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A new family of Mn-based perovskite (La1-xYxMnO3) with improved oxygen electrocatalytic activity for metal-air batteries

Author

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  • Miao, He
  • Wang, Zhouhang
  • Wang, Qin
  • Sun, Shanshan
  • Xue, Yejian
  • Wang, Fu
  • Zhao, Jiapei
  • Liu, Zhaoping
  • Yuan, Jinliang

Abstract

The sluggish reaction kinetics occurring at the cathodes limits the performances of the metal-air batteries. Therefore, developing the oxygen electrocatalysts which can accelerate oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is a critical issue. Mn-based perovskite has drawn extensive interests though their ORR and OER catalytic activity still needs to be improved. In this work, a new family of Mn-based perovskite (La1-xYxMnO3, LYM) is developed which demonstrates an improved ORR and OER catalytic activity compared with the representative strontium-doped Mn-based perovskite (LSM). For La0.9Y0.1MnO3 (LYM-10), the onset potential and half-wave potential during ORR can reach 0.909 V and 0.750 V (vs. RHE), respectively, which are more positive than those of LSM reported in most of the recent reports. Furthermore, LYM-10 also shows a better OER catalytic activity than La0.7Sr0.3MnO3 (LSM-30). In addition to its good bifunctional property, LYM-10 also achieves the superior durability compared with Pt/C during ORR, and the current retention of LYM-10 is as high as 97.3% after 43000 s. Using LYM-10 as the cathode catalyst, the alunimum-air battery can reach the maximum power density of 266 mW/cm2, and zinc-air battery can obtain low charge-discharge overpotential and the good cycling stability.

Suggested Citation

  • Miao, He & Wang, Zhouhang & Wang, Qin & Sun, Shanshan & Xue, Yejian & Wang, Fu & Zhao, Jiapei & Liu, Zhaoping & Yuan, Jinliang, 2018. "A new family of Mn-based perovskite (La1-xYxMnO3) with improved oxygen electrocatalytic activity for metal-air batteries," Energy, Elsevier, vol. 154(C), pages 561-570.
    • Handle: RePEc:eee:energy:v:154:y:2018:i:c:p:561-570
    DOI: 10.1016/j.energy.2018.04.145
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    References listed on IDEAS

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    1. Chou, Chang-Chen & Liu, Cheng-Hong & Chen, Bing-Hung, 2014. "Effects of reduction temperature and pH value of polyol process on reduced graphene oxide supported Pt electrocatalysts for oxygen reduction reaction," Energy, Elsevier, vol. 70(C), pages 231-238.
    2. Chaisubanan, Napapat & Maniwan, Witchaya & Hunsom, Mali, 2017. "Effect of heat-treatment on the performance of PtM/C (M = Cr, Pd, Co) catalysts towards the oxygen reduction reaction in PEM fuel cell," Energy, Elsevier, vol. 127(C), pages 454-461.
    3. Pei, Pucheng & Wang, Keliang & Ma, Ze, 2014. "Technologies for extending zinc–air battery’s cyclelife: A review," Applied Energy, Elsevier, vol. 128(C), pages 315-324.
    4. Jung, Chi-Young & Kim, Tae-Hyun & Kim, Wha-Jung & Yi, Sung-Chul, 2016. "Computational analysis of the zinc utilization in the primary zinc-air batteries," Energy, Elsevier, vol. 102(C), pages 694-704.
    5. Wang, Wei & Song, Junnan & Kang, Yumao & Chai, Dan & Zhao, Rui & Lei, Ziqiang, 2017. "Sm2O3 embedded in nitrogen doped carbon with mosaic structure: An effective catalyst for oxygen reduction reaction," Energy, Elsevier, vol. 133(C), pages 115-120.
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    3. Liu, Xuan & Xue, Jilai, 2019. "The role of Al2Gd cuboids in the discharge performance and electrochemical behaviors of AZ31-Gd anode for Mg-air batteries," Energy, Elsevier, vol. 189(C).
    4. Liu, Zhenning & Li, Zhiyuan & Ma, Jian & Dong, Xu & Ku, Wen & Wang, Mi & Sun, Hang & Liang, Song & Lu, Guolong, 2018. "Nitrogen and cobalt-doped porous biocarbon materials derived from corn stover as efficient electrocatalysts for aluminum-air batteries," Energy, Elsevier, vol. 162(C), pages 453-459.
    5. Flores-Lasluisa, J.X. & Huerta, F. & Cazorla-Amorós, D. & Morallón, E., 2023. "LaNi1-xCoxO3 perovskites for application in electrochemical reactions involving molecular oxygen," Energy, Elsevier, vol. 273(C).

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