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Facilely synthesized porous polymer as support of poly(ethyleneimine) for effective CO2 capture

Author

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  • Irani, Maryam
  • Jacobson, Andrew T.
  • Gasem, Khaled A.M.
  • Fan, Maohong

Abstract

In this work, an effective adsorbent (polyHIPE/PEI) was developed for use in CO2 capture technologies. For this purpose, a porous polymer was prepared by high internal phase emulsion (HIPE) using 2-Ethylhexyl methacrylate (EHMA) and divinylbenzene (DVB). This prepared porous polymer (polyHIPE) was then used as a novel support for the wet impregnation of polyethylenimine (PEI), thus resulting in the polyHIPE/PEI adsorbent. The prepared adsorbent was characterized using Fourier transform infrared spectroscopy (FTIR), solid-state nuclear magnetic resonance (NMR) spectroscopy, scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and Brunauer-Emmett-Teller (BET) surface area analyses. At the optimal PEI loading of 60 wt% on polyHIPE, the CO2 sorption capacity reached 4 mmol CO2/g-sorbent using 10 vol% CO2 and 3 vol% H2O in N2 at 70 °C. Kinetic and thermodynamic adsorption studies showed that the activation energies for CO2 adsorption and desorption of polyHIPE/PEI are 13.74 kJ/mol and 36.12 kJ/mol, respectively. These results indicate that CO2 desorption using polyHIPE/PEI has the potential to reduce CO2 capture cost due to the low activation energy and high CO2 desorption rate. As such, polyHIPE/PEI constitutes an advantageous alternative to traditional methods in CO2 capture from gas mixtures.

Suggested Citation

  • Irani, Maryam & Jacobson, Andrew T. & Gasem, Khaled A.M. & Fan, Maohong, 2018. "Facilely synthesized porous polymer as support of poly(ethyleneimine) for effective CO2 capture," Energy, Elsevier, vol. 157(C), pages 1-9.
    • Handle: RePEc:eee:energy:v:157:y:2018:i:c:p:1-9
    DOI: 10.1016/j.energy.2018.05.141
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    2. Zhao, Peiyu & Yin, Yanchao & Xu, Xianmang & Yang, Deliang & Wang, Jin & Yang, Fuxing & Zhang, Guojie, 2022. "Facile fabrication of mesoporosity silica as support for solid amine CO2 adsorbents with enhanced adsorption capacity and kinetics," Energy, Elsevier, vol. 253(C).
    3. Fereshteh Hojatisaeidi & Mauro Mureddu & Federica Dessì & Geraldine Durand & Basudeb Saha, 2020. "Metal-Free Modified Boron Nitride for Enhanced CO 2 Capture," Energies, MDPI, vol. 13(3), pages 1-11, January.
    4. Fatemeh Fashi & Ahad Ghaemi & Peyman Moradi, 2019. "Piperazine‐modified activated alumina as a novel promising candidate for CO2 capture: experimental and modeling," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 9(1), pages 37-51, February.
    5. Chen, Hao & Zhang, Yao Jun & He, Pan Yang & Li, Chan Juan, 2019. "Synthesis, characterization and modification of monolithic ZSM-5 from geopolymer for CO2 capture: Experiments and DFT calculations," Energy, Elsevier, vol. 179(C), pages 422-430.
    6. Mukhtar, Ahmad & Ullah, Sami & Inayat, Abrar & Saqib, Sidra & Mellon, Nurhayati Binti & Assiri, Mohammed Ali & Al-Sehemi, Abdullah G. & Khan Niazi, Muhammad Bilal & Jahan, Zaib & Bustam, Mohamad Azmi , 2021. "Synthesis-structure-property relationship of nitrogen-doped porous covalent triazine frameworks for pre-combustion CO2 capture," Energy, Elsevier, vol. 216(C).
    7. Dissanayake, Pavani Dulanja & You, Siming & Igalavithana, Avanthi Deshani & Xia, Yinfeng & Bhatnagar, Amit & Gupta, Souradeep & Kua, Harn Wei & Kim, Sumin & Kwon, Jung-Hwan & Tsang, Daniel C.W. & Ok, , 2020. "Biochar-based adsorbents for carbon dioxide capture: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).

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    Keywords

    CO2 capture; Porous polymer; Adsorption; Desorption; Kinetics;
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