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Polyols as phase change materials for surplus thermal energy storage

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  • Gunasekara, Saman Nimali
  • Pan, Ruijun
  • Chiu, Justin Ningwei
  • Martin, Viktoria

Abstract

Storing low-temperature surplus thermal energy from industries, power plants, and the like, using phase change materials (PCM) is an effective alternative in alleviating the use of fossil based thermal energy provision. Polyols; of some also known as sugar alcohols, are an emerging PCM category for thermal energy storage (TES). A review on polyols as PCM for TES shows that polyols have phase change temperatures in the range of −15 to 245°C, and considerable phase change enthalpies of 100–413kJ/kg. However, the knowledge on the thermo-physical properties of polyols as desirable PCM for TES design is presently sparse and rather inconsistent. Moreover, the phase change and state change behaviors of polyols need to be better-understood in order to use these as PCM; e.g. the state change glass transition which many polyols at pure state are found to undergo. In this work preliminary material property characterization with the use of Temperature-History method of some selected polyols, Erythritol, Xylitol and Polyethylene glycol (PEG) 10,000 were done. Complex behaviors were observed for some of the polyols. These are: two different melting temperatures, 118.5–120°C and 106–108°C at different cycles and an average subcooling 18.5°C of for Erythritol, probable glass-transition between 0 and 113°C for Xylitol, as well as a thermally activated change that is likely an oxidation, after three to five heating/cooling cycles for Xylitol and Erythritol. PEG 10,000 had negligible subcooling, no glass-transition nor thermally activated oxidation. However a hysteresis of around 10°C was observed for PEG 10,000. Therefore these materials require detailed studies to further evaluate their PCM-suitability. This study is expected to be an initiation of an upcoming extensive polyol-blends phase equilibrium evaluation.

Suggested Citation

  • Gunasekara, Saman Nimali & Pan, Ruijun & Chiu, Justin Ningwei & Martin, Viktoria, 2016. "Polyols as phase change materials for surplus thermal energy storage," Applied Energy, Elsevier, vol. 162(C), pages 1439-1452.
    • Handle: RePEc:eee:appene:v:162:y:2016:i:c:p:1439-1452
    DOI: 10.1016/j.apenergy.2015.03.064
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    1. Oró, E. & de Gracia, A. & Castell, A. & Farid, M.M. & Cabeza, L.F., 2012. "Review on phase change materials (PCMs) for cold thermal energy storage applications," Applied Energy, Elsevier, vol. 99(C), pages 513-533.
    2. Cabeza, L.F. & Castell, A. & Barreneche, C. & de Gracia, A. & Fernández, A.I., 2011. "Materials used as PCM in thermal energy storage in buildings: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(3), pages 1675-1695, April.
    3. Zhou, D. & Zhao, C.Y. & Tian, Y., 2012. "Review on thermal energy storage with phase change materials (PCMs) in building applications," Applied Energy, Elsevier, vol. 92(C), pages 593-605.
    4. Chiu, Justin N.W. & Martin, Viktoria, 2012. "Submerged finned heat exchanger latent heat storage design and its experimental verification," Applied Energy, Elsevier, vol. 93(C), pages 507-516.
    5. Jankowski, Nicholas R. & McCluskey, F. Patrick, 2014. "A review of phase change materials for vehicle component thermal buffering," Applied Energy, Elsevier, vol. 113(C), pages 1525-1561.
    6. Al-Abidi, Abduljalil A. & Bin Mat, Sohif & Sopian, K. & Sulaiman, M.Y. & Lim, C.H. & Th, Abdulrahman, 2012. "Review of thermal energy storage for air conditioning systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 5802-5819.
    7. Kapil, Ankur & Bulatov, Igor & Smith, Robin & Kim, Jin-Kuk, 2012. "Process integration of low grade heat in process industry with district heating networks," Energy, Elsevier, vol. 44(1), pages 11-19.
    8. Fang, Hao & Xia, Jianjun & Zhu, Kan & Su, Yingbo & Jiang, Yi, 2013. "Industrial waste heat utilization for low temperature district heating," Energy Policy, Elsevier, vol. 62(C), pages 236-246.
    9. Kenisarin, Murat & Mahkamov, Khamid, 2007. "Solar energy storage using phase change materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(9), pages 1913-1965, December.
    10. Li, Hailong & Wang, Weilong & Yan, Jinyue & Dahlquist, Erik, 2013. "Economic assessment of the mobilized thermal energy storage (M-TES) system for distributed heat supply," Applied Energy, Elsevier, vol. 104(C), pages 178-186.
    11. Sharma, Atul & Tyagi, V.V. & Chen, C.R. & Buddhi, D., 2009. "Review on thermal energy storage with phase change materials and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(2), pages 318-345, February.
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