IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v289y2024ics0360544223033911.html
   My bibliography  Save this article

Ni agglomeration and performance degradation of solid oxide fuel cell: A model-based quantitative study and microstructure optimization

Author

Listed:
  • Fu, Quanrong
  • Tian, Chunyu
  • Hun, Lianming
  • Wang, Xin
  • Li, Zhiyi
  • Liu, Zhijun
  • Wei, Wei

Abstract

Nickel agglomeration poses a noteworthy impediment to the commercialization of SOFCs. A comprehensive coupled degradation model is established, encompassing a Ni-particle coarsening model, microstructural parameters, effective mesoscopic parameters, and various transport processes (mass/momentum/heat/charge/multi-species transports), and chemical/electrochemical reactions. The initial anode microstructural parameters are optimized by the comprehensive model and response surface method (RSM). Single-factor analysis shows that within the initial Ni-particle diameter (dNi(t=0)) range of 0.6–0.9 μm, a particle size ratio (R) of 1.0–1.5 between YSZ-particle and Ni-particle, and a solid-phase volume fraction of Ni-particle (ψNi) ranging from 0.35 to 0.55, SOFC demonstrates high power density and a reduced degradation rate. Using the single-factor results, RSM is employed for -anode microstructure optimization, specifying: dNi(t=0) = 0.7 μm, R = 1.0, and ψNi = 0.49. Correspondingly, the average power density at 0.6 V (PD‾0.6V) reaches 2828.5 W/m2, with a degradation rate (Vde) off 0.441 %/1000 h. In comparison to original microstructure parameters (dNi(t=0) = 0.6 μm, R = 1.0, ψNi = 0.4), the optimal SOFC exhibits a remarkable enhancement in electrical performance and durability, with an 11.9 % increase in PD‾0.6V and a 69 % reduction in Vde. The integration of the comprehensive model and RSM presents a promising strategy for predicting performance, refining operation condition, and optimizing electrode microstructure for long-term operating SOFC.

Suggested Citation

  • Fu, Quanrong & Tian, Chunyu & Hun, Lianming & Wang, Xin & Li, Zhiyi & Liu, Zhijun & Wei, Wei, 2024. "Ni agglomeration and performance degradation of solid oxide fuel cell: A model-based quantitative study and microstructure optimization," Energy, Elsevier, vol. 289(C).
    • Handle: RePEc:eee:energy:v:289:y:2024:i:c:s0360544223033911
    DOI: 10.1016/j.energy.2023.129997
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544223033911
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2023.129997?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Li, Haolong & Wei, Wei & Liu, Fengxia & Xu, Xiaofei & Li, Zhiyi & Liu, Zhijun, 2023. "Identification of internal polarization dynamics for solid oxide fuel cells investigated by electrochemical impedance spectroscopy and distribution of relaxation times," Energy, Elsevier, vol. 267(C).
    2. Zhu, Jiang & Lin, Zijing, 2018. "Degradations of the electrochemical performance of solid oxide fuel cell induced by material microstructure evolutions," Applied Energy, Elsevier, vol. 231(C), pages 22-28.
    3. Al-Khori, Khalid & Bicer, Yusuf & Koç, Muammer, 2021. "Comparative techno-economic assessment of integrated PV-SOFC and PV-Battery hybrid system for natural gas processing plants," Energy, Elsevier, vol. 222(C).
    4. Wang, Xusheng & Lv, Xiaojing & Weng, Yiwu, 2020. "Performance analysis of a biogas-fueled SOFC/GT hybrid system integrated with anode-combustor exhaust gas recirculation loops," Energy, Elsevier, vol. 197(C).
    5. Wang, Yang & Wu, Chengru & Zhao, Siyuan & Wang, Jian & Zu, Bingfeng & Han, Minfang & Du, Qing & Ni, Meng & Jiao, Kui, 2022. "Coupling deep learning and multi-objective genetic algorithms to achieve high performance and durability of direct internal reforming solid oxide fuel cell," Applied Energy, Elsevier, vol. 315(C).
    6. Wang, Heng & Zhao, Hongbin & Du, Huicheng & Zhao, Zefeng & Zhang, Taiheng, 2022. "Thermodynamic performance study of a new diesel-fueled CLHG/SOFC/STIG cogeneration system with CO2 recovery," Energy, Elsevier, vol. 246(C).
    7. Chitgar, Nazanin & Moghimi, Mahdi, 2020. "Design and evaluation of a novel multi-generation system based on SOFC-GT for electricity, fresh water and hydrogen production," Energy, Elsevier, vol. 197(C).
    8. Liang, Wenxing & Yu, Zeting & Liu, Wenjing & Ji, Shaobo, 2023. "Investigation of a novel near-zero emission poly-generation system based on biomass gasification and SOFC: A thermodynamic and exergoeconomic evaluation," Energy, Elsevier, vol. 282(C).
    9. Wei, Ya & Stanford, Russell J., 2019. "Parameter identification of solid oxide fuel cell by Chaotic Binary Shark Smell Optimization method," Energy, Elsevier, vol. 188(C).
    10. Wang, Xusheng & Lv, Xiaojing & Mi, Xicong & Spataru, Catalina & Weng, Yiwu, 2022. "Coordinated control approach for load following operation of SOFC-GT hybrid system," Energy, Elsevier, vol. 248(C).
    11. Jing, Rui & Wang, Meng & Brandon, Nigel & Zhao, Yingru, 2017. "Multi-criteria evaluation of solid oxide fuel cell based combined cooling heating and power (SOFC-CCHP) applications for public buildings in China," Energy, Elsevier, vol. 141(C), pages 273-289.
    12. Ong, Samuel & Al-Othman, Amani & Tawalbeh, Muhammad, 2023. "Emerging technologies in prognostics for fuel cells including direct hydrocarbon fuel cells," Energy, Elsevier, vol. 277(C).
    13. Wei Kong & Xiang Gao & Shixue Liu & Shichuan Su & Daifen Chen, 2014. "Optimization of the Interconnect Ribs for a Cathode-Supported Solid Oxide Fuel Cell," Energies, MDPI, vol. 7(1), pages 1-19, January.
    14. Mehr, A.S. & Lanzini, A. & Santarelli, M. & Rosen, Marc A., 2021. "Polygeneration systems based on high temperature fuel cell (MCFC and SOFC) technology: System design, fuel types, modeling and analysis approaches," Energy, Elsevier, vol. 228(C).
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Xu, Yuhao & Luo, Xiaobing & Tu, Zhengkai & Siew Hwa Chan,, 2022. "Multi-criteria assessment of solid oxide fuel cell–combined cooling, heating, and power system model for residential application," Energy, Elsevier, vol. 259(C).
    2. Li, Haolong & Wei, Wei & Liu, Fengxia & Xu, Xiaofei & Li, Zhiyi & Liu, Zhijun, 2023. "Identification of internal polarization dynamics for solid oxide fuel cells investigated by electrochemical impedance spectroscopy and distribution of relaxation times," Energy, Elsevier, vol. 267(C).
    3. Zeng, Rong & Gan, Jijuan & Guo, Baoxin & Zhang, Xiaofeng & Li, Hongqiang & Yin, Wei & Zhang, Guoqiang, 2023. "Thermodynamic performance analysis of solid oxide fuel cell - combined cooling, heating and power system with integrated supercritical CO2 power cycle - organic Rankine cycle and absorption refrigerat," Energy, Elsevier, vol. 283(C).
    4. Wang, Xusheng & Lv, Xiaojing & Mi, Xicong & Spataru, Catalina & Weng, Yiwu, 2022. "Coordinated control approach for load following operation of SOFC-GT hybrid system," Energy, Elsevier, vol. 248(C).
    5. Fathy, Ahmed & Rezk, Hegazy, 2022. "Political optimizer based approach for estimating SOFC optimal parameters for static and dynamic models," Energy, Elsevier, vol. 238(PC).
    6. Eichhorn Colombo, Konrad W. & Kharton, Vladislav V. & Berto, Filippo & Paltrinieri, Nicola, 2020. "Mathematical modeling and simulation of hydrogen-fueled solid oxide fuel cell system for micro-grid applications - Effect of failure and degradation on transient performance," Energy, Elsevier, vol. 202(C).
    7. Mohammad shafie, Mohammad & Ali rajabipour, & Mehrpooya, Mehdi, 2022. "Investigation of an electrochemical conversion of carbon dioxide to ethanol and solid oxide fuel cell, gas turbine hybrid process," Renewable Energy, Elsevier, vol. 184(C), pages 1112-1129.
    8. Yang, Chao & Jing, Xiuhui & Miao, He & Xu, Jingxiang & Lin, Peijian & Li, Ping & Liang, Chaoyu & Wu, Yu & Yuan, Jinliang, 2021. "The physical properties and effects of sintering conditions on rSOFC fuel electrodes evaluated by molecular dynamics simulation," Energy, Elsevier, vol. 216(C).
    9. Calise, F. & Cappiello, F.L. & Cimmino, L. & Vicidomini, M., 2022. "Dynamic simulation modelling of reversible solid oxide fuel cells for energy storage purpose," Energy, Elsevier, vol. 260(C).
    10. Kasaeian, Alibakhsh & Hadavi, Hamed & Amirhaeri, Yasaman & Pourfayaz, Fathollah, 2022. "Thermodynamic analysis of a wood chips-based cycle integrated with solid oxide fuel cell," Renewable Energy, Elsevier, vol. 195(C), pages 1174-1193.
    11. Sadeghi, Shayan & Ghandehariun, Samane, 2022. "A standalone solar thermochemical water splitting hydrogen plant with high-temperature molten salt: Thermodynamic and economic analyses and multi-objective optimization," Energy, Elsevier, vol. 240(C).
    12. Konstantina Peloriadi & Petros Iliadis & Panagiotis Boutikos & Konstantinos Atsonios & Panagiotis Grammelis & Aristeidis Nikolopoulos, 2022. "Technoeconomic Assessment of LNG-Fueled Solid Oxide Fuel Cells in Small Island Systems: The Patmos Island Case Study," Energies, MDPI, vol. 15(11), pages 1-20, May.
    13. Cormos, Calin-Cristian, 2023. "Green hydrogen production from decarbonized biomass gasification: An integrated techno-economic and environmental analysis," Energy, Elsevier, vol. 270(C).
    14. Liu, Jiejie & Li, Yao & Ma, Yanan & Qin, Ruomu & Meng, Xianyang & Wu, Jiangtao, 2023. "Two-layer multiple scenario optimization framework for integrated energy system based on optimal energy contribution ratio strategy," Energy, Elsevier, vol. 285(C).
    15. Li, Jiaojiao & Zoghi, Mohammad & Zhao, Linfeng, 2022. "Thermo-economic assessment and optimization of a geothermal-driven tri-generation system for power, cooling, and hydrogen production," Energy, Elsevier, vol. 244(PB).
    16. Ebrahimi-Moghadam, Amir & Farzaneh-Gord, Mahmood, 2022. "Optimal operation of a multi-generation district energy hub based on electrical, heating, and cooling demands and hydrogen production," Applied Energy, Elsevier, vol. 309(C).
    17. Wang, Chao & Liao, Mingzheng & Jiang, Zhiqiang & Liang, Bo & Weng, Jiahong & Song, Qingbin & Zhao, Ming & Chen, Ying & Lei, Libin, 2022. "Sorption-enhanced propane partial oxidation hydrogen production for solid oxide fuel cell (SOFC) applications," Energy, Elsevier, vol. 247(C).
    18. Guk, Erdogan & Venkatesan, Vijay & Babar, Shumaila & Jackson, Lisa & Kim, Jung-Sik, 2019. "Parameters and their impacts on the temperature distribution and thermal gradient of solid oxide fuel cell," Applied Energy, Elsevier, vol. 241(C), pages 164-173.
    19. Dong, Weijie & He, Guoqing & Cui, Quansheng & Sun, Wenwen & Hu, Zhenlong & Ahli raad, Erfan, 2022. "Self-scheduling of a novel hybrid GTSOFC unit in day-ahead energy and spinning reserve markets within ancillary services using a novel energy storage," Energy, Elsevier, vol. 239(PE).
    20. Teymouri, Matin & Sadeghi, Shayan & Moghimi, Mahdi & Ghandehariun, Samane, 2021. "3E analysis and optimization of an innovative cogeneration system based on biomass gasification and solar photovoltaic thermal plant," Energy, Elsevier, vol. 230(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:289:y:2024:i:c:s0360544223033911. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.