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Development of a new clay supported polyethylenimine composite for CO2 capture

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  • Wang, Weilong
  • Xiao, Jing
  • Wei, Xiaolan
  • Ding, Jing
  • Wang, Xiaoxing
  • Song, Chunshan

Abstract

A new inexpensive inorganic–organic composite sorbent for CO2 capture was prepared by the immobilization of a branched polyethyleneimine (PEI) onto porosity-enhanced clays using the wet impregnation method. In the composite, a low cost and naturally abundant clays (e.g. kaolinite and montmorillonite) was used as the supporting material, which was pre-modified by acid- or alkaline-treatment to improve its textural properties, i.e. pore volume and surface area, for accommodating the CO2-philic PEI. Among the modified clays, the montmorillonite modified by 6M HCl (Mon_HCl_6M) showed the highest porosity with the pore volume of 0.71cm3/g from 0.16cm3/g, and BET surface area of 253m2/g from 72m2/g. The cost of the Mon_HCl_6M was estimated as $0.14/kg, which was significantly lower than reported supporting materials for the amine-based sorbents for CO2 capture. At the optimal PEI loading of 50 wt% on the Mon_HCl_6M support, the CO2 sorption capacity reached 112mg CO2/g-sorbent at 75°C under dry condition, which can be further enhanced to 142mg CO2/g-sorbent with the moisture addition (ca. 3vol%) due to the change in the interaction mechanism between CO2 and amine in the presence of moisture. Moreover, the PEI/Mon_HCl_6M sorbent showed a good regenerability for 10 sorption–desorption cycles tested and a good thermal stability in the temperature range of CO2 sorption (75°C) and desorption (100°C).

Suggested Citation

  • Wang, Weilong & Xiao, Jing & Wei, Xiaolan & Ding, Jing & Wang, Xiaoxing & Song, Chunshan, 2014. "Development of a new clay supported polyethylenimine composite for CO2 capture," Applied Energy, Elsevier, vol. 113(C), pages 334-341.
    • Handle: RePEc:eee:appene:v:113:y:2014:i:c:p:334-341
    DOI: 10.1016/j.apenergy.2013.03.090
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    1. Lai, Qinghua & Diao, Zhijun & Kong, Lingli & Adidharma, Hertanto & Fan, Maohong, 2018. "Amine-impregnated silicic acid composite as an efficient adsorbent for CO2 capture," Applied Energy, Elsevier, vol. 223(C), pages 293-301.
    2. Li, Kaimin & Jiang, Jianguo & Yan, Feng & Tian, Sicong & Chen, Xuejing, 2014. "The influence of polyethyleneimine type and molecular weight on the CO2 capture performance of PEI-nano silica adsorbents," Applied Energy, Elsevier, vol. 136(C), pages 750-755.
    3. Ren, Yanping & Ding, Ruiyu & Yue, Hairong & Tang, Siyang & Liu, Changjun & Zhao, Jinbo & Lin, Wen & Liang, Bin, 2017. "Amine-grafted mesoporous copper silicates as recyclable solid amine sorbents for post-combustion CO2 capture," Applied Energy, Elsevier, vol. 198(C), pages 250-260.
    4. Guo, Yafei & Zhao, Chuanwen & Chen, Xiaoping & Li, Changhai, 2015. "CO2 capture and sorbent regeneration performances of some wood ash materials," Applied Energy, Elsevier, vol. 137(C), pages 26-36.
    5. Zhao, Chuanwen & Guo, Yafei & Li, Changhai & Lu, Shouxiang, 2014. "Removal of low concentration CO2 at ambient temperature using several potassium-based sorbents," Applied Energy, Elsevier, vol. 124(C), pages 241-247.
    6. Wang, Xianfeng & Akhmedov, Novruz G. & Hopkinson, David & Hoffman, James & Duan, Yuhua & Egbebi, Adefemi & Resnik, Kevin & Li, Bingyun, 2016. "Phase change amino acid salt separates into CO2-rich and CO2-lean phases upon interacting with CO2," Applied Energy, Elsevier, vol. 161(C), pages 41-47.
    7. Li, Xiaoqiang & Ding, Yudong & Guo, Liheng & Liao, Qiang & Zhu, Xun & Wang, Hong, 2019. "Non-aqueous energy-efficient absorbents for CO2 capture based on porous silica nanospheres impregnated with amine," Energy, Elsevier, vol. 171(C), pages 109-119.
    8. Guo, Yafei & Zhao, Chuanwen & Li, Changhai & Lu, Shouxiang, 2014. "Application of PEI–K2CO3/AC for capturing CO2 from flue gas after combustion," Applied Energy, Elsevier, vol. 129(C), pages 17-24.
    9. Wang, Weilong & Guo, Shaopeng & Li, Hailong & Yan, Jinyue & Zhao, Jun & Li, Xun & Ding, Jing, 2014. "Experimental study on the direct/indirect contact energy storage container in mobilized thermal energy system (M-TES)," Applied Energy, Elsevier, vol. 119(C), pages 181-189.
    10. Irani, Maryam & Jacobson, Andrew T. & Gasem, Khaled A.M. & Fan, Maohong, 2018. "Facilely synthesized porous polymer as support of poly(ethyleneimine) for effective CO2 capture," Energy, Elsevier, vol. 157(C), pages 1-9.
    11. Nie, Lijuan & Jin, Junsu & Chen, Jian & Mi, Jianguo, 2018. "Preparation and performance of amine-based polyacrylamide composite beads for CO2 capture," Energy, Elsevier, vol. 161(C), pages 60-69.
    12. Wang, Weilong & Li, Jiang & Wei, Xiaolan & Ding, Jing & Feng, Haijun & Yan, Jinyue & Yang, Jianping, 2015. "Carbon dioxide adsorption thermodynamics and mechanisms on MCM-41 supported polyethylenimine prepared by wet impregnation method," Applied Energy, Elsevier, vol. 142(C), pages 221-228.
    13. Yaumi, A.L. & Bakar, M.Z. Abu & Hameed, B.H., 2017. "Recent advances in functionalized composite solid materials for carbon dioxide capture," Energy, Elsevier, vol. 124(C), pages 461-480.
    14. Tao, Huayu & Qian, Xi & Zhou, Yi & Cheng, Hongfei, 2022. "Research progress of clay minerals in carbon dioxide capture," Renewable and Sustainable Energy Reviews, Elsevier, vol. 164(C).

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