IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v179y2019icp422-430.html
   My bibliography  Save this article

Synthesis, characterization and modification of monolithic ZSM-5 from geopolymer for CO2 capture: Experiments and DFT calculations

Author

Listed:
  • Chen, Hao
  • Zhang, Yao Jun
  • He, Pan Yang
  • Li, Chan Juan

Abstract

Zeolites exhibit the highest performance metrics among the second generation of post-combustion CO2 capture materials; however, conventional synthetic zeolite powders are relatively expensive and need to be shaped by binding agents for end use. In this study, cost-effective monolithic Na/ZSM-5 was successfully prepared for the first time using metakaolin and industrial silica fume waste as starting materials via polycondensation and seed-induced hydrothermal crystallization. The synthesised Na/ZSM-5 exhibited an adsorption capacity of 1.79 mmol/g CO2. To further enhance the CO2 adsorption capacity, the Ni/ZSM-5 was modified by ion-exchange of Na+ with Ni2+, revealing an improved adsorption capacity of 2.38 mmol/g CO2. Density functional theory (DFT) calculations were employed to explain the adsorption mechanism and the superior CO2 adsorption performance of Ni/ZSM-5 compared to Na/ZSM-5. The results show that the sorption of CO2 in both Na/ZSM-5 and Ni/ZSM-5 is physisorption by ion–dipole interaction, and the energy emission using Ni/ZSM-5 is higher than that using Na/ZSM-5 for the same CO2 capture efficiency. This research demonstrates a new method of preparing cost-effective shape-controllable zeolites with excellent CO2 capture capacity. Furthermore, it enables the high value-added utilization of the industrial waste of silica fume.

Suggested Citation

  • Chen, Hao & Zhang, Yao Jun & He, Pan Yang & Li, Chan Juan, 2019. "Synthesis, characterization and modification of monolithic ZSM-5 from geopolymer for CO2 capture: Experiments and DFT calculations," Energy, Elsevier, vol. 179(C), pages 422-430.
    • Handle: RePEc:eee:energy:v:179:y:2019:i:c:p:422-430
    DOI: 10.1016/j.energy.2019.04.113
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544219307467
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2019.04.113?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Irani, Maryam & Jacobson, Andrew T. & Gasem, Khaled A.M. & Fan, Maohong, 2018. "Facilely synthesized porous polymer as support of poly(ethyleneimine) for effective CO2 capture," Energy, Elsevier, vol. 157(C), pages 1-9.
    2. Bhave, Amit & Taylor, Richard H.S. & Fennell, Paul & Livingston, William R. & Shah, Nilay & Dowell, Niall Mac & Dennis, John & Kraft, Markus & Pourkashanian, Mohammed & Insa, Mathieu & Jones, Jenny & , 2017. "Screening and techno-economic assessment of biomass-based power generation with CCS technologies to meet 2050 CO2 targets," Applied Energy, Elsevier, vol. 190(C), pages 481-489.
    3. Yang, Ao & Sun, Shirui & Eslamimanesh, Ali & Wei, Shun'an & Shen, Weifeng, 2019. "Energy-saving investigation for diethyl carbonate synthesis through the reactive dividing wall column combining the vapor recompression heat pump or different pressure thermally coupled technique," Energy, Elsevier, vol. 172(C), pages 320-332.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Tan, R.R. & Aviso, K.B. & Ng, D.K.S., 2019. "Optimization models for financing innovations in green energy technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    2. Ren, Siyue & Feng, Xiao & Wang, Yufei, 2021. "Emergy evaluation of the integrated gasification combined cycle power generation systems with a carbon capture system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 147(C).
    3. Negri, Valentina & Galán-Martín, Ángel & Pozo, Carlos & Fajardy, Mathilde & Reiner, David M. & Mac Dowell, Niall & Guillén-Gosálbez, Gonzalo, 2021. "Life cycle optimization of BECCS supply chains in the European Union," Applied Energy, Elsevier, vol. 298(C).
    4. Saharudin, Djasmine Mastisya & Jeswani, Harish Kumar & Azapagic, Adisa, 2023. "Bioenergy with carbon capture and storage (BECSS): Life cycle environmental and economic assessment of electricity generated from palm oil wastes," Applied Energy, Elsevier, vol. 349(C).
    5. Galán-Martín, Ángel & Contreras, María del Mar & Romero, Inmaculada & Ruiz, Encarnación & Bueno-Rodríguez, Salvador & Eliche-Quesada, Dolores & Castro-Galiano, Eulogio, 2022. "The potential role of olive groves to deliver carbon dioxide removal in a carbon-neutral Europe: Opportunities and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 165(C).
    6. Mohd Idris, Muhammad Nurariffudin & Hashim, Haslenda & Leduc, Sylvain & Yowargana, Ping & Kraxner, Florian & Woon, Kok Sin, 2021. "Deploying bioenergy for decarbonizing Malaysian energy sectors and alleviating renewable energy poverty," Energy, Elsevier, vol. 232(C).
    7. Wu, Zitao & Zhai, Haibo, 2021. "Consumptive life cycle water use of biomass-to-power plants with carbon capture and sequestration," Applied Energy, Elsevier, vol. 303(C).
    8. Fereshteh Hojatisaeidi & Mauro Mureddu & Federica Dessì & Geraldine Durand & Basudeb Saha, 2020. "Metal-Free Modified Boron Nitride for Enhanced CO 2 Capture," Energies, MDPI, vol. 13(3), pages 1-11, January.
    9. Mukhtar, Ahmad & Ullah, Sami & Inayat, Abrar & Saqib, Sidra & Mellon, Nurhayati Binti & Assiri, Mohammed Ali & Al-Sehemi, Abdullah G. & Khan Niazi, Muhammad Bilal & Jahan, Zaib & Bustam, Mohamad Azmi , 2021. "Synthesis-structure-property relationship of nitrogen-doped porous covalent triazine frameworks for pre-combustion CO2 capture," Energy, Elsevier, vol. 216(C).
    10. Sun, Shirui & Chun, Wei & Yang, Ao & Shen, Weifeng & Cui, Peizhe & Ren, Jingzheng, 2020. "The separation of ternary azeotropic mixture: Thermodynamic insight and improved multi-objective optimization," Energy, Elsevier, vol. 206(C).
    11. Zhang, Huafu & Tong, Lige & Zhang, Zhentao & Song, Yanchang & Yang, Junling & Yue, Yunkai & Wu, Zhenqun & Wang, Youdong & Yu, Ze & Zhang, Junhao, 2023. "A integrated mechanical vapor compression enrichment system of radioactive wastewater: Experimental study, model optimization and performance prediction," Energy, Elsevier, vol. 282(C).
    12. Sammarchi, Sergio & Li, Jia & Izikowitz, David & Yang, Qiang & Xu, Dong, 2022. "China’s coal power decarbonization via CO2 capture and storage and biomass co-firing: A LCA case study in Inner Mongolia," Energy, Elsevier, vol. 261(PA).
    13. Pour, Nasim & Webley, Paul A. & Cook, Peter J., 2018. "Opportunities for application of BECCS in the Australian power sector," Applied Energy, Elsevier, vol. 224(C), pages 615-635.
    14. Kiss, Anton A. & Smith, Robin, 2020. "Rethinking energy use in distillation processes for a more sustainable chemical industry," Energy, Elsevier, vol. 203(C).
    15. Cohen, Francois & Pfeiffer, Alexander, 2018. "The Impact of Negative Emissions Technologies and Natural Climate Solutions on Power-Sector Asset Stranding," INET Oxford Working Papers 2018-02, Institute for New Economic Thinking at the Oxford Martin School, University of Oxford.
    16. Arning, K. & Offermann-van Heek, J. & Linzenich, A. & Kaetelhoen, A. & Sternberg, A. & Bardow, A. & Ziefle, M., 2019. "Same or different? Insights on public perception and acceptance of carbon capture and storage or utilization in Germany," Energy Policy, Elsevier, vol. 125(C), pages 235-249.
    17. Safdarnejad, Seyed Mostafa & Hedengren, John D. & Powell, Kody M., 2018. "Performance comparison of low temperature and chemical absorption carbon capture processes in response to dynamic electricity demand and price profiles," Applied Energy, Elsevier, vol. 228(C), pages 577-592.
    18. Stančin, H. & Mikulčić, H. & Wang, X. & Duić, N., 2020. "A review on alternative fuels in future energy system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 128(C).
    19. Ma, Chunyan & Wang, Nan & Chen, Yifeng & Khokarale, Santosh Govind & Bui, Thai Q. & Weiland, Fredrik & Lestander, Torbjörn A. & Rudolfsson, Magnus & Mikkola, Jyri-Pekka & Ji, Xiaoyan, 2020. "Towards negative carbon emissions: Carbon capture in bio-syngas from gasification by aqueous pentaethylenehexamine," Applied Energy, Elsevier, vol. 279(C).
    20. Wang Lu & Pietro Bartocci & Alberto Abad & Aldo Bischi & Haiping Yang & Arturo Cabello & Margarita de Las Obras Loscertales & Mauro Zampilli & Francesco Fantozzi, 2023. "Dimensioning Air Reactor and Fuel Reactor of a Pressurized CLC Plant to Be Coupled to a Gas Turbine: Part 2, the Fuel Reactor," Energies, MDPI, vol. 16(9), pages 1-16, April.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:179:y:2019:i:c:p:422-430. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.