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A high-energy-density and long-stable-performance zinc-air fuel cell system

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  • Pei, Pucheng
  • Huang, Shangwei
  • Chen, Dongfang
  • Li, Yuehua
  • Wu, Ziyao
  • Ren, Peng
  • Wang, Keliang
  • Jia, Xiaoning

Abstract

Metal-air fuel cells are regarded as potential alternatives of power supply due to their high specific energy. However, the excessive accumulation of reaction products leads to performance degradation, low energy density, and short service life, hampering more widespread application. This study focuses on enormously increasing the fuel cell system energy density by electrolyte isolation and management. Filters are used to isolate metal oxide (including ZnO, MgO, and Al2O3) from supersaturated electrolyte solutions in fuel cells. The filtration efficiency is close to 100%. The flow field is optimized to suppress the anode passivation. In zinc-air fuel cells (ZAFCs), the ratio of discharge capacity to electrolyte volume (electrolyte capacity) is up to 1025 Ah L−1, and the discharging voltage still remains stable. The zinc-air fuel cell system (ZAFCS) exhibits high energy density, high stability, and low cost, rendering this type of metal-air fuel cell a promising energy storage in electric vehicles.

Suggested Citation

  • Pei, Pucheng & Huang, Shangwei & Chen, Dongfang & Li, Yuehua & Wu, Ziyao & Ren, Peng & Wang, Keliang & Jia, Xiaoning, 2019. "A high-energy-density and long-stable-performance zinc-air fuel cell system," Applied Energy, Elsevier, vol. 241(C), pages 124-129.
    • Handle: RePEc:eee:appene:v:241:y:2019:i:c:p:124-129
    DOI: 10.1016/j.apenergy.2019.03.004
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    References listed on IDEAS

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    1. Xu, Nengneng & Qiao, Jinli & Zhang, Xia & Ma, Chengyu & Jian, Saiai & Liu, Yuyu & Pei, Pucheng, 2016. "Morphology controlled La2O3/Co3O4/MnO2–CNTs hybrid nanocomposites with durable bi-functional air electrode in high-performance zinc–air energy storage," Applied Energy, Elsevier, vol. 175(C), pages 495-504.
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    3. Pei, Pucheng & Wang, Keliang & Ma, Ze, 2014. "Technologies for extending zinc–air battery’s cyclelife: A review," Applied Energy, Elsevier, vol. 128(C), pages 315-324.
    4. Zhou, Xuejun & Tang, Sheng & Yin, Yan & Sun, Shuihui & Qiao, Jinli, 2016. "Hierarchical porous N-doped graphene foams with superior oxygen reduction reactivity for polymer electrolyte membrane fuel cells," Applied Energy, Elsevier, vol. 175(C), pages 459-467.
    5. Wenger, Erez & Epstein, Michael & Kribus, Abraham, 2017. "Thermo-electro-chemical storage (TECS) of solar energy," Applied Energy, Elsevier, vol. 190(C), pages 788-799.
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    Cited by:

    1. Sangeetha, Thangavel & Chen, Po-Tuan & Yan, Wei-Mon & Huang, K. David, 2020. "Enhancement of air-flow management in Zn-air fuel cells by the optimization of air-flow parameters," Energy, Elsevier, vol. 197(C).
    2. Wang, Yifei & Kwok, Holly Y.H. & Pan, Wending & Zhang, Huimin & Lu, Xu & Leung, Dennis Y.C., 2019. "Parametric study and optimization of a low-cost paper-based Al-air battery with corrosion inhibition ability," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    3. Igor Iwakiri & Tiago Antunes & Helena Almeida & João P. Sousa & Rita Bacelar Figueira & Adélio Mendes, 2021. "Redox Flow Batteries: Materials, Design and Prospects," Energies, MDPI, vol. 14(18), pages 1-45, September.
    4. Wei, Manhui & Wang, Keliang & Pei, Pucheng & Zhong, Liping & Züttel, Andreas & Pham, Thi Ha My & Shang, Nuo & Zuo, Yayu & Wang, Hengwei & Zhao, Siyuan, 2023. "Zinc carboxylate optimization strategy for extending Al-air battery system's lifetime," Applied Energy, Elsevier, vol. 350(C).
    5. Xu, Nengneng & Zhang, Yanxing & Wang, Yudong & Wang, Min & Su, Tianshun & Coco, Cameron A. & Qiao, Jinli & Zhou, Xiao-Dong, 2020. "Hierarchical bifunctional catalysts with tailored catalytic activity for high-energy rechargeable Zn-air batteries," Applied Energy, Elsevier, vol. 279(C).
    6. Pan, Lyuming & Chen, Dongfang & Pei, Pucheng & Huang, Shangwei & Ren, Peng & Song, Xin, 2021. "A novel structural design of air cathodes expanding three-phase reaction interfaces for zinc-air batteries," Applied Energy, Elsevier, vol. 290(C).
    7. Wei, Manhui & Wang, Keliang & Pei, Pucheng & Zuo, Yayu & Zhong, Liping & Shang, Nuo & Wang, Hengwei & Chen, Junfeng & Zhang, Pengfei & Chen, Zhuo, 2022. "An enhanced-performance Al-air battery optimizing the alkaline electrolyte with a strong Lewis acid ZnCl2," Applied Energy, Elsevier, vol. 324(C).

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