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Non-aqueous energy-efficient absorbents for CO2 capture based on porous silica nanospheres impregnated with amine

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  • Li, Xiaoqiang
  • Ding, Yudong
  • Guo, Liheng
  • Liao, Qiang
  • Zhu, Xun
  • Wang, Hong

Abstract

Colloidal suspensions as absorbents were synthesized by dispersing porous silica nanospheres (PSNs) modified by amine impregnation in dimethyaminoethoxyethanol (DMEE) for CO2 capture. The results of SEM, TEM, BET, FTIR analysis and TGA indicated that PSNs presented high surface areas and uniform morphology, and the impregnation method could effectively control the amine loading content. In addition, CO2 absorption measurements were conducted to investigate the effects of PEI loading content. The results revealed that the absorption capacities of PEI-PSNs/DMEE first increased and then decreased, and 50 wt%PEI-PSNs/DMEE exhibited the highest CO2 capture capacity, which could be up to 0.728 mmol g−1. Further studies on the effects of the structure of the amines were conducted using polyamines (PEI(600) and PEI(1800)), alkylamines (DETA, TETA, TEPA), and other amines (MEA and [N1111][Gly]). It was found that MEA-PSNs/DMEE and DETA-PSNs/DMEE exhibited better absorption performance than PEI(1800)-PSNs/DMEE and ILs-PSNs/DMEE. This suggested that the functional groups and molecular weight of the amines were important factors affecting the CO2 absorption performance of the colloidal suspensions. Finally, regeneration studies suggested that CO2 could be easily removed from the anhydrous sorbents, thus avoiding the generation of waste water and thereby significantly reducing the energy consumption during the regeneration process.

Suggested Citation

  • Li, Xiaoqiang & Ding, Yudong & Guo, Liheng & Liao, Qiang & Zhu, Xun & Wang, Hong, 2019. "Non-aqueous energy-efficient absorbents for CO2 capture based on porous silica nanospheres impregnated with amine," Energy, Elsevier, vol. 171(C), pages 109-119.
  • Handle: RePEc:eee:energy:v:171:y:2019:i:c:p:109-119
    DOI: 10.1016/j.energy.2018.12.175
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    Cited by:

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    2. Guo, Liheng & Ding, Yudong & Liao, Qiang & Zhu, Xun & Wang, Hong, 2022. "A new heat supply strategy for CO2 capture process based on the heat recovery from turbine exhaust steam in a coal-fired power plant," Energy, Elsevier, vol. 239(PA).
    3. Mukhtar, Ahmad & Ullah, Sami & Inayat, Abrar & Saqib, Sidra & Mellon, Nurhayati Binti & Assiri, Mohammed Ali & Al-Sehemi, Abdullah G. & Khan Niazi, Muhammad Bilal & Jahan, Zaib & Bustam, Mohamad Azmi , 2021. "Synthesis-structure-property relationship of nitrogen-doped porous covalent triazine frameworks for pre-combustion CO2 capture," Energy, Elsevier, vol. 216(C).
    4. Wang, Rujie & Zhao, Huajun & Yang, Xiaotong & Qi, Cairao & Zhao, Haonan & Zhang, Shihan & Li, Qiangwei & Li, Ping & Wang, Lidong, 2023. "Energy-efficient non-aqueous biphasic solvent for carbon capture: Absorption mechanism, phase evolution process, and non-corrosiveness," Energy, Elsevier, vol. 281(C).
    5. Zhao, Xingxing & Ding, Yudong & Ma, Lijiao & Zhu, Xun & Wang, Hong & Cheng, Min & Liao, Qiang, 2023. "An amine-functionalized strategy to enhance the CO2 absorption of type III porous liquids," Energy, Elsevier, vol. 279(C).
    6. Li, Xiangyu & Wang, Zhiqing & Liu, Zheyu & Feng, Ru & Song, Shuangshuang & Huang, Jiejie & Fang, Yitian, 2022. "A novel preparation of solid amine sorbents for enhancing CO2 adsorption capacity using alumina-extracted waste," Energy, Elsevier, vol. 248(C).
    7. Ding, Yudong & Ma, Lijiao & Yang, Xiaoqiang & Zhu, Xun & Wang, Hong & Cheng, Min & Liao, Qiang, 2023. "Anhydrous multi-hybrid absorbent with low viscosity and high regeneration efficiency for post-combustion CO2 capture," Energy, Elsevier, vol. 263(PA).
    8. Yudong Ding & Liheng Guo & Xiaoqiang Li & Qiang Liao & Xun Zhu & Hong Wang, 2021. "CO2 absorption of anhydrous colloidal suspension based silica nanospheres with different microstructures," Energy & Environment, , vol. 32(8), pages 1437-1456, December.

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