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Hydrophilic modification of expanded graphite to develop form-stable composite phase change material based on modified CaCl2·6H2O

Author

Listed:
  • Zou, Ting
  • Fu, Wanwan
  • Liang, Xianghui
  • Wang, Shuangfeng
  • Gao, Xuenong
  • Zhang, Zhengguo
  • Fang, Yutang

Abstract

Cold energy storage using phase change materials (PCMs) in air-conditioning system is a favorable solution to the improvement of energy efficiency. In this work, the hydrophilic modification of EG through TiO2 coating was conducted to improve the compatibility of EG with modified CaCl2·6H2O PCM. Subsequently, the compressed modified EG (MEG) block was immersed into the melted modified CaCl2·6H2O to develop form-stable composite PCM. The results of contact angle and adsorption capacity tests confirmed that MEG possessed an enhanced hydrophilicity and improved adsorption property for modified CaCl2·6H2O PCM in comparison to EG. The results of SEM and pore analysis revealed that MEG still retained its inherent mesopore structure, contributing to the adsorption of MEG on the melted modified CaCl2·6H2O. The obtained composite PCM melted at 10.67 °C with the melting enthalpy of 88.39 J/g and a negligible supercooling degree (0.18 °C) as well as the enhanced thermal conductivity (8.831 W m−1K−1). Besides, the composite PCM exhibited a good thermal stability. The modified CaCl2·6H2O/MEG composite PCM shows good application prospects in cold energy storage, providing a new routine for improving the compatibility of EG with salt hydrates.

Suggested Citation

  • Zou, Ting & Fu, Wanwan & Liang, Xianghui & Wang, Shuangfeng & Gao, Xuenong & Zhang, Zhengguo & Fang, Yutang, 2020. "Hydrophilic modification of expanded graphite to develop form-stable composite phase change material based on modified CaCl2·6H2O," Energy, Elsevier, vol. 190(C).
    • Handle: RePEc:eee:energy:v:190:y:2020:i:c:s0360544219321681
    DOI: 10.1016/j.energy.2019.116473
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    References listed on IDEAS

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    Cited by:

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    2. Liu, Yali & Li, Ming & Emam Hassanien, Reda Hassanien & Wang, Yunfeng & Tang, Runsheng & Zhang, Ying, 2024. "Fabrication of shape-stable glycine water-based phase-change material using modified expanded graphite for cold energy storage," Energy, Elsevier, vol. 290(C).
    3. Gowthami, D. & Sharma, R.K., 2023. "Influence of Hydrophilic and Hydrophobic modification of the porous matrix on the thermal performance of form stable phase change materials: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 185(C).
    4. Jiang, Zhu & Palacios, Anabel & Zou, Boyang & Zhao, Yanqi & Deng, Weiyu & Zhang, Xiaosong & Ding, Yulong, 2022. "A review on the fabrication methods for structurally stabilised composite phase change materials and their impacts on the properties of materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).

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