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Comparative performance evaluation of self-humidifying PEMFCs with short-side-chain and long-side-chain membranes under various operating conditions

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  • Cha, Dowon
  • Jeon, Seung Won
  • Yang, Wonseok
  • Kim, Dongwoo
  • Kim, Yongchan

Abstract

The performance of a proton electrolyte membrane fuel cell (PEMFC) with a perfluorosulfonic-acid-based membrane is strongly dependent on the water content in the membrane. In this study, comparative performance evaluation of self-humidifying PEMFCs with short-side-chain (SSC) and long-side-chain (LSC) membranes is conducted under various operating temperatures, air stoichiometries, back pressures, and voltages. The optimal operating conditions at each voltage are determined by using response surface methodology. The self-humidifying PEMFC with the SSC membrane exhibits higher power density than that with the LSC membrane owing to higher water retention. The dominant operating parameter for the system performance changes from the back pressure to air stoichiometry with a decrease in the voltage. Moreover, based on the dynamic response tests, the self-humidifying PEMFC with the SSC membrane exhibits better reliability and settling time than that with the LSC membrane.

Suggested Citation

  • Cha, Dowon & Jeon, Seung Won & Yang, Wonseok & Kim, Dongwoo & Kim, Yongchan, 2018. "Comparative performance evaluation of self-humidifying PEMFCs with short-side-chain and long-side-chain membranes under various operating conditions," Energy, Elsevier, vol. 150(C), pages 320-328.
    • Handle: RePEc:eee:energy:v:150:y:2018:i:c:p:320-328
    DOI: 10.1016/j.energy.2018.02.133
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    Cited by:

    1. Yang, Wonseok & Cha, Dowon & Kim, Yongchan, 2019. "Effects of flow direction on dynamic response and stability of nonhumidification PEM fuel cell," Energy, Elsevier, vol. 185(C), pages 386-395.
    2. Guo, Xinru & Zhang, Houcheng, 2020. "Performance analyses of a combined system consisting of high-temperature polymer electrolyte membrane fuel cells and thermally regenerative electrochemical cycles," Energy, Elsevier, vol. 193(C).
    3. Wang, Ya-Xiong & Chen, Quan & Zhang, Jin & He, Hongwen, 2021. "Real-time power optimization for an air-coolant proton exchange membrane fuel cell based on active temperature control," Energy, Elsevier, vol. 220(C).
    4. Tiancai Ma & Kai Wang & Qiongqiong Zhou & Weikang Lin & Ming Cong & Wenya Jia, 2019. "Numerical Study on Humidification Performance of Fuel Cell Test Platform Humidifier," Energies, MDPI, vol. 12(20), pages 1-14, October.
    5. Chang, Yafei & Qin, Yanzhou & Yin, Yan & Zhang, Junfeng & Li, Xianguo, 2018. "Humidification strategy for polymer electrolyte membrane fuel cells – A review," Applied Energy, Elsevier, vol. 230(C), pages 643-662.
    6. Najmi, Aezid-Ul-Hassan & Anyanwu, Ikechukwu S. & Xie, Xu & Liu, Zhi & Jiao, Kui, 2021. "Experimental investigation and optimization of proton exchange membrane fuel cell using different flow fields," Energy, Elsevier, vol. 217(C).
    7. Chen, Xin & Zhang, Ying & Xu, Sheng & Dong, Fei, 2023. "Bibliometric analysis for research trends and hotspots in heat and mass transfer and its management of proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 333(C).
    8. Cai, Yonghua & Wu, Di & Sun, Jingming & Chen, Ben, 2021. "The effect of cathode channel blockages on the enhanced mass transfer and performance of PEMFC," Energy, Elsevier, vol. 222(C).
    9. Qiu, Diankai & Peng, Linfa & Liang, Peng & Yi, Peiyun & Lai, Xinmin, 2018. "Mechanical degradation of proton exchange membrane along the MEA frame in proton exchange membrane fuel cells," Energy, Elsevier, vol. 165(PB), pages 210-222.
    10. Yuemeng Zhang & Jia Wang & Zhanhui Yao, 2023. "Recent Development of Fuel Cell Core Components and Key Materials: A Review," Energies, MDPI, vol. 16(5), pages 1-23, February.

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