IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v214y2021ics0360544220321605.html
   My bibliography  Save this article

Fabrication of copper centered metal organic framework and nitrogen, sulfur dual doped graphene oxide composite as a novel electrocatalyst for oxygen reduction reaction

Author

Listed:
  • Mousavi, Seyed Ali
  • Mehrpooya, Mehdi

Abstract

The main focus of this study is to synthesize a free – platinum electrocatalyst for ORR applications. Since the price of copper is much lower than platinum, the Copper - centered Metal Organic Framework (Cu - MOF) is selected as the electrocatalyst. The electron conductivity of MOFs is low. Accordingly, in order to enhance the ORR kinetics and electrochemistry activity, for the first time, Nitrogen and Sulfur Dual-Doped Reduced Graphene Oxide (NS - RGO) with different concentrations are incorporated into the Cu – MOF structure. In other words, NS-RGO has high electrical conductivity which can operate as an efficient carrier for electron transfer. For evaluating the structural properties and morphology of synthesized electrocatalysts, six main characterization techniques, consist of XRD, FESEM, Raman, EDS, TEM, and FTIR are employed. Also, in order to assess the durability and ORR activity, the electrochemical measurements are performed. The electrochemical tests are implemented using the Rotary Disk Electrode (RDE) device in the alkaline medium. Based on the achieved results, the best ORR activity is related to the 8% NS – RGO - Cu – MOF catalyst. The onset potential and electron transferred number (n) of this catalyst are obtained to be −0.06 V vs Ag/AgCl and 3.53, respectively. In other words, it tends to favor the 4e-pathway for ORR. In this project, the relationship between structure and electrochemistry activity of non-precious metal/carbon composites is investigated. materials Finally, the electrochemistry activity of synthesized electrocatalysts is compared to the previous investigations and commercial 20 wt% Pt/C. These comparisons indicated that mixing different concentrations of NS-RGO with Cu-MOF can improve the electrochemistry activity of MOFs considerably. Actually, the NS – RGO - Cu – MOF composite can be considered as a new cost-effective electrocatalyst that can help to the development of fuel cell technology.

Suggested Citation

  • Mousavi, Seyed Ali & Mehrpooya, Mehdi, 2021. "Fabrication of copper centered metal organic framework and nitrogen, sulfur dual doped graphene oxide composite as a novel electrocatalyst for oxygen reduction reaction," Energy, Elsevier, vol. 214(C).
    • Handle: RePEc:eee:energy:v:214:y:2021:i:c:s0360544220321605
    DOI: 10.1016/j.energy.2020.119053
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544220321605
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2020.119053?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Yuan, Wenjing & Xie, Anjian & Chen, Ping & Huang, Fangzhi & Li, Shikuo & Shen, Yuhua, 2018. "Combustion reaction-derived nitrogen-doped porous carbon as an effective metal-Free catalyst for the oxygen reduction reaction," Energy, Elsevier, vol. 152(C), pages 333-340.
    2. Li, Jie-Cheng & Wu, Xiao-Tong & Chen, Li-Jun & Li, Nan & Liu, Zhao-Qing, 2018. "Bifunctional MOF-derived Co-N-doped carbon electrocatalysts for high-performance zinc-air batteries and MFCs," Energy, Elsevier, vol. 156(C), pages 95-102.
    3. Yuan, Wenjing & Xu, Wanghua & Xie, Anjian & Zhang, Hui & Wang, Cuiping & Shen, Yuhua, 2017. "An effective strategy for the preparation of nitrogen-doped carbon from Imperata cylindrica panicle and its use as a metal-free catalyst for the oxygen reduction reaction," Energy, Elsevier, vol. 141(C), pages 1324-1331.
    4. Xin, Shuaishuai & Shen, Jianguo & Liu, Guocheng & Chen, Qinghua & Xiao, Zhou & Zhang, Guodong & Xin, Yanjun, 2020. "High electricity generation and COD removal from cattle wastewater in microbial fuel cells with 3D air cathode employed non-precious Cu2O/reduced graphene oxide as cathode catalyst," Energy, Elsevier, vol. 196(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Pongratz, Gernot & Subotić, Vanja & Hochenauer, Christoph & Scharler, Robert & Anca-Couce, Andrés, 2022. "Solid oxide fuel cell operation with biomass gasification product gases: Performance- and carbon deposition risk evaluation via a CFD modelling approach," Energy, Elsevier, vol. 244(PB).
    2. Zhang, Junfeng & Yan, Detian & Zhou, Sandong & Wang, Hua & Deng, Yong & Liu, Entao & Song, Guangzeng, 2023. "Sedimentological and diagenetic effects on petrophysical characteristics and hydraulic flow units of Zhujiang sandstones in the Pearl River Mouth Basin, south China Sea," Energy, Elsevier, vol. 282(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Liu, Xuan & Xue, Jilai, 2019. "The role of Al2Gd cuboids in the discharge performance and electrochemical behaviors of AZ31-Gd anode for Mg-air batteries," Energy, Elsevier, vol. 189(C).
    2. Shahid, Kanwal & Ramasamy, Deepika Lakshmi & Haapasaari, Sampo & Sillanpää, Mika & Pihlajamäki, Arto, 2021. "Stainless steel and carbon brushes as high-performance anodes for energy production and nutrient recovery using the microbial nutrient recovery system," Energy, Elsevier, vol. 233(C).
    3. Wei, Manhui & Wang, Keliang & Zuo, Yayu & Wang, Hengwei & Zhao, Siyuan & Zhang, Pengfei & Zhang, Songmao & Shui, Youfu & Pei, Pucheng & Chen, Junfeng, 2023. "Inner Zn layer and outer glutamic acid film as efficient dual-protective interface of Al anode in Al-air fuel cell," Energy, Elsevier, vol. 267(C).
    4. Sayed, Enas Taha & Abdelkareem, Mohammad Ali & Alawadhi, Hussain & Elsaid, Khaled & Wilberforce, Tabbi & Olabi, A.G., 2021. "Graphitic carbon nitride/carbon brush composite as a novel anode for yeast-based microbial fuel cells," Energy, Elsevier, vol. 221(C).
    5. Hajiali, Mahboube & Farhadian, Mehrdad & khosravi, Mohsen, 2024. "Evaluation of a novel continuous baffled photo-reactor for tetracycline degradation and simultaneous electricity production in photocatalytic fuel cell," Renewable Energy, Elsevier, vol. 226(C).
    6. Han, Chaoling & Chen, Zhenqian, 2021. "Study on the synergism of thermal transport and electrochemical of PEMFC based on N, P co-doped graphene substrate electrode," Energy, Elsevier, vol. 214(C).
    7. Mohamed, Hend Omar & Talas, Sawsan Abo & Sayed, Enas T. & Park, Sung-Gwan & Eisa, Tasnim & Abdelkareem, Mohammad Ali & Fadali, Olfat A. & Chae, Kyu-Jung & Castaño, Pedro, 2021. "Enhancing power generation in microbial fuel cell using tungsten carbide on reduced graphene oxide as an efficient anode catalyst material," Energy, Elsevier, vol. 229(C).
    8. Cui, Hongmin & Xu, Jianguo & Shi, Jinsong & Yan, Nanfu & Liu, Yuewei, 2019. "Facile fabrication of nitrogen doped carbon from filter paper for CO2 adsorption," Energy, Elsevier, vol. 187(C).
    9. Chen, Wenwen & Liu, Zhongliang & Li, Yanxia & Liao, Qiang & Zhu, Xun, 2021. "High electricity generation achieved by depositing rGO@MnO2 composite catalysts on three-dimensional stainless steel fiber felt for preparing the energy-efficient air cathode in microbial fuel cells," Energy, Elsevier, vol. 222(C).
    10. de Ramón-Fernández, A. & Salar-García, M.J. & Ruiz Fernández, D. & Greenman, J. & Ieropoulos, I.A., 2020. "Evaluation of artificial neural network algorithms for predicting the effect of the urine flow rate on the power performance of microbial fuel cells," Energy, Elsevier, vol. 213(C).
    11. Pan, Siyu & Cai, Zhuang & Yang, Liu & Tang, Bo & Xu, Xin & Chen, Hun & Ran, Lingling & Jing, Baojian & Zou, Jinlong, 2018. "Exposure of sufficient edge sites on well-crystallized MoSe2 induced by nitrogen doping (Mo−Nx) for Pt: Enhanced co-catalytic activity and methanol tolerance for oxygen reduction," Energy, Elsevier, vol. 159(C), pages 11-20.
    12. Liu, Zhenning & Li, Zhiyuan & Ma, Jian & Dong, Xu & Ku, Wen & Wang, Mi & Sun, Hang & Liang, Song & Lu, Guolong, 2018. "Nitrogen and cobalt-doped porous biocarbon materials derived from corn stover as efficient electrocatalysts for aluminum-air batteries," Energy, Elsevier, vol. 162(C), pages 453-459.
    13. Silveira, Gustavo & de Aquino Neto, Sidney & Schneedorf, José Maurício, 2020. "Development, characterization and application of a low-cost single chamber microbial fuel cell based on hydraulic couplers," Energy, Elsevier, vol. 208(C).
    14. Zhang, Yi-Jie & Gao, Yi-Jun & Wang, Xiaoge & Ye, Qin & Zhang, Ya & Wu, Yu & Chen, Shu-Han & Ruan, Bo & Shi, Dean & Jiang, Tao & Tsai, Fang-Chang & Ma, Ning, 2022. "MoTe2 on metal-organic framework derived MoO2/N-doped carbon rods for enhanced sodium-ion storage properties," Energy, Elsevier, vol. 243(C).
    15. Chen, Bor-Yann & Liao, Jia-Hui & Hsueh, Chung-Chuan & Qu, Ziwei & Hsu, An-Wei & Chang, Chang-Tang & Zhang, Shuping, 2018. "Deciphering biostimulation strategy of using medicinal herbs and tea extracts for bioelectricity generation in microbial fuel cells," Energy, Elsevier, vol. 161(C), pages 1042-1054.
    16. Tan, Peng & Chen, Bin & Xu, Haoran & Cai, Weizi & He, Wei & Ni, Meng, 2019. "Porous Co3O4 nanoplates as the active material for rechargeable Zn-air batteries with high energy efficiency and cycling stability," Energy, Elsevier, vol. 166(C), pages 1241-1248.
    17. Mokhtar Ali Amrani & Yara Haddad & Firas Obeidat & Atef M. Ghaleb & Sobhi Mejjaouli & Ibrahim Rahoma & Mansour S. A. Galil & Mutahar Shameeri & Ahmed A. Alsofi & Amin Saif, 2022. "Productive and Sustainable H 2 Production from Waste Aluminum Using Copper Oxides-Based Graphene Nanocatalysts: A Techno-Economic Analysis," Sustainability, MDPI, vol. 14(22), pages 1-21, November.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:214:y:2021:i:c:s0360544220321605. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.