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A high-performance intermediate temperature reversible solid oxide cell with a new barrier layer free oxygen electrode

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  • Zhao, Kai
  • Lu, Jiaxin
  • Le, Long
  • Coyle, Chris
  • Marina, Olga A.
  • Huang, Kevin

Abstract

The best solution to address the critical durability issue of solid oxide electrolytic cells (SOECs) for high-efficiency and high-rate H2 production is to lower the operating temperature without sacrificing the performance. Developing high performance oxygen electrodes (OEs) is a key to capitalizing this solution. Here we report on a highly active OE for intermediate temperature ZrO2-based SOECs without a CeO2 barrier layer. The new barrier-layer-free (BLF) OE is a composite of two materials, (Bi0.75Y0.25)0.93Ce0.07O1.5±δ (BYC) that exhibits high oxide-ion conductivity and La0.8Sr0.2MnO3 (LSM) that possesses a high electronic conductivity to enable fast oxygen reduction/evolution reactions (ORR/OER). Featuring a microscale porous BYC scaffold decorated with high surface area LSM nanoparticles (NPs), the new BLF-OE exhibited a low area specific resistance (ASR) of 0.10 Ω cm2 at 650 °C in air. With 50%H2–50%H2O as a feed to hydrogen electrode (HE) and air to OE, the single cell performance achieved 588 mA cm−2 at 0.80 V in the fuel cell mode and 688 mA cm−2 at 1.30 V in the electrolytic mode at 650 °C. Our in-house testing showed that this level of performance was ∼3.5× higher than the cell with the benchmark La0.6Sr0.4Co0.2Fe0.8O3-δ-Ce0.9Gd0.1O2-δ OE. The long-term durability testing under alternating fuel cell and electrolytic modes showed a low degradation rate of 0.10 mA cm−2 h−1 over 550 h. These encouraging results showed the great promise of the newly developed BYC-LSM to be an excellent OE candidate for intermediate temperature SOECs.

Suggested Citation

  • Zhao, Kai & Lu, Jiaxin & Le, Long & Coyle, Chris & Marina, Olga A. & Huang, Kevin, 2024. "A high-performance intermediate temperature reversible solid oxide cell with a new barrier layer free oxygen electrode," Applied Energy, Elsevier, vol. 361(C).
    • Handle: RePEc:eee:appene:v:361:y:2024:i:c:s0306261924003453
    DOI: 10.1016/j.apenergy.2024.122962
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    References listed on IDEAS

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    1. Meng, Xiuxia & Liu, Yongna & Yang, Naitao & Tan, Xiaoyao & Liu, Jian & Diniz da Costa, João C. & Liu, Shaomin, 2017. "Highly compact and robust hollow fiber solid oxide cells for flexible power generation and gas production," Applied Energy, Elsevier, vol. 205(C), pages 741-748.
    2. Liu, Zhao & Han, Beibei & Lu, Zhiyi & Guan, Wanbing & Li, Yuanyuan & Song, Changjiang & Chen, Liang & Singhal, Subhash C., 2021. "Efficiency and stability of hydrogen production from seawater using solid oxide electrolysis cells," Applied Energy, Elsevier, vol. 300(C).
    3. Khan, M.S. & Xu, X. & Knibbe, R. & Zhu, Z., 2021. "Air electrodes and related degradation mechanisms in solid oxide electrolysis and reversible solid oxide cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    4. Pan, Zehua & Liu, Qinglin & Zhang, Lan & Zhou, Juan & Zhang, Caizhi & Chan, Siew Hwa, 2017. "Experimental and thermodynamic study on the performance of water electrolysis by solid oxide electrolyzer cells with Nb-doped Co-based perovskite anode," Applied Energy, Elsevier, vol. 191(C), pages 559-567.
    5. Li, Haolong & Wei, Wei & Liu, Fengxia & Xu, Xiaofei & Li, Zhiyi & Liu, Zhijun, 2023. "Identification of internal polarization dynamics for solid oxide fuel cells investigated by electrochemical impedance spectroscopy and distribution of relaxation times," Energy, Elsevier, vol. 267(C).
    6. Min, Gyubin & Choi, Saeyoung & Hong, Jongsup, 2022. "A review of solid oxide steam-electrolysis cell systems: Thermodynamics and thermal integration," Applied Energy, Elsevier, vol. 328(C).
    7. Wang, Jincheng & Zhao, Kai & Zhao, Jishi & Li, Jun & Liu, Yihui & Chen, Dongchu & Xu, Qing & Chen, Min, 2022. "A NiMo-YSZ catalyst support layer for regenerable solid oxide fuel cells running on isooctane," Applied Energy, Elsevier, vol. 326(C).
    Full references (including those not matched with items on IDEAS)

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