IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v267y2023ics0360544222033680.html
   My bibliography  Save this article

Identification of internal polarization dynamics for solid oxide fuel cells investigated by electrochemical impedance spectroscopy and distribution of relaxation times

Author

Listed:
  • Li, Haolong
  • Wei, Wei
  • Liu, Fengxia
  • Xu, Xiaofei
  • Li, Zhiyi
  • Liu, Zhijun

Abstract

Reliability and durability are two major problems restricting for Solid oxide fuel cells (SOFCs) industrial applications. To ensure the long-term stability, understood the internal operation mechanism of SOFC was necessary. The polarization curve combined with the distribution of relaxation times (DRT) method to analyze the electrochemical impedance spectroscopy (EIS) was used to identify the SOFCs modulation and degradation effect through the excitation frequency. Dynamic evolution of carbon deposition process and specific time constants were determined employing EIS and DRT. Special attention was paid to the dependency between the complex reaction processes that occur during the different operation of SOFC. The corresponding frequencies of concentration and activation polarization resistances in EIS were investigated under various gas compositions. The high concentration polarization resistance caused by the addition of nitrogen and hydrogen starvation was the key limiting factor for high cell power density. The total polarization resistance increased from 1.50 Ω/cm2 to 5.26 Ω/cm2 when the H2:N2 ratio decreased from 1:0 to 1:5. The anode did not deteriorate due to the poisoning of Ni particles in a short-term tested under 0.5 A/cm2 current density when the fuel was methane.

Suggested Citation

  • Li, Haolong & Wei, Wei & Liu, Fengxia & Xu, Xiaofei & Li, Zhiyi & Liu, Zhijun, 2023. "Identification of internal polarization dynamics for solid oxide fuel cells investigated by electrochemical impedance spectroscopy and distribution of relaxation times," Energy, Elsevier, vol. 267(C).
  • Handle: RePEc:eee:energy:v:267:y:2023:i:c:s0360544222033680
    DOI: 10.1016/j.energy.2022.126482
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544222033680
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2022.126482?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Al-Khori, Khalid & Bicer, Yusuf & Koç, Muammer, 2021. "Comparative techno-economic assessment of integrated PV-SOFC and PV-Battery hybrid system for natural gas processing plants," Energy, Elsevier, vol. 222(C).
    2. Lee, Young Duk & Ahn, Kook Young & Morosuk, Tatiana & Tsatsaronis, George, 2018. "Exergetic and exergoeconomic evaluation of an SOFC-Engine hybrid power generation system," Energy, Elsevier, vol. 145(C), pages 810-822.
    3. Jing, Rui & Wang, Meng & Brandon, Nigel & Zhao, Yingru, 2017. "Multi-criteria evaluation of solid oxide fuel cell based combined cooling heating and power (SOFC-CCHP) applications for public buildings in China," Energy, Elsevier, vol. 141(C), pages 273-289.
    4. Kamalimeera, N. & Kirubakaran, V., 2021. "Prospects and restraints in biogas fed SOFC for rural energization: A critical review in indian perspective," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    5. Wang, Xusheng & Lv, Xiaojing & Mi, Xicong & Spataru, Catalina & Weng, Yiwu, 2022. "Coordinated control approach for load following operation of SOFC-GT hybrid system," Energy, Elsevier, vol. 248(C).
    6. Subotić, Vanja & Stoeckl, Bernhard & Lawlor, Vincent & Strasser, Johannes & Schroettner, Hartmuth & Hochenauer, Christoph, 2018. "Towards a practical tool for online monitoring of solid oxide fuel cell operation: An experimental study and application of advanced data analysis approaches," Applied Energy, Elsevier, vol. 222(C), pages 748-761.
    7. Cheng, Cai & Cherian, Jacob & Sial, Muhammad Safdar & Zaman, Umer & Niroumandi, Hosein, 2021. "Performance assessment of a novel biomass-based solid oxide fuel cell power generation cycle; Economic analysis and optimization," Energy, Elsevier, vol. 224(C).
    8. John T. S. Irvine & Dragos Neagu & Maarten C. Verbraeken & Christodoulos Chatzichristodoulou & Christopher Graves & Mogens B. Mogensen, 2016. "Evolution of the electrochemical interface in high-temperature fuel cells and electrolysers," Nature Energy, Nature, vol. 1(1), pages 1-13, January.
    9. Khazaee, I. & Rava, A., 2017. "Numerical simulation of the performance of solid oxide fuel cell with different flow channel geometries," Energy, Elsevier, vol. 119(C), pages 235-244.
    10. Yuan, Hao & Dai, Haifeng & Ming, Pingwen & Wang, Xueyuan & Wei, Xuezhe, 2021. "Quantitative analysis of internal polarization dynamics for polymer electrolyte membrane fuel cell by distribution of relaxation times of impedance," Applied Energy, Elsevier, vol. 303(C).
    11. Cavalli, A. & Fernandes, A. & Aravind, P.V., 2021. "Thermodynamic analysis of an improved integrated biomass gasifier solid oxide fuel cell micro combined heat and power system," Energy, Elsevier, vol. 231(C).
    12. Mehr, A.S. & Lanzini, A. & Santarelli, M. & Rosen, Marc A., 2021. "Polygeneration systems based on high temperature fuel cell (MCFC and SOFC) technology: System design, fuel types, modeling and analysis approaches," Energy, Elsevier, vol. 228(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhao, Kai & Lu, Jiaxin & Le, Long & Coyle, Chris & Marina, Olga A. & Huang, Kevin, 2024. "A high-performance intermediate temperature reversible solid oxide cell with a new barrier layer free oxygen electrode," Applied Energy, Elsevier, vol. 361(C).
    2. Li, Haolong & Zhang, Tuo & Wei, Wei & Liu, Fengxia & Xu, Xiaofei & Li, Zhiyi & Liu, Zhijun, 2023. "Performance enhancement of multi-gas compatible dual-channel interconnector for planar solid oxide fuel cells," Energy, Elsevier, vol. 283(C).
    3. Fan, Chuanxin & Liu, Kailong & Zhu, Tao & Peng, Qiao, 2024. "Understanding of Lithium-ion battery degradation using multisine-based nonlinear characterization method," Energy, Elsevier, vol. 290(C).
    4. Li, Haolong & Wei, Wei & Zhang, Tuo & Liu, Fengxia & Xu, Xiaofei & Li, Zhiyi & Liu, Zhijun, 2024. "Degradation mechanisms and mitigation strategies of direct methane solid oxide fuel cells," Applied Energy, Elsevier, vol. 359(C).
    5. Fu, Quanrong & Tian, Chunyu & Hun, Lianming & Wang, Xin & Li, Zhiyi & Liu, Zhijun & Wei, Wei, 2024. "Ni agglomeration and performance degradation of solid oxide fuel cell: A model-based quantitative study and microstructure optimization," Energy, Elsevier, vol. 289(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Fu, Quanrong & Tian, Chunyu & Hun, Lianming & Wang, Xin & Li, Zhiyi & Liu, Zhijun & Wei, Wei, 2024. "Ni agglomeration and performance degradation of solid oxide fuel cell: A model-based quantitative study and microstructure optimization," Energy, Elsevier, vol. 289(C).
    2. Xu, Yuhao & Luo, Xiaobing & Tu, Zhengkai & Siew Hwa Chan,, 2022. "Multi-criteria assessment of solid oxide fuel cell–combined cooling, heating, and power system model for residential application," Energy, Elsevier, vol. 259(C).
    3. Wang, Qiushi & Duan, Liqiang & Zheng, Nan & Lu, Ziyi, 2023. "4E Analysis of a novel combined cooling, heating and power system coupled with solar thermochemical process and energy storage," Energy, Elsevier, vol. 275(C).
    4. Fathy, Ahmed & Rezk, Hegazy, 2022. "Political optimizer based approach for estimating SOFC optimal parameters for static and dynamic models," Energy, Elsevier, vol. 238(PC).
    5. Calise, F. & Cappiello, F.L. & Cimmino, L. & Vicidomini, M., 2022. "Dynamic simulation modelling of reversible solid oxide fuel cells for energy storage purpose," Energy, Elsevier, vol. 260(C).
    6. Tanaka, T. & Inui, Y. & Pongratz, G. & Subotić, V. & Hochenauer, C., 2021. "Numerical investigation on the performance and detection of an industrial-sized planar solid oxide fuel cell with fuel gas leakage," Applied Energy, Elsevier, vol. 285(C).
    7. Chen, Yi & Niroumandi, Hossein & Duan, Yinying, 2021. "Thermodynamic and economic analyses of a syngas-fueled high-temperature fuel cell with recycling processes in novel electricity and freshwater cogeneration plant," Energy, Elsevier, vol. 235(C).
    8. Nawaz Edoo & Robert T. F. Ah King, 2021. "Techno-Economic Analysis of Utility-Scale Solar Photovoltaic Plus Battery Power Plant," Energies, MDPI, vol. 14(23), pages 1-22, December.
    9. Konstantina Peloriadi & Petros Iliadis & Panagiotis Boutikos & Konstantinos Atsonios & Panagiotis Grammelis & Aristeidis Nikolopoulos, 2022. "Technoeconomic Assessment of LNG-Fueled Solid Oxide Fuel Cells in Small Island Systems: The Patmos Island Case Study," Energies, MDPI, vol. 15(11), pages 1-20, May.
    10. Teng, Su & Hamrang, Farzad & Ashraf Talesh, Seyed Saman, 2021. "Economic performance assessment of a novel combined power generation cycle," Energy, Elsevier, vol. 231(C).
    11. Cormos, Calin-Cristian, 2023. "Green hydrogen production from decarbonized biomass gasification: An integrated techno-economic and environmental analysis," Energy, Elsevier, vol. 270(C).
    12. Liu, Jiejie & Li, Yao & Ma, Yanan & Qin, Ruomu & Meng, Xianyang & Wu, Jiangtao, 2023. "Two-layer multiple scenario optimization framework for integrated energy system based on optimal energy contribution ratio strategy," Energy, Elsevier, vol. 285(C).
    13. Maria Psillaki & Nikolaos Apostolopoulos & Ilias Makris & Panagiotis Liargovas & Sotiris Apostolopoulos & Panos Dimitrakopoulos & George Sklias, 2023. "Hospitals’ Energy Efficiency in the Perspective of Saving Resources and Providing Quality Services through Technological Options: A Systematic Literature Review," Energies, MDPI, vol. 16(2), pages 1-21, January.
    14. Nhuchhen, Daya R. & Sit, Song P. & Layzell, David B., 2022. "Towards net-zero emission cement and power production using Molten Carbonate Fuel Cells," Applied Energy, Elsevier, vol. 306(PB).
    15. Cavalli, Alessandro & Chundru, Pradeep & Brunner, Thomas & Obernberger, Ingwald & Mirabelli, Ilaria & Makkus, Robert & Aravind, Purushothaman Vellayani, 2021. "Interactions of high temperature H2S and HCl cleaning sorbents with biosyngas main components and testing in a pilot integrated biomass gasifier SOFC system," Renewable Energy, Elsevier, vol. 180(C), pages 673-682.
    16. Zhao, Lei & Yuan, Hao & Xie, Jiaping & Jiang, Shangfeng & Wei, Xuezhe & Tang, Wei & Ming, Pingwen & Dai, Haifeng, 2023. "Inconsistency evaluation of vehicle-oriented fuel cell stacks based on electrochemical impedance under dynamic operating conditions," Energy, Elsevier, vol. 265(C).
    17. Petrone, Giovanni & Zamboni, Walter & Spagnuolo, Giovanni, 2019. "An interval arithmetic-based method for parametric identification of a fuel cell equivalent circuit model," Applied Energy, Elsevier, vol. 242(C), pages 1226-1236.
    18. Dong, Weijie & He, Guoqing & Cui, Quansheng & Sun, Wenwen & Hu, Zhenlong & Ahli raad, Erfan, 2022. "Self-scheduling of a novel hybrid GTSOFC unit in day-ahead energy and spinning reserve markets within ancillary services using a novel energy storage," Energy, Elsevier, vol. 239(PE).
    19. D.F. Chuahy, Flavio & Kokjohn, Sage L., 2019. "Solid oxide fuel cell and advanced combustion engine combined cycle: A pathway to 70% electrical efficiency," Applied Energy, Elsevier, vol. 235(C), pages 391-408.
    20. Li, Sida & Wei, Xuezhe & Jiang, Shangfeng & Yuan, Hao & Ming, Pingwen & Wang, Xueyuan & Dai, Haifeng, 2022. "Hydrogen crossover diagnosis for fuel cell stack: An electrochemical impedance spectroscopy based method," Applied Energy, Elsevier, vol. 325(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:267:y:2023:i:c:s0360544222033680. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.