.1016/j.energy.2014.10.092
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