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Ni agglomeration and performance degradation of solid oxide fuel cell: A model-based quantitative study and microstructure optimization

Author

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  • Fu, Quanrong
  • Tian, Chunyu
  • Hun, Lianming
  • Wang, Xin
  • Li, Zhiyi
  • Liu, Zhijun
  • Wei, Wei

Abstract

Nickel agglomeration poses a noteworthy impediment to the commercialization of SOFCs. A comprehensive coupled degradation model is established, encompassing a Ni-particle coarsening model, microstructural parameters, effective mesoscopic parameters, and various transport processes (mass/momentum/heat/charge/multi-species transports), and chemical/electrochemical reactions. The initial anode microstructural parameters are optimized by the comprehensive model and response surface method (RSM). Single-factor analysis shows that within the initial Ni-particle diameter (dNi(t=0)) range of 0.6–0.9 μm, a particle size ratio (R) of 1.0–1.5 between YSZ-particle and Ni-particle, and a solid-phase volume fraction of Ni-particle (ψNi) ranging from 0.35 to 0.55, SOFC demonstrates high power density and a reduced degradation rate. Using the single-factor results, RSM is employed for -anode microstructure optimization, specifying: dNi(t=0) = 0.7 μm, R = 1.0, and ψNi = 0.49. Correspondingly, the average power density at 0.6 V (PD‾0.6V) reaches 2828.5 W/m2, with a degradation rate (Vde) off 0.441 %/1000 h. In comparison to original microstructure parameters (dNi(t=0) = 0.6 μm, R = 1.0, ψNi = 0.4), the optimal SOFC exhibits a remarkable enhancement in electrical performance and durability, with an 11.9 % increase in PD‾0.6V and a 69 % reduction in Vde. The integration of the comprehensive model and RSM presents a promising strategy for predicting performance, refining operation condition, and optimizing electrode microstructure for long-term operating SOFC.

Suggested Citation

  • Fu, Quanrong & Tian, Chunyu & Hun, Lianming & Wang, Xin & Li, Zhiyi & Liu, Zhijun & Wei, Wei, 2024. "Ni agglomeration and performance degradation of solid oxide fuel cell: A model-based quantitative study and microstructure optimization," Energy, Elsevier, vol. 289(C).
    • Handle: RePEc:eee:energy:v:289:y:2024:i:c:s0360544223033911
    DOI: 10.1016/j.energy.2023.129997
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    as
    1. Al-Khori, Khalid & Bicer, Yusuf & Koç, Muammer, 2021. "Comparative techno-economic assessment of integrated PV-SOFC and PV-Battery hybrid system for natural gas processing plants," Energy, Elsevier, vol. 222(C).
    2. Wang, Xusheng & Lv, Xiaojing & Weng, Yiwu, 2020. "Performance analysis of a biogas-fueled SOFC/GT hybrid system integrated with anode-combustor exhaust gas recirculation loops," Energy, Elsevier, vol. 197(C).
    3. Jing, Rui & Wang, Meng & Brandon, Nigel & Zhao, Yingru, 2017. "Multi-criteria evaluation of solid oxide fuel cell based combined cooling heating and power (SOFC-CCHP) applications for public buildings in China," Energy, Elsevier, vol. 141(C), pages 273-289.
    4. Wei Kong & Xiang Gao & Shixue Liu & Shichuan Su & Daifen Chen, 2014. "Optimization of the Interconnect Ribs for a Cathode-Supported Solid Oxide Fuel Cell," Energies, MDPI, vol. 7(1), pages 1-19, January.
    5. Zhu, Jiang & Lin, Zijing, 2018. "Degradations of the electrochemical performance of solid oxide fuel cell induced by material microstructure evolutions," Applied Energy, Elsevier, vol. 231(C), pages 22-28.
    6. Wang, Yang & Wu, Chengru & Zhao, Siyuan & Wang, Jian & Zu, Bingfeng & Han, Minfang & Du, Qing & Ni, Meng & Jiao, Kui, 2022. "Coupling deep learning and multi-objective genetic algorithms to achieve high performance and durability of direct internal reforming solid oxide fuel cell," Applied Energy, Elsevier, vol. 315(C).
    7. Chitgar, Nazanin & Moghimi, Mahdi, 2020. "Design and evaluation of a novel multi-generation system based on SOFC-GT for electricity, fresh water and hydrogen production," Energy, Elsevier, vol. 197(C).
    8. Wang, Xusheng & Lv, Xiaojing & Mi, Xicong & Spataru, Catalina & Weng, Yiwu, 2022. "Coordinated control approach for load following operation of SOFC-GT hybrid system," Energy, Elsevier, vol. 248(C).
    9. Liang, Wenxing & Yu, Zeting & Liu, Wenjing & Ji, Shaobo, 2023. "Investigation of a novel near-zero emission poly-generation system based on biomass gasification and SOFC: A thermodynamic and exergoeconomic evaluation," Energy, Elsevier, vol. 282(C).
    10. Wei, Ya & Stanford, Russell J., 2019. "Parameter identification of solid oxide fuel cell by Chaotic Binary Shark Smell Optimization method," Energy, Elsevier, vol. 188(C).
    11. Li, Haolong & Wei, Wei & Liu, Fengxia & Xu, Xiaofei & Li, Zhiyi & Liu, Zhijun, 2023. "Identification of internal polarization dynamics for solid oxide fuel cells investigated by electrochemical impedance spectroscopy and distribution of relaxation times," Energy, Elsevier, vol. 267(C).
    12. Wang, Heng & Zhao, Hongbin & Du, Huicheng & Zhao, Zefeng & Zhang, Taiheng, 2022. "Thermodynamic performance study of a new diesel-fueled CLHG/SOFC/STIG cogeneration system with CO2 recovery," Energy, Elsevier, vol. 246(C).
    13. Ong, Samuel & Al-Othman, Amani & Tawalbeh, Muhammad, 2023. "Emerging technologies in prognostics for fuel cells including direct hydrocarbon fuel cells," Energy, Elsevier, vol. 277(C).
    14. Mehr, A.S. & Lanzini, A. & Santarelli, M. & Rosen, Marc A., 2021. "Polygeneration systems based on high temperature fuel cell (MCFC and SOFC) technology: System design, fuel types, modeling and analysis approaches," Energy, Elsevier, vol. 228(C).
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