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Biochar-based adsorbents for carbon dioxide capture: A critical review

Author

Listed:
  • Dissanayake, Pavani Dulanja
  • You, Siming
  • Igalavithana, Avanthi Deshani
  • Xia, Yinfeng
  • Bhatnagar, Amit
  • Gupta, Souradeep
  • Kua, Harn Wei
  • Kim, Sumin
  • Kwon, Jung-Hwan
  • Tsang, Daniel C.W.
  • Ok, Yong Sik

Abstract

Carbon dioxide (CO2) is the main anthropogenic greenhouse gas contributing to global warming, causing tremendous impacts on the global ecosystem. Fossil fuel combustion is the main anthropogenic source of CO2 emissions. Biochar, a porous carbonaceous material produced through the thermochemical conversion of organic materials in oxygen-depleted conditions, is emerging as a cost-effective green sorbent to maintain environmental quality by capturing CO2. Currently, the modification of biochar using different physico-chemical processes, as well as the synthesis of biochar composites to enhance the contaminant sorption capacity, has drawn significant interest from the scientific community, which could also be used for capturing CO2. This review summarizes and evaluates the potential of using pristine and engineered biochar as CO2 capturing media, as well as the factors influencing the CO2 adsorption capacity of biochar and issues related to the synthesis of biochar-based CO2 adsorbents. The CO2 adsorption capacity of biochar is greatly governed by physico-chemical properties of biochar such as specific surface area, microporosity, aromaticity, hydrophobicity and the presence of basic functional groups which are influenced by feedstock type and production conditions of biochar. Micropore area (R2 = 0.9032, n = 32) and micropore volume (R2 = 0.8793, n = 32) showed a significant positive relationship with CO2 adsorption capacity of biochar. These properties of biochar are closely related to the type of feedstock and the thermochemical conditions of biochar production. Engineered biochar significantly increases CO2 adsorption capacity of pristine biochar due to modification of surface properties. Despite the progress in biochar development, further studies should be conducted to develop cost-effective, sustainable biochar-based composites for use in large-scale CO2 capture.

Suggested Citation

  • Dissanayake, Pavani Dulanja & You, Siming & Igalavithana, Avanthi Deshani & Xia, Yinfeng & Bhatnagar, Amit & Gupta, Souradeep & Kua, Harn Wei & Kim, Sumin & Kwon, Jung-Hwan & Tsang, Daniel C.W. & Ok, , 2020. "Biochar-based adsorbents for carbon dioxide capture: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    • Handle: RePEc:eee:rensus:v:119:y:2020:i:c:s1364032119307907
    DOI: 10.1016/j.rser.2019.109582
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    2. Dahl Winters & Kwaku Boakye & Steven Simske, 2022. "Toward Carbon-Neutral Concrete through Biochar–Cement–Calcium Carbonate Composites: A Critical Review," Sustainability, MDPI, vol. 14(8), pages 1-25, April.
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    4. Han, Lanfang & Sun, Haoran & Sun, Ke & Yang, Yan & Fang, Liping & Xing, Baoshan, 2021. "Effect of Fe and Al ions on the production of biochar from agricultural biomass: Properties, stability and adsorption efficiency of biochar," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    5. Farihahusnah Hussin & Mohamed Kheireddine Aroua & Mohd Azlan Kassim & Umi Fazara Md. Ali, 2021. "Transforming Plastic Waste into Porous Carbon for Capturing Carbon Dioxide: A Review," Energies, MDPI, vol. 14(24), pages 1-22, December.
    6. Chiappero, Marco & Norouzi, Omid & Hu, Mingyu & Demichelis, Francesca & Berruti, Franco & Di Maria, Francesco & Mašek, Ondřej & Fiore, Silvia, 2020. "Review of biochar role as additive in anaerobic digestion processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 131(C).
    7. Haleem, Noor & Khattak, Alishba & Jamal, Yousuf & Sajid, Masooma & Shahzad, Zainab & Raza, Hammad, 2022. "Development of poly vinyl alcohol (PVA) based biochar nanofibers for carbon dioxide (CO2) adsorption," Renewable and Sustainable Energy Reviews, Elsevier, vol. 157(C).
    8. Shukla, Parul & Giri, Balendu Shekhar & Mishra, Rakesh K. & Pandey, Ashok & Chaturvedi, Preeti, 2021. "Lignocellulosic biomass-based engineered biochar composites: A facile strategy for abatement of emerging pollutants and utilization in industrial applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    9. Kumar, A. Naresh & Dissanayake, Pavani Dulanja & Masek, Ondrej & Priya, Anshu & Ki Lin, Carol Sze & Ok, Yong Sik & Kim, Sang-Hyoun, 2021. "Recent trends in biochar integration with anaerobic fermentation: Win-win strategies in a closed-loop," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
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    11. Aan Mohammad Nusrat Aman & Anurita Selvarajoo & Teck Leong Lau & Wei-Hsin Chen, 2022. "Biochar as Cement Replacement to Enhance Concrete Composite Properties: A Review," Energies, MDPI, vol. 15(20), pages 1-20, October.
    12. Safarzadeh, Soroush & Hafezalkotob, Ashkan & Jafari, Hamed, 2022. "Energy supply chain empowerment through tradable green and white certificates: A pathway to sustainable energy generation," Applied Energy, Elsevier, vol. 323(C).
    13. Piotr Sakiewicz & Marcin Lutyński & Jakub Sobieraj & Krzysztof Piotrowski & Francesco Miccio & Sylwester Kalisz, 2022. "Adsorption of CO 2 on In Situ Functionalized Straw Burning Ashes—An Innovative, Circular Economy-Based Concept for Limitation of Industrial-Scale Greenhouse Gas Emission," Energies, MDPI, vol. 15(4), pages 1-28, February.
    14. Georgios Varvoutis & Athanasios Lampropoulos & Evridiki Mandela & Michalis Konsolakis & George E. Marnellos, 2022. "Recent Advances on CO 2 Mitigation Technologies: On the Role of Hydrogenation Route via Green H 2," Energies, MDPI, vol. 15(13), pages 1-38, June.
    15. Senthil, Chenrayan & Lee, Chang Woo, 2021. "Biomass-derived biochar materials as sustainable energy sources for electrochemical energy storage devices," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).

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