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Modelling of the calcination behaviour of a uniformly-distributed CuO/CaCO3 particle in Ca–Cu chemical looping

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  • Qin, Changlei
  • Yin, Junjun
  • Feng, Bo
  • Ran, Jingyu
  • Zhang, Li
  • Manovic, Vasilije

Abstract

Ca–Cu chemical looping (CaL-CLC), consisting of calcination (regeneration), carbonation, and oxidation stages, is a novel process with high potential for CO2 capture. Its implementation is largely dependent on the effective matching, transferring and utilisation of the heat generated by CuO reduction, for CaCO3 decomposition, where the former is an exothermic and the latter an endothermic reaction. To better understand the calcination behaviour during CaL-CLC cycles, we developed a mathematical model coupling chemical reactions, mass and heat transfer inside a spherical particle composed of a number of uniformly distributed CuO and CaCO3 grains. Using the model, we simulated the dynamics of CuO and CaCO3 conversion, the profiles of temperature and gas concentrations, and the changes in porosity and the grain size inside the particle with time. Furthermore, the influence of several key variables on calcination behaviour within the spherical particle was numerically analysed. Results show that it is better to have an ambient temperature in the range of 1198–1223K, a similar value of the initial particle temperature, and a small CaCO3 grain size to attain a good match between reactions of CuO and CaCO3, and to avoid the onset of local superheating within the particle.

Suggested Citation

  • Qin, Changlei & Yin, Junjun & Feng, Bo & Ran, Jingyu & Zhang, Li & Manovic, Vasilije, 2016. "Modelling of the calcination behaviour of a uniformly-distributed CuO/CaCO3 particle in Ca–Cu chemical looping," Applied Energy, Elsevier, vol. 164(C), pages 400-410.
    • Handle: RePEc:eee:appene:v:164:y:2016:i:c:p:400-410
    DOI: 10.1016/j.apenergy.2015.11.059
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    References listed on IDEAS

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    1. Wang, Wenjing & Li, Yingjie & Xie, Xin & Sun, Rongyue, 2014. "Effect of the presence of HCl on cyclic CO2 capture of calcium-based sorbent in calcium looping process," Applied Energy, Elsevier, vol. 125(C), pages 246-253.
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    Cited by:

    1. Han, Rui & Gao, Jihui & Wei, Siyu & Su, Yanlin & Sun, Fei & Zhao, Guangbo & Qin, Yukun, 2018. "Strongly coupled calcium carbonate/antioxidative graphite nanosheets composites with high cycling stability for thermochemical energy storage," Applied Energy, Elsevier, vol. 231(C), pages 412-422.
    2. Yan Shao & Donglin He & Changlei Qin & Jingyu Ran & Li Zhang, 2017. "SO 2 removal characteristics using waste CaO from calcium looping CO 2 capture process," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 7(4), pages 637-648, August.
    3. Shi, Jiewen & Li, Yingjie & Zhang, Qing & Ma, Xiaotong & Duan, Lunbo & Zhou, Xingang, 2017. "CO2 capture performance of a novel synthetic CaO/sepiolite sorbent at calcium looping conditions," Applied Energy, Elsevier, vol. 203(C), pages 412-421.
    4. Wei Liu & Ye Wu & Tianyi Cai & Xiaoping Chen & Dong Liu, 2019. "Use of nanoparticles Cu/TiO(OH)2 for CO2 removal with K2CO3/KHCO3 based solution: enhanced thermal conductivity and reaction kinetics enhancing the CO2 sorption/desorption performance of K2CO3/KHCO3," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 9(1), pages 10-18, February.

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