IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v115y2014icp265-271.html
   My bibliography  Save this article

Thermal property measurement and heat storage analysis of LiNO3/KCl – expanded graphite composite phase change material

Author

Listed:
  • Huang, Zhaowen
  • Gao, Xuenong
  • Xu, Tao
  • Fang, Yutang
  • Zhang, Zhengguo

Abstract

A LiNO3/KCl-expanded graphite (EG) composite phase change material (PCM) was prepared for solar thermal energy storage application at high temperature (∼200°C). In such composite material, eutectic system LiNO3/KCl is characterized by high phase change latent heat and EG serves as the heat transfer promoter. Investigations by means of differential scanning calorimetry (DSC), hot disk analyzer and heat storage performance tests in a latent thermal energy storage (LTES) unit were devoted to the thermal property measurement and heat storage performance analysis of the LiNO3/KCl–EG composite. Experimental results revealed that the melting temperature of the composite material was close to that of the eutectic LiNO3/KCl, and the phase change latent heat ranging from 142.41 to 178.10J/g was dependent on its mass fraction of EG. The thermal conductivities of the composites were 1.85–7.56 times higher compared with the eutectic LiNO3/KCl, and the conductivity value varied with the EG mass content and the apparent density of the composite. In addition, the heat transfer in the composite material during the heat storage process was enhanced through the thermal conductivity improvement, while the heat storage duration was affected by the phase change latent heat and the apparent density of the composite material.

Suggested Citation

  • Huang, Zhaowen & Gao, Xuenong & Xu, Tao & Fang, Yutang & Zhang, Zhengguo, 2014. "Thermal property measurement and heat storage analysis of LiNO3/KCl – expanded graphite composite phase change material," Applied Energy, Elsevier, vol. 115(C), pages 265-271.
    • Handle: RePEc:eee:appene:v:115:y:2014:i:c:p:265-271
    DOI: 10.1016/j.apenergy.2013.11.019
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261913009124
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2013.11.019?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Kuznik, Frédéric & David, Damien & Johannes, Kevyn & Roux, Jean-Jacques, 2011. "A review on phase change materials integrated in building walls," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 379-391, January.
    2. Zhang, Zhengguo & Zhang, Ni & Peng, Jing & Fang, Xiaoming & Gao, Xuenong & Fang, Yutang, 2012. "Preparation and thermal energy storage properties of paraffin/expanded graphite composite phase change material," Applied Energy, Elsevier, vol. 91(1), pages 426-431.
    3. Fan, Liwu & Khodadadi, J.M., 2011. "Thermal conductivity enhancement of phase change materials for thermal energy storage: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 24-46, January.
    4. Kenisarin, Murat M., 2010. "High-temperature phase change materials for thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(3), pages 955-970, April.
    5. Li, TingXian & Lee, Ju-Hyuk & Wang, RuZhu & Kang, Yong Tae, 2013. "Enhancement of heat transfer for thermal energy storage application using stearic acid nanocomposite with multi-walled carbon nanotubes," Energy, Elsevier, vol. 55(C), pages 752-761.
    6. Li, Min, 2013. "A nano-graphite/paraffin phase change material with high thermal conductivity," Applied Energy, Elsevier, vol. 106(C), pages 25-30.
    7. Wang, Xianglei & Guo, Quangui & Zhong, Yajuan & Wei, Xinghai & Liu, Lang, 2013. "Heat transfer enhancement of neopentyl glycol using compressed expanded natural graphite for thermal energy storage," Renewable Energy, Elsevier, vol. 51(C), pages 241-246.
    8. Tyagi, Vineet Veer & Buddhi, D., 2007. "PCM thermal storage in buildings: A state of art," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(6), pages 1146-1166, August.
    9. Sharma, Atul & Tyagi, V.V. & Chen, C.R. & Buddhi, D., 2009. "Review on thermal energy storage with phase change materials and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(2), pages 318-345, February.
    10. Tian, Y. & Zhao, C.Y., 2013. "A review of solar collectors and thermal energy storage in solar thermal applications," Applied Energy, Elsevier, vol. 104(C), pages 538-553.
    11. Li, Wei & Zhang, Rong & Jiang, Nan & Tang, Xiao-fen & Shi, Hai-feng & Zhang, Xing-xiang & Zhang, Yuankai & Dong, Lin & Zhang, Ningxin, 2013. "Composite macrocapsule of phase change materials/expanded graphite for thermal energy storage," Energy, Elsevier, vol. 57(C), pages 607-614.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Tao, Y.B. & He, Ya-Ling, 2018. "A review of phase change material and performance enhancement method for latent heat storage system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 93(C), pages 245-259.
    2. Ge, Haoshan & Li, Haiyan & Mei, Shengfu & Liu, Jing, 2013. "Low melting point liquid metal as a new class of phase change material: An emerging frontier in energy area," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 331-346.
    3. Kenisarin, Murat & Mahkamov, Khamid, 2016. "Passive thermal control in residential buildings using phase change materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 371-398.
    4. Zhang, P. & Xiao, X. & Ma, Z.W., 2016. "A review of the composite phase change materials: Fabrication, characterization, mathematical modeling and application to performance enhancement," Applied Energy, Elsevier, vol. 165(C), pages 472-510.
    5. Aadmi, Moussa & Karkri, Mustapha & El Hammouti, Mimoun, 2014. "Heat transfer characteristics of thermal energy storage of a composite phase change materials: Numerical and experimental investigations," Energy, Elsevier, vol. 72(C), pages 381-392.
    6. Zhou, Zhihua & Zhang, Zhiming & Zuo, Jian & Huang, Ke & Zhang, Liying, 2015. "Phase change materials for solar thermal energy storage in residential buildings in cold climate," Renewable and Sustainable Energy Reviews, Elsevier, vol. 48(C), pages 692-703.
    7. Amaral, C. & Vicente, R. & Marques, P.A.A.P. & Barros-Timmons, A., 2017. "Phase change materials and carbon nanostructures for thermal energy storage: A literature review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1212-1228.
    8. Soares, N. & Bastos, J. & Pereira, L. Dias & Soares, A. & Amaral, A.R. & Asadi, E. & Rodrigues, E. & Lamas, F.B. & Monteiro, H. & Lopes, M.A.R. & Gaspar, A.R., 2017. "A review on current advances in the energy and environmental performance of buildings towards a more sustainable built environment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 845-860.
    9. Soares, N. & Gaspar, A.R. & Santos, P. & Costa, J.J., 2015. "Experimental study of the heat transfer through a vertical stack of rectangular cavities filled with phase change materials," Applied Energy, Elsevier, vol. 142(C), pages 192-205.
    10. Khadiran, Tumirah & Hussein, Mohd Zobir & Zainal, Zulkarnain & Rusli, Rafeadah, 2016. "Advanced energy storage materials for building applications and their thermal performance characterization: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 916-928.
    11. Zeinelabdein, Rami & Omer, Siddig & Gan, Guohui, 2018. "Critical review of latent heat storage systems for free cooling in buildings," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2843-2868.
    12. Soares, N. & Santos, P. & Gervásio, H. & Costa, J.J. & Simões da Silva, L., 2017. "Energy efficiency and thermal performance of lightweight steel-framed (LSF) construction: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 78(C), pages 194-209.
    13. Yuan, Yanping & Zhang, Nan & Li, Tianyu & Cao, Xiaoling & Long, Weiyue, 2016. "Thermal performance enhancement of palmitic-stearic acid by adding graphene nanoplatelets and expanded graphite for thermal energy storage: A comparative study," Energy, Elsevier, vol. 97(C), pages 488-497.
    14. Zhou, Dan & Wu, Shaowen & Wu, Zhigen & Yu, Xingjuan, 2021. "Thermal performance analysis of multi-slab phase change thermal energy storage unit with heat transfer enhancement approaches," Renewable Energy, Elsevier, vol. 172(C), pages 46-56.
    15. Li, Min & Mu, Boyuan, 2019. "Effect of different dimensional carbon materials on the properties and application of phase change materials: A review," Applied Energy, Elsevier, vol. 242(C), pages 695-715.
    16. Mohamed, Shamseldin A. & Al-Sulaiman, Fahad A. & Ibrahim, Nasiru I. & Zahir, Md. Hasan & Al-Ahmed, Amir & Saidur, R. & Yılbaş, B.S. & Sahin, A.Z., 2017. "A review on current status and challenges of inorganic phase change materials for thermal energy storage systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 1072-1089.
    17. Jankowski, Nicholas R. & McCluskey, F. Patrick, 2014. "A review of phase change materials for vehicle component thermal buffering," Applied Energy, Elsevier, vol. 113(C), pages 1525-1561.
    18. Memon, Shazim Ali, 2014. "Phase change materials integrated in building walls: A state of the art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 870-906.
    19. Jiang, Feng & Zhang, Lingling & She, Xiaohui & Li, Chuan & Cang, Daqiang & Liu, Xianglei & Xuan, Yimin & Ding, Yulong, 2020. "Skeleton materials for shape-stabilization of high temperature salts based phase change materials: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    20. Ma, Zhenjun & Lin, Wenye & Sohel, M. Imroz, 2016. "Nano-enhanced phase change materials for improved building performance," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 1256-1268.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:115:y:2014:i:c:p:265-271. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.