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Vacuum promoted methane decomposition for hydrogen production with carbon separation: Parameter optimization and economic assessment

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  • Chen, Zong
  • Zhang, Rongjun
  • Xia, Guofu
  • Wu, Yu
  • Li, Hongwei
  • Sun, Zhao
  • Sun, Zhiqiang

Abstract

Catalytic methane decomposition (CMD) is a promising method for directly extracting hydrogen from methane. Nevertheless, relatively low methane conversion and carbon deposition on the catalyst are two main shortcomings to be resolved. A new process, vacuum promoted methane decomposition with carbon separation (VPMDCS), is proposed and simulated by Aspen Plus. The VPMDCS system is comprised of two reactors, a methane decomposition reactor (MDR) and a carbon separation reactor (CSR), which continuously generates hydrogen in the MDR and converts carbon into CO basically in the CSR based on Le Chatelier’s principle. The effects of methane decomposition temperature and pressure, gasifying agent concentration, CO2/C molar ratio, carbon separation temperature and pressure were comprehensively investigated and optimized. Besides, an economic analysis was conducted compared with that of steam methane reforming, evaluating the competitiveness of VPMDCS. Results reveal that VPMDCS can produce high-purity H2 and CO in the MDR and CSR, respectively, obtaining CH4 conversion of 99.18%, and H2 and CO concentrations of both 99.59 vol%. Economic analysis indicates that the cost to produce hydrogen in the VPMDCS process is 5.40 €/kg, which is somewhat competitive compared to hydrogen produced by small-scale SRM (4.55 €/kg).

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  • Chen, Zong & Zhang, Rongjun & Xia, Guofu & Wu, Yu & Li, Hongwei & Sun, Zhao & Sun, Zhiqiang, 2021. "Vacuum promoted methane decomposition for hydrogen production with carbon separation: Parameter optimization and economic assessment," Energy, Elsevier, vol. 222(C).
    • Handle: RePEc:eee:energy:v:222:y:2021:i:c:s0360544221002024
    DOI: 10.1016/j.energy.2021.119953
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    References listed on IDEAS

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    1. Luo, Ming & Yi, Yang & Wang, Shuzhong & Wang, Zhuliang & Du, Min & Pan, Jianfeng & Wang, Qian, 2018. "Review of hydrogen production using chemical-looping technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 3186-3214.
    2. Keipi, Tiina & Li, Tian & Løvås, Terese & Tolvanen, Henrik & Konttinen, Jukka, 2017. "Methane thermal decomposition in regenerative heat exchanger reactor: Experimental and modeling study," Energy, Elsevier, vol. 135(C), pages 823-832.
    3. Cai, Lei & He, Tianzhi & Xiang, Yanlei & Guan, Yanwen, 2020. "Study on the reaction pathways of steam methane reforming for H2 production," Energy, Elsevier, vol. 207(C).
    4. Zhang, Xiang & Kätelhön, Arne & Sorda, Giovanni & Helmin, Marta & Rose, Marcus & Bardow, André & Madlener, Reinhard & Palkovits, Regina & Mitsos, Alexander, 2018. "CO2 mitigation costs of catalytic methane decomposition," Energy, Elsevier, vol. 151(C), pages 826-838.
    5. Yamani, Noureddine & Khellaf, Abdallah & Mohammedi, Kamal & Behar, Omar, 2017. "Assessment of solar thermal tower technology under Algerian climate," Energy, Elsevier, vol. 126(C), pages 444-460.
    6. Martínez, I. & Romano, M.C. & Fernández, J.R. & Chiesa, P. & Murillo, R. & Abanades, J.C., 2014. "Process design of a hydrogen production plant from natural gas with CO2 capture based on a novel Ca/Cu chemical loop," Applied Energy, Elsevier, vol. 114(C), pages 192-208.
    7. Boyano, A. & Blanco-Marigorta, A.M. & Morosuk, T. & Tsatsaronis, G., 2011. "Exergoenvironmental analysis of a steam methane reforming process for hydrogen production," Energy, Elsevier, vol. 36(4), pages 2202-2214.
    8. Lee, Boreum & Kim, Hyunwoo & Lee, Hyunjun & Byun, Manhee & Won, Wangyun & Lim, Hankwon, 2020. "Technical and economic feasibility under uncertainty for methane dry reforming of coke oven gas as simultaneous H2 production and CO2 utilization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 133(C).
    9. Abánades, A. & Rubbia, C. & Salmieri, D., 2012. "Technological challenges for industrial development of hydrogen production based on methane cracking," Energy, Elsevier, vol. 46(1), pages 359-363.
    10. Sun, Zhao & Russell, Christopher K. & Fan, Maohong, 2021. "Effect of calcium ferrites on carbon dioxide gasification reactivity and kinetics of pine wood derived char," Renewable Energy, Elsevier, vol. 163(C), pages 445-452.
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    1. Seunghyun Cheon & Manhee Byun & Dongjun Lim & Hyunjun Lee & Hankwon Lim, 2021. "Parametric Study for Thermal and Catalytic Methane Pyrolysis for Hydrogen Production: Techno-Economic and Scenario Analysis," Energies, MDPI, vol. 14(19), pages 1-19, September.
    2. Mirkarimi, S.M.R. & Bensaid, S. & Negro, V. & Chiaramonti, D., 2023. "Review of methane cracking over carbon-based catalyst for energy and fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 187(C).

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