IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v152y2018icp333-340.html
   My bibliography  Save this article

Combustion reaction-derived nitrogen-doped porous carbon as an effective metal-Free catalyst for the oxygen reduction reaction

Author

Listed:
  • Yuan, Wenjing
  • Xie, Anjian
  • Chen, Ping
  • Huang, Fangzhi
  • Li, Shikuo
  • Shen, Yuhua

Abstract

Finding an effective approach to prepare low-cost metal-free catalysts with excellent catalytic performance for the oxygen reduction reaction (ORR) is a crucial challenge for the commercialization of fuel cells. Herein, a novel and effective combustion approach was designed in order to construct the three-dimensional porous carbon foam and followed by heat treatment in an NH3 atmosphere. In the combustion process, sucrose was used as the carbon source to produce the carbon framework, sodium bicarbonate as the pore-foaming agent to form the porous structure. This synthetic route is novel, cost-effective and without using any templates, expensive equipment as well as highly toxic chemical reagents. Compared with the control samples, the typical product exhibits the excellent catalytic activity in terms of not only a positive onset potential and high current density, but also low H2O2 yield and approximate four-electron reaction pathway in alkaline media. The reason may be attributed to the synergistic effect of the three-dimensional porous structure, high BET surface area (up to 1216 m2 g−1) and effective nitrogen-doping of the product. In addition, the novel method is of great importance, which may guide future efforts for the development of other porous carbon-based materials for applications in multi-fields.

Suggested Citation

  • Yuan, Wenjing & Xie, Anjian & Chen, Ping & Huang, Fangzhi & Li, Shikuo & Shen, Yuhua, 2018. "Combustion reaction-derived nitrogen-doped porous carbon as an effective metal-Free catalyst for the oxygen reduction reaction," Energy, Elsevier, vol. 152(C), pages 333-340.
    • Handle: RePEc:eee:energy:v:152:y:2018:i:c:p:333-340
    DOI: 10.1016/j.energy.2018.03.175
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S036054421830584X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2018.03.175?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Chou, Chang-Chen & Liu, Cheng-Hong & Chen, Bing-Hung, 2014. "Effects of reduction temperature and pH value of polyol process on reduced graphene oxide supported Pt electrocatalysts for oxygen reduction reaction," Energy, Elsevier, vol. 70(C), pages 231-238.
    2. V., Vijayalekshmi & Khastgir, Dipak, 2018. "Fabrication and comprehensive investigation of physicochemical and electrochemical properties of chitosan-silica supported silicotungstic acid nanocomposite membranes for fuel cell applications," Energy, Elsevier, vol. 142(C), pages 313-330.
    3. Kakaei, Karim & Gharibi, Hussien, 2014. "Palladium nanoparticle catalysts synthesis on graphene in sodium dodecyl sulfate for oxygen reduction reaction," Energy, Elsevier, vol. 65(C), pages 166-171.
    4. Wang, Wei & Song, Junnan & Kang, Yumao & Chai, Dan & Zhao, Rui & Lei, Ziqiang, 2017. "Sm2O3 embedded in nitrogen doped carbon with mosaic structure: An effective catalyst for oxygen reduction reaction," Energy, Elsevier, vol. 133(C), pages 115-120.
    5. Ma, Zhuo & Wang, Kaixuan & Qiu, Yunfeng & Liu, Xizheng & Cao, Changyan & Feng, Yujie & Hu, PingAn, 2018. "Nitrogen and sulfur co-doped porous carbon derived from bio-waste as a promising electrocatalyst for zinc-air battery," Energy, Elsevier, vol. 143(C), pages 43-55.
    6. Yuan, Wenjing & Xie, Anjian & Li, Shikuo & Huang, Fangzhi & Zhang, Peigen & Shen, Yuhua, 2016. "High-activity oxygen reduction catalyst based on low-cost bagasse, nitrogen and large specific surface area," Energy, Elsevier, vol. 115(P1), pages 397-403.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Mousavi, Seyed Ali & Mehrpooya, Mehdi, 2021. "Fabrication of copper centered metal organic framework and nitrogen, sulfur dual doped graphene oxide composite as a novel electrocatalyst for oxygen reduction reaction," Energy, Elsevier, vol. 214(C).
    2. Pan, Siyu & Cai, Zhuang & Yang, Liu & Tang, Bo & Xu, Xin & Chen, Hun & Ran, Lingling & Jing, Baojian & Zou, Jinlong, 2018. "Exposure of sufficient edge sites on well-crystallized MoSe2 induced by nitrogen doping (Mo−Nx) for Pt: Enhanced co-catalytic activity and methanol tolerance for oxygen reduction," Energy, Elsevier, vol. 159(C), pages 11-20.
    3. Cui, Hongmin & Xu, Jianguo & Shi, Jinsong & Yan, Nanfu & Liu, Yuewei, 2019. "Facile fabrication of nitrogen doped carbon from filter paper for CO2 adsorption," Energy, Elsevier, vol. 187(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yuan, Wenjing & Xu, Wanghua & Xie, Anjian & Zhang, Hui & Wang, Cuiping & Shen, Yuhua, 2017. "An effective strategy for the preparation of nitrogen-doped carbon from Imperata cylindrica panicle and its use as a metal-free catalyst for the oxygen reduction reaction," Energy, Elsevier, vol. 141(C), pages 1324-1331.
    2. Kiyani, Roya & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Nitrogen doped graphene supported palladium-cobalt as a promising catalyst for methanol oxidation reaction: Synthesis, characterization and electrocatalytic performance," Energy, Elsevier, vol. 113(C), pages 1162-1173.
    3. Mirzaei, Farokh & Parnian, Mohammad Javad & Rowshanzamir, Soosan, 2017. "Durability investigation and performance study of hydrothermal synthesized platinum-multi walled carbon nanotube nanocomposite catalyst for proton exchange membrane fuel cell," Energy, Elsevier, vol. 138(C), pages 696-705.
    4. Pan, Siyu & Cai, Zhuang & Yang, Liu & Tang, Bo & Xu, Xin & Chen, Hun & Ran, Lingling & Jing, Baojian & Zou, Jinlong, 2018. "Exposure of sufficient edge sites on well-crystallized MoSe2 induced by nitrogen doping (Mo−Nx) for Pt: Enhanced co-catalytic activity and methanol tolerance for oxygen reduction," Energy, Elsevier, vol. 159(C), pages 11-20.
    5. Yuan, Wenjing & Xie, Anjian & Li, Shikuo & Huang, Fangzhi & Zhang, Peigen & Shen, Yuhua, 2016. "High-activity oxygen reduction catalyst based on low-cost bagasse, nitrogen and large specific surface area," Energy, Elsevier, vol. 115(P1), pages 397-403.
    6. Miao, He & Wang, Zhouhang & Wang, Qin & Sun, Shanshan & Xue, Yejian & Wang, Fu & Zhao, Jiapei & Liu, Zhaoping & Yuan, Jinliang, 2018. "A new family of Mn-based perovskite (La1-xYxMnO3) with improved oxygen electrocatalytic activity for metal-air batteries," Energy, Elsevier, vol. 154(C), pages 561-570.
    7. Li, Li & Zheng, Keqing & Ni, Meng & Leung, Michael K.H. & Xuan, Jin, 2015. "Partial modification of flow-through porous electrodes in microfluidic fuel cell," Energy, Elsevier, vol. 88(C), pages 563-571.
    8. Liu, Xuan & Xue, Jilai, 2019. "The role of Al2Gd cuboids in the discharge performance and electrochemical behaviors of AZ31-Gd anode for Mg-air batteries," Energy, Elsevier, vol. 189(C).
    9. Wei, Manhui & Wang, Keliang & Zuo, Yayu & Wang, Hengwei & Zhao, Siyuan & Zhang, Pengfei & Zhang, Songmao & Shui, Youfu & Pei, Pucheng & Chen, Junfeng, 2023. "Inner Zn layer and outer glutamic acid film as efficient dual-protective interface of Al anode in Al-air fuel cell," Energy, Elsevier, vol. 267(C).
    10. Hidalgo, Diana & Tommasi, Tonia & Cauda, Valentina & Porro, Samuele & Chiodoni, Angelica & Bejtka, Katarzyna & Ruggeri, Bernardo, 2014. "Streamlining of commercial Berl saddles: A new material to improve the performance of microbial fuel cells," Energy, Elsevier, vol. 71(C), pages 615-623.
    11. Pourzare, K. & Mansourpanah, Y. & Farhadi, S. & Sadrabadi, M.M. Hasani & Ulbricht, M., 2022. "Improvement of proton conductivity of magnetically aligned phosphotungstic acid-decorated cobalt oxide embedded Nafion membrane," Energy, Elsevier, vol. 239(PA).
    12. Liu, Zhenning & Li, Zhiyuan & Ma, Jian & Dong, Xu & Ku, Wen & Wang, Mi & Sun, Hang & Liang, Song & Lu, Guolong, 2018. "Nitrogen and cobalt-doped porous biocarbon materials derived from corn stover as efficient electrocatalysts for aluminum-air batteries," Energy, Elsevier, vol. 162(C), pages 453-459.
    13. Stoševski, Ivan & Krstić, Jelena & Milikić, Jadranka & Šljukić, Biljana & Kačarević-Popović, Zorica & Mentus, Slavko & Miljanić, Šćepan, 2016. "Radiolitically synthesized nano Ag/C catalysts for oxygen reduction and borohydride oxidation reactions in alkaline media, for potential applications in fuel cells," Energy, Elsevier, vol. 101(C), pages 79-90.
    14. Kakaei, Karim & Rahnavardi, Mohammad, 2021. "Synthesis of nitrogen-doped reduced graphene oxide and its decoration with high efficiency palladium nanoparticles for direct ethanol fuel cell," Renewable Energy, Elsevier, vol. 163(C), pages 1277-1286.
    15. Jaimes-Paez, C.D. & Morallón, E. & Cazorla-Amorós, D., 2023. "Few layers graphene-based electrocatalysts for ORR synthesized by electrochemical exfoliation methods," Energy, Elsevier, vol. 278(PA).
    16. Rivera-Lugo, Yazmín Y. & Salazar-Gastélum, Moisés I. & López-Rosas, Deisly M. & Reynoso-Soto, Edgar A. & Pérez-Sicairos, Sergio & Velraj, Samgopiraj & Flores-Hernández, José R. & Félix-Navarro, Rosa M, 2018. "Effect of template, reaction time and platinum concentration in the synthesis of PtCu/CNT catalyst for PEMFC applications," Energy, Elsevier, vol. 148(C), pages 561-570.
    17. Ojani, Reza & Hasheminejad, Ehteram & Raoof, Jahan Bakhsh, 2015. "Direct growth of 3D flower-like Pt nanostructures by a template-free electrochemical route as an efficient electrocatalyst for methanol oxidation reaction," Energy, Elsevier, vol. 90(P1), pages 1122-1131.
    18. Qiu, Diankai & Peng, Linfa & Liang, Peng & Yi, Peiyun & Lai, Xinmin, 2018. "Mechanical degradation of proton exchange membrane along the MEA frame in proton exchange membrane fuel cells," Energy, Elsevier, vol. 165(PB), pages 210-222.
    19. Yang, H.N. & Lee, D.C. & Park, K.W. & Kim, W.J., 2015. "Platinum–boron doped graphene intercalated by carbon black for cathode catalyst in proton exchange membrane fuel cell," Energy, Elsevier, vol. 89(C), pages 500-510.
    20. Brenda Ai-Lian Lim & Steven Lim & Yean Ling Pang & Siew Hoong Shuit & Kam Huei Wong & Jong Boon Ooi, 2022. "Investigation on the Potential of Various Biomass Waste for the Synthesis of Carbon Material for Energy Storage Application," Sustainability, MDPI, vol. 14(5), pages 1-17, March.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:152:y:2018:i:c:p:333-340. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.