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Biomass pyrolysis in a fixed-bed reactor: Effects of pyrolysis parameters on product yields and characterization of products

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  • Aysu, Tevfik
  • Küçük, M. Maşuk

Abstract

Slow pyrolysis of eastern giant fennel (Ferula orientalis L.) stalks has been performed in a fixed-bed tubular reactor with (ZnO, Al2O3) and without catalyst at six different temperatures ranging from 350 °C to 600 °C with heating rates of 15, 30, 50 °C/min. The amounts of bio-char, bio-oil and gas produced, as well as the compositions of the resulting bio-oils were determined by FT-IR and GC–MS. The effects of pyrolysis parameters such as temperature, catalyst and ratio of catalyst, particle size (Dp) and sweeping gas flow rate on product yields were investigated. According to results, temperature and catalyst seem to be the main factors effecting the conversion of F. orientalis L. into solid, liquid and gaseous products. The highest liquid yield (45.22%) including water was obtained with 15% zinc oxide catalyst at 500 °C temperature at a heating rate of 50 °C/min when 0.224 > Dp > 0.150 mm particle size raw material and 100 cm3/min of sweeping gas flow rate were used.

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  • Aysu, Tevfik & Küçük, M. Maşuk, 2014. "Biomass pyrolysis in a fixed-bed reactor: Effects of pyrolysis parameters on product yields and characterization of products," Energy, Elsevier, vol. 64(C), pages 1002-1025.
    • Handle: RePEc:eee:energy:v:64:y:2014:i:c:p:1002-1025
    DOI: 10.1016/j.energy.2013.11.053
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    15. Feng, Qunjie & Lin, Yunqin, 2017. "Integrated processes of anaerobic digestion and pyrolysis for higher bioenergy recovery from lignocellulosic biomass: A brief review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 1272-1287.
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    17. Chen, Rongjie & Lun, Liyong & Cong, Kunlin & Li, Qinghai & Zhang, Yanguo, 2019. "Insights into pyrolysis and co-pyrolysis of tobacco stalk and scrap tire: Thermochemical behaviors, kinetics, and evolved gas analysis," Energy, Elsevier, vol. 183(C), pages 25-34.
    18. Yang, S.I. & Hsu, T.C. & Wu, M.S., 2016. "Spray combustion characteristics of kerosene/bio-oil part II: Numerical study," Energy, Elsevier, vol. 115(P1), pages 458-467.
    19. Anand, Abhijeet & Kumar, Vivek & Kaushal, Priyanka, 2022. "Biochar and its twin benefits: Crop residue management and climate change mitigation in India," Renewable and Sustainable Energy Reviews, Elsevier, vol. 156(C).
    20. Qambrani, Naveed Ahmed & Rahman, Md. Mukhlesur & Won, Seunggun & Shim, Soomin & Ra, Changsix, 2017. "Biochar properties and eco-friendly applications for climate change mitigation, waste management, and wastewater treatment: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 255-273.
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    22. Opatokun, Suraj Adebayo & Strezov, Vladimir & Kan, Tao, 2015. "Product based evaluation of pyrolysis of food waste and its digestate," Energy, Elsevier, vol. 92(P3), pages 349-354.

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