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Experimental investigations of Alum/expanded graphite composite phase change material for thermal energy storage and its compatibility with metals

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  • Zhang, Suling
  • Wu, Wei
  • Wang, Shuangfeng

Abstract

A novel composite phase change material(CPCM) were prepared with Aluminum potassium sulfate dodecahydrate(Alum, KAl(SO4)2·12H2O) as PCM and expanded graphite(EG) as nucleating agent and porous matrix for thermal conductivity enhancing. The detailed thermo-physical properties and thermal energy storage performance were studied. The DSC revealed that the melting temperature and latent heat of fusion of Alum/EG CPCM were 87.92 °C and 214.9J/g, respectively. The thermal conductivity of Alum/EG CPCM was improved from 0.497W·m−1·K−1 to 5.875W·m−1·K−1 due to the addition of EG, which can also be confirmed by the infrared thermal imager during charging/discharging process. The Alum/EG CPCM exhibited prominent chemical stability and thermal reliability before and after 500 thermal cycle tests. Furthermore, the corrosion of three metals and one metal alloy were studied and the gravimetric analysis and the results of element composition of four samples exhibited that the brass was the suitable materials for the container for long-term used while stainless steel 304L and aluminum were severely corroded. The results demonstrated that Alum/EG CPCM was a prospective candidate for thermal energy storage and accelerated the research on the Alum/EG heat storage system.

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  • Zhang, Suling & Wu, Wei & Wang, Shuangfeng, 2018. "Experimental investigations of Alum/expanded graphite composite phase change material for thermal energy storage and its compatibility with metals," Energy, Elsevier, vol. 161(C), pages 508-516.
  • Handle: RePEc:eee:energy:v:161:y:2018:i:c:p:508-516
    DOI: 10.1016/j.energy.2018.07.075
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    References listed on IDEAS

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    1. Huang, Zhaowen & Gao, Xuenong & Xu, Tao & Fang, Yutang & Zhang, Zhengguo, 2014. "Thermal property measurement and heat storage analysis of LiNO3/KCl – expanded graphite composite phase change material," Applied Energy, Elsevier, vol. 115(C), pages 265-271.
    2. Zhang, Suling & Wu, Wei & Wang, Shuangfeng, 2017. "Preparation, thermal properties and thermal reliability of a novel mid-temperature composite phase change material for energy conservation," Energy, Elsevier, vol. 130(C), pages 228-235.
    3. Zhang, Suling & Wu, Wei & Wang, Shuangfeng, 2017. "Integration highly concentrated photovoltaic module exhaust heat recovery system with adsorption air-conditioning module via phase change materials," Energy, Elsevier, vol. 118(C), pages 1187-1197.
    4. Fu, Lulu & Wang, Qianhao & Ye, Rongda & Fang, Xiaoming & Zhang, Zhengguo, 2017. "A calcium chloride hexahydrate/expanded perlite composite with good heat storage and insulation properties for building energy conservation," Renewable Energy, Elsevier, vol. 114(PB), pages 733-743.
    5. Huang, Xiang & Alva, Guruprasad & Jia, Yuting & Fang, Guiyin, 2017. "Morphological characterization and applications of phase change materials in thermal energy storage: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 128-145.
    6. Zhang, P. & Xiao, X. & Ma, Z.W., 2016. "A review of the composite phase change materials: Fabrication, characterization, mathematical modeling and application to performance enhancement," Applied Energy, Elsevier, vol. 165(C), pages 472-510.
    7. Gunasekara, Saman Nimali & Pan, Ruijun & Chiu, Justin Ningwei & Martin, Viktoria, 2016. "Polyols as phase change materials for surplus thermal energy storage," Applied Energy, Elsevier, vol. 162(C), pages 1439-1452.
    8. Moreno, Pere & Miró, Laia & Solé, Aran & Barreneche, Camila & Solé, Cristian & Martorell, Ingrid & Cabeza, Luisa F., 2014. "Corrosion of metal and metal alloy containers in contact with phase change materials (PCM) for potential heating and cooling applications," Applied Energy, Elsevier, vol. 125(C), pages 238-245.
    9. Dannemand, Mark & Dragsted, Janne & Fan, Jianhua & Johansen, Jakob Berg & Kong, Weiqiang & Furbo, Simon, 2016. "Experimental investigations on prototype heat storage units utilizing stable supercooling of sodium acetate trihydrate mixtures," Applied Energy, Elsevier, vol. 169(C), pages 72-80.
    10. Wang, Weilong & Yang, Xiaoxi & Fang, Yutang & Ding, Jing & Yan, Jinyue, 2009. "Preparation and thermal properties of polyethylene glycol/expanded graphite blends for energy storage," Applied Energy, Elsevier, vol. 86(9), pages 1479-1483, September.
    11. Huang, Zhaowen & Luo, Zigeng & Gao, Xuenong & Fang, Xiaoming & Fang, Yutang & Zhang, Zhengguo, 2017. "Investigations on the thermal stability, long-term reliability of LiNO3/KCl – expanded graphite composite as industrial waste heat storage material and its corrosion properties with metals," Applied Energy, Elsevier, vol. 188(C), pages 521-528.
    12. Oró, Eduard & Miró, Laia & Barreneche, Camila & Martorell, Ingrid & Farid, Mohammed M. & Cabeza, Luisa F., 2013. "Corrosion of metal and polymer containers for use in PCM cold storage," Applied Energy, Elsevier, vol. 109(C), pages 449-453.
    13. Liu, Yushi & Yang, Yingzi, 2018. "Form-stable phase change material based on Na2CO3·10H2O-Na2HPO4·12H2O eutectic hydrated salt/expanded graphite oxide composite: The influence of chemical structures of expanded graphite oxide," Renewable Energy, Elsevier, vol. 115(C), pages 734-740.
    14. Rathgeber, Christoph & Schmit, Henri & Hennemann, Peter & Hiebler, Stefan, 2014. "Investigation of pinacone hexahydrate as phase change material for thermal energy storage around 45°C," Applied Energy, Elsevier, vol. 136(C), pages 7-13.
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    2. Zou, Ting & Fu, Wanwan & Liang, Xianghui & Wang, Shuangfeng & Gao, Xuenong & Zhang, Zhengguo & Fang, Yutang, 2020. "Hydrophilic modification of expanded graphite to develop form-stable composite phase change material based on modified CaCl2·6H2O," Energy, Elsevier, vol. 190(C).
    3. Zhao, B.C. & Wang, R.Z., 2019. "Perspectives for short-term thermal energy storage using salt hydrates for building heating," Energy, Elsevier, vol. 189(C).
    4. Yu, Kunyang & Liu, Yushi & Yang, Yingzi, 2021. "Review on form-stable inorganic hydrated salt phase change materials: Preparation, characterization and effect on the thermophysical properties," Applied Energy, Elsevier, vol. 292(C).
    5. Li, Y. & Jiang, S.L. & Wang, C.G. & Zhu, Q.Z., 2022. "Effect of EG particle size on the thermal properties of NaNO3–NaCl/EG shaped composite phase change materials," Energy, Elsevier, vol. 239(PB).
    6. Nie, Binjian & Palacios, Anabel & Zou, Boyang & Liu, Jiaxu & Zhang, Tongtong & Li, Yunren, 2020. "Review on phase change materials for cold thermal energy storage applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).

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